• Journal of Biosystems Engineering
• /
• 제16권3호
• /
• pp.263-271
• /
• 1991

When grains is subjected to oscillating load, the dynamic viscoelastic behavior of the material will be describe the complex modulus of the material. The complex modulus and therefore the storage modulus, the loss modulus, and the phase angle for the sample should be obtainable with a given static viscoelastic property of the material under static load. The complex relaxation moduli of the rough rice kernel were computed from the Burger's model describing creep behavior of the material which were obtained in the previous study. Also, the effects of cyclic load and moisture content of grain on the dynamic viscoelastic behavior of the samples were analized. The storage modulus of the rough rice kernel slightly increased with the frequency applied but at above the frequency of 0.1 Hz it was nearly constant with the frequency, and the loss modulus of the sample very rapidly decreased with increase in the frequency on those frequency ranges. It was shown that the storage modulus and the loss modulus of the sample increased with decrease in grain moisture content. Effect of grain moisture content on the storage modulus of the sample was highly significant than effect of the frequency applied, but effect of the frequency on the loss modulus of the sample was more significant than effect of grain moisture content.

• Food Science and Biotechnology
• /
• 제16권3호
• /
• pp.496-499
• /
• 2007

Dynamic rheological properties of hot pepper-soybean paste (HPSP) samples mixed with guar gum and xanthan gum were evaluated at different storage temperatures (5, 15, and $25^{\circ}C$) by using a dynamic rheometer. Magnitudes of storage modulus (G'), loss modulus (G"), and complex viscosity (${\eta}^*$) in the HPSP-gum mixtures increased with an increase in storage temperature from 5 to $25^{\circ}C$. After 3-month storage at 5 and $15^{\circ}C$ there were no significant changes in dynamic rheological properties. The increase in dynamic moduli (G', G", and ${\eta}^*$) with storage temperature is less pronounced at HPSP-xanthan gum mixtures in comparison to HPSP-guar gum mixtures. The slopes of G' (0.16-0.18) of HPSP-guar gum mixtures at 3-month storage were much higher than that (0.10) at 0-month storage, indicating that the elastic properties of the HPSP-guar gum mixtures can be decreased after 3-month storage. However, there were not much differences between the slopes of G' in HPSP-xathan gum mixtures. Xanthan gum was observed to be better structure stabilizer for HPSP during storage.

• Carbon letters
• /
• 제11권4호
• /
• pp.285-292
• /
• 2010

Novel unsaturated polyester composites with PAN-based nanofiber, stabilized PAN nanofiber, and carbonized nanofiber webs have been fabricated, respectively, and the effects of the nanofiber web content on their electrical resistivity, the thermal stability, dynamic storage modulus, and fracture surfaces were studied. The result demonstrated that the introduction of just one single layer (which is corresponding to 2 wt.%) of the carbonized nanofiber web to unsaturated polyester resin (UPE) could contribute to reducing markedly the electrical resistivity of the resin reflecting the percolation threshold, to improving the storage modulus, and to increasing the thermal stability above $350^{\circ}C$. The effect on decreasing the resistivity and increasing the modulus was the greatest at the carbonized PAN nanofiber web content of 8 wt.%, particularly showing that the storage modulus was increased about 257~283% in the measuring temperature range of $-25^{\circ}C$ to $50^{\circ}C$. The result also exhibited that the carbonized PAN nanofibers were distributed uniformly and compactly in the unsaturated polyester, connecting the matrix three-dimensionally through the thickness direction of each specimen. It seemed that such the fiber distribution played a role in reducing the electrical resistivity as well as in improving the dynamic storage modulus.

• 한국재료학회지
• /
• 제2권3호
• /
• pp.220-227
• /
• 1992

전기유변유체(electrorheological fluid : ERF)는 크기가 $10^{-6}m$정도를 가진 분극성이 강한 입자 분말을 유전유체속에 혼합하여 만든 콜로이드용액으로서 외부전기 장에 의하여 액체상태로부터 겔(gel)상태로 상태변환을 한다. 상태변환과정은 가역과정이며 $10^{-3}$초 정도의 빠른 시간내에 이루어진다. 본 논문에서는 주기적응력이나 주기적 변형이 가해지는 강제진동실험을 통하여 ERF의 점탄성 특성을 조사하였다. 점탄성은 복소수로서 실수부인 동적전단탄성율(storage shear modulus, G')과 허수부인 동적손실율(loss modulus, G")의 합으로 표현된다. 동적전단탄성율은 강제진동의 진폭과 주파수의 함수로 외부전기장에 의하여 크게 변화되었으나 손실계수(loss factor, ${\eta}=G"/G'$)는 진동의 진폭, 진동수 및 외부전기 장에 거의 독립적이었다. 실험(1)은 강제진동의 진폭을 고정하고 진동수를 변화하는 방법(frequency sweep)과 실험(2)는 진동 진폭을 변화시키는 방법(amplitude sweep)으로 실행했다. 본 실험에서는 cornstarch입자를 corn oil에 혼합한 것과 zeolite입자를 silicone oil에 흔합한 콜로이드 용액이 ERF로서 사용되었으며 인가된 전기장은 약$(1~3){\times}10^6V/m$의 직류전기장이 가하여졌다.기장이 가하여졌다.

• Korea-Australia Rheology Journal
• /
• 제21권3호
• /
• pp.185-191
• /
• 2009

Polystyrene/multi-walled carbon nanotube (PS/MWCNT) composites were prepared by the use of latex technology. The monodisperse PS latex was synthesized by an emulsifier-free emulsion polymerization from styrene/potassium persulfate/water system in the presence of ethanol. The MWCNTs were first treated with acid mixture to eliminate impurities, dispersed in deionized water driven by ultrasonicator, and then mixed with the PS latex. From these mixtures, PS/MWCNT composites were prepared by freeze-drying and subsequent compression molding. In the small-amplitude oscillatory shear experiments, both complex viscosity and storage modulus increased with increasing MWCNT content. A pronounced effect of MWCNT content was observed, resulting in larger storage modulus and stronger yield behavior at low frequencies when compared to unmodified PS. It showed a transition from viscous to elastic behavior with increasing MWCNT content. Over the MWCNT content of 3 wt%, the storage modulus was higher than the loss modulus across all frequencies.

• Korea-Australia Rheology Journal
• /
• 제20권4호
• /
• pp.227-233
• /
• 2008

High impact polystyrene (HIPS)/organoclay nanocomposites via in situ polymerization were synthesized and their rheological properties were investigated. For the study, two types of organoclays were used: a commercially available organoclay, Cloisite 10A (C10A), and a laboratory-prepared organoclay having a reactant group, vinylclay (ODVC). The X-ray diffraction and transmission electron microscopy experiments revealed that the HIPS/ODVC nanocomposite achieved an exfoliated structure, whereas the HIPS/C10A nanocomposite achieved an intercalated structure. In the small-amplitude oscillatory shear experiments, both storage modulus and complex viscosity increased with increasing organoclay. A pronounced effect of the organoclay content was observed, resulting in larger storage modulus and stronger yield behavior in the low frequency region when compared to neat HIPS. The crossover frequencies associated with the inverse of a longest relaxation time decreased as the organoclay content increased. Over a certain value of ODVC content, a change of pattern in rheological properties could be found, indicating a solid-like response with storage modulus greater than loss modulus at all frequencies.

• 터널과지하공간
• /
• 제33권2호
• /
• pp.71-82
• /
• 2023

본 연구에서는 암반 수리-역학적 관계의 기본모델 입력인자인 암석 입자 체적계수에 대하여 직접적인 측정 실험법을 제시하고, 실험을 수행함으로써 암석 입자 체적계수를 도출하였다. 또한, 서로 다른 기하학적 특성을 가진 암석에 대하여 암석 입자 체적계수를 비교함으로써 입자 체적계수에 영향을 미치는 요인에 대해 살펴보았다. 실험 결과 이론적으로 추정하는 암석 입자 체적계수의 값이 실제보다 과대예측 하고 있음을 확인하였으며, 이에 대해 암체 입자 구조에 따른 암석 내부 고립돼있는 공극의 존재로 인한 가능성을 고찰하였다. 최종적으로, 본 연구에서 제시한 직접적인 측정방법이 사암의 입자 체적계수를 신뢰성 있게 예측할 수 있음을 확인하였다.

• 터널과지하공간
• /
• 제7권2호
• /
• pp.91-99
• /
• 1997

To stabilize the energy price, the more storage facilities of energy are required and among the storage methods of LPG and LNG, the method of storage at low temperature under normal confining pressure is considered. It is needed to understand the mechanical and thermal characteristics of rock under temperature variation so that the behaviors of rock can be predicted. In this paper, the variation of the rock charateristics of the Hwangdeung granite and the Boryung sandstone is studied at low temperature. The mechanical characteristics of rock under low temperatures are that as temperature decreased, unaxial compression strength and Young's modulus increased for Hwangdeung granite; strength and Young's modulus in wet condition were greater than those in dry condition. In the case of Boryung sandstone, as temperature decreases unaxial compression strength and Young's modulus increase but decrease below -10$0^{\circ}C$ in dry condition and below -16$0^{\circ}C$ in wet condtion. The mechanical characteristics of rock after cooling to previous temperature and thawing are that uniaxial compression strength and Young's modulus decrease as temperature decreases. Uniaxial compression strength and Young's modulus in wet conditon decrease more than those in dry condition. Brazilian tension strength decreases as temperature decreases.

• Journal of Pharmaceutical Investigation
• /
• 제39권3호
• /
• pp.185-199
• /
• 2009

Using a strain-controlled rheometer [Advanced Rheometric Expansion System (ARES)], the steady shear flow properties and the dynamic viscoelastic properties of $Antiphlamine-S^{(R)}$ lotion have been measured at $20^{\circ}C$ (storage temperature) and $37^{\circ}C$ (body temperature). In this article, the temperature dependence of the linear viscoelastic behavior was firstly reported from the experimental data obtained from a temperature-sweep test. The steady shear flow behavior was secondly reported and then the effect of shear rate on this behavior was discussed in detail. In addition, several inelastic-viscoplastic flow models including a yield stress parameter were employed to make a quantitative evaluation of the steady shear flow behavior, and then the applicability of these models was examined by calculating the various material parameters. The angular frequency dependence of the linear viscoelastic behavior was nextly explained and quantitatively predicted using a fractional derivative model. Finally, the strain amplitude dependence of the dynamic viscoelastic behavior was discussed in full to elucidate a nonlinear rheological behavior in large amplitude oscillatory shear flow fields. Main findings obtained from this study can be summarized as follows : (1) The linear viscoelastic behavior is almostly independent of temperature over a temperature range of $15{\sim}40^{circ}C$. (2) The steady shear viscosity is sharply decreased as an increase in shear rate, demonstrating a pronounced Non-Newtonian shear-thinning flow behavior. (3) The shear stress tends to approach a limiting constant value as a decrease in shear rate, exhibiting an existence of a yield stress. (4) The Herschel-Bulkley, Mizrahi-Berk and Heinz-Casson models are all applicable and have an equivalent validity to quantitatively describe the steady shear flow behavior of $Antiphlamine-S^{(R)}$ lotion whereas both the Bingham and Casson models do not give a good applicability. (5) In small amplitude oscillatory shear flow fields, the storage modulus is always greater than the loss modulus over an entire range of angular frequencies tested and both moduli show a slight dependence on angular frequency. This means that the linear viscoelastic behavior of $Antiphlamine-S^{(R)}$ lotion is dominated by an elastic nature rather than a viscous feature and that a gel-like structure is present in this system. (6) In large amplitude oscillatory shear flow fields, the storage modulus shows a nonlinear strain-thinning behavior at strain amplitude range larger than 10 % while the loss modulus exhibits a weak strain-overshoot behavior up to a strain amplitude of 50 % beyond which followed by a decrease in loss modulus with an increase in strain amplitude. (7) At sufficiently large strain amplitude range (${\gamma}_0$>100 %), the loss modulus is found to be greater than the storage modulus, indicating that a viscous property becomes superior to an elastic character in large shear deformations.

• Journal of the Korean Wood Science and Technology
• /
• 제35권5호
• /
• pp.76-86
• /
• 2007

This study was conducted to investigate the effects of formaldehyde to urea (F/U) mole ratio on thermomechanical curing of UF resin adhesives with different F/U mole ratios. Thermomechanical curing of these UF resin adhesives was characterized using parameters of dynamic mechanical analysis (DMA) such as the gel temperature, maximum storage modulus, and peak temperatures of storage and loss modulus. As the F/U mole ratio decreased, the gel temperature of UF resin adhesives increased. The maximum storage modulus as an indicator of the rigidity of UF resin adhesives decreased with decreasing F/U mole ratio. The peak temperature of tan $\delta$ increased with decreasing F/U mole ratio, indicating that the vitrification occurred faster for high F/U mole ratio of UF resin adhesives than for the one of lower F/U mole ratio. These results partially explained the reason why UF resin adhesives with lower F/U mole ratio resulted in relatively poor adhesion performance when they were applied.