• 펄프종이기술
• /
• 제30권3호
• /
• pp.29-37
• /
• 1998

In order to set up a proper AKD quantification method for studing AKD hydrolysis, a quantitative analysis method using Uv/vis spectroscopy was evaluated and compared to the conventional GC-MS analysis. Hydrolysis rates of AKD emulsions during storage at 4$0^{\circ}C$ were measured by the UV/vis analysis. Owing to its simplicity and capability of measuring the unreacted AKD significantly even in a small amount, UV/vis method proved to be more suitable for studing AKD hydrolysis than GC-MS analysis. AKD hydrolysis was affected by the types of emulsifiers. Polymer stabilized AKD emulsion hydrolyzed more rapidly than starch stabilized AKD.

• 한국세라믹학회지
• /
• 제35권12호
• /
• pp.1294-1300
• /
• 1998

Yttria-stabilized zirconia ceramics with irregular grain shapes and curved grain boundaries was prepared by ceria doping. The amount of ceria doped into zirconia compacts by a dipping method were at range of 2 to 20 mol% Irregular grain shapes and curved grain boundaries were formed only inspecimens doped with more than 8mol% cerial. Ceria-doped specimens showed large grain size and low sintered density compared with pure yttria-stabilized zirconia which was due to the increase in the contents of stabilizer and cubic phase. The amount of doped ceria was larger on the surface than the inside regions and therefore mi-crostructure and phase on the surface were different from those in the inside regions. Transgranular frac-ture mode was observed ion ceria doped specimens due to irregular large grain sizes.

• Macromolecular Research
• /
• 제12권6호
• /
• pp.604-607
• /
• 2004

We report an important and useful method for preparing ${\omega}-sulfonated$ polystyrene-stabilized cadmium sulfide (CdS) nanoclusters. The ${\omega}-sulfonated$ polystyrene $(M_n\;=\;5000\;g/mol)$ was prepared successfully through chain-end sulfonation of poly(styryl)lithium using 1,3-propanesultone; the resulting polymer was used successfully as a polymeric stabilizing agent for the preparation of semiconductor CdS nanoclusters by reduction of cadmium acetate in a mixture of toluene and methanol (9:1, v/v). The nanoclusters that formed were characterized by a combination of transmission electron microscopy, X-ray diffraction, and UVN is spectroscopic analysis. The ${\omega}-sulfonated$ polystyrene-stabilized CdS nanoclusters synthesized in this study exhibited the cubic phase (zinc-blende phase) structure in the range of 2-8 nm.

• 한국세라믹학회지
• /
• 제22권4호
• /
• pp.40-46
• /
• 1985

Thermal diffusivities of zirconia samples partially or fully stabilized by MgO and $Y_2O_3$ were measured b laser-flash method up to 140$0^{\circ}C$ The values of thermal diffusivity decreased as the contents of MgO and $Y_2O_3$ increased due to the phonon scattering effect of defect structure of cubic phase formed. The temperature dependence of thermal diffusivity showed that the thermal diffusivity values decreased due to phono-phonon scattering as the temperature increased. The difference in thermal diffusivity was observed on cooling after heating up to 140$0^{\circ}C$ for magnesia stabi-lized zirconia samples but not for yttria stabilized zirconia samples.

• 한국정보디스플레이학회:학술대회논문집
• /
• 한국정보디스플레이학회 2003년도 International Meeting on Information Display
• /
• pp.589-594
• /
• 2003

The pi-cell [1] is known as one of the candidates for a fast response time and a good viewing angle characteristics due to a self-compensated configuration and can be a replaceable mode instead of the current TN mode and the IPS mode for moving picture in future. This paper shows the optimized condition to maintain bend state instead of splay state, which is mortal demerit for good optical properties in a pi-cell, by using the polymer stabilized method [2]. The good electro-optical characteristics are also obtained by optimizing the various factors, which are monomer concentration in a LC, UV intensity, curing time, curing voltage, and curing temperature, and by using retardation film. We use a scanning electron microscope to study the structures of the polymer stabilized polymer network in a pi-cell as a key to figure out why bend state is occurred.

• Geomechanics and Engineering
• /
• 제23권5호
• /
• pp.481-491
• /
• 2020

Piles installed in row(s) are used as an effective technique to improve the stability of soil slopes. The analysis of pile-stabilized slopes require a reliable prediction of lateral resistance offered by the piles. In this work, an analytical solution is developed to estimate the lateral resistance offered by the stabilizing piles in sand and c - 𝜙 soil slopes considering soil arching phenomenon. The soil arching in both horizontal direction (between the neighboring piles) and vertical direction (in the active wedge in front of the pile row) are studied and their effects are incorporated in the proposed model. The shape of soil arch is assumed to be circular and principal stress trajectories are defined separately for both modes of arching. Experimental and numerical studies found in literature were used to validate the proposed method. A detailed parametric analysis was performed to study the influence of pile diameter, center-to-center spacing, slope angle and angle of internal friction on the lateral pile resistance.

• 약학회지
• /
• 제44권3호
• /
• pp.251-256
• /
• 2000

Sterically stabilized liposomes (SSL) composed of distearoylphosphatidylcholine, cholesterol, dicetylphosphate and distearoylphosphatiodylethanolamine-N-poly(ethyleneglycol) 2000 (DSPE-PEG 2000) were made by reverse phase evaporation method to prolong biological half-life and decrease toxic side effect of drug. Streptozocin (572), a water-soluble antitumor agent with short half-life, was selected as a model drug. The size of SSL was controlled by polycarbonate extrusion to 100 nm which is adequate size for long circulation in plasma. The release rate of drugs from SSL in PBS was evaluated. And the stability of STZ-containing liposomes against drug leakage into rat plasma was evaluated in order to investigate the interaction of liposome and plasma protein. Incorporation of DSPE-PEG 2000 into conventional liposomes significantly decreased the drug leakage into rat plasma.

• Wind and Structures
• /
• 제14권5호
• /
• pp.465-480
• /
• 2011

In this paper, a stabilized large eddy simulation technique is developed to predict turbulent flow with high Reynolds number. Streamline Upwind Petrov-Galerkin (SUPG) stabilized method and three-step technique are both implemented for the finite element formulation of Smagorinsky sub-grid scale (SGS) model. Temporal discretization is performed using three-step technique with viscous term treated implicitly. And the pressure is computed from Poisson equation derived from the incompressible condition. Then two numerical examples of turbulent flow with high Reynolds number are discussed. One is lid driven flow at Re = $10^5$ in a triangular cavity, the other is turbulent flow past a square cylinder at Re = 22000. Results show that the present technique can effectively suppress the instabilities of turbulent flow caused by traditional FEM and well predict the unsteady flow even with coarse mesh.

• Geomechanics and Engineering
• /
• 제36권3호
• /
• pp.277-293
• /
• 2024

Shored Mechanically Stabilized Earth (SMSE) walls are types of soil retaining structures that increase soil stability under static and dynamic loads. The damage caused by an earthquake can be determined by evaluating the probabilistic seismic response of SMSE walls. This study aimed to assess the seismic performance of SMSE walls and provide fragility curves for evaluating failure levels. The generated fragility curves can help to improve the seismic performance of these walls through assessing and controlling variables like backfill surface settlement, lateral deformation of facing, and permanent relocation of the wall. A parametric study was performed based on a non-linear elastoplastic constitutive model known as the hardening soil model with small-strain stiffness, HSsmall. The analyses were conducted using PLAXIS 2D, a Finite Element Method (FEM) program, under plane-strain conditions to study the effect of the number of geogrid layers and the axial stiffness of geogrids on the performance of SMSE walls. In this study, three areas of damage (minor, moderate, and severe) were observed and, in all cases, the wall has not completely entered the stage of destruction. For the base model (Model A), at the highest ground acceleration coefficient (1 g), in the moderate damage state, the fragility probability was 76%. These values were 62%, and 54%, respectively, by increasing the number of geogrids (Model B) and increasing the geogrid stiffness (Model C). Meanwhile, the fragility values were 99%, 98%, and 97%, respectively in the case of minor damage. Notably, the probability of complete destruction was zero percent in all models.

• Journal of Pharmaceutical Investigation
• /
• 제31권3호
• /
• pp.197-200
• /
• 2001

Lectin-conjugated ellagitannin (LET), a newly introduced melanoma-specific antitumor agent which has been synthesized by conjugation of wheat germ agglutinin as a lectin with praecoxin A as an ellagitannin, was encapsulated into sterically stabilized liposomes (SSL). Modified Folin phenol method was established for the quantitation of LET contents in liposomal formulations protein employing the standard calibration curve with bovine serum albumin. After removal of phospholipid by organic solvent extraction, which interferes the specific selectivity of the Folin-Ciocalteu reagent with the protein, recovery of LET was $94.5{\pm}2.3%$ and the encapsulation efficiency was revealed as $37.8{\pm}5.9%$ for 2.5 mg/ml LET solution.