Browse > Article

Synthesis and Characterization of ${\omega}-Sulfonated$ Polystyrene-stabilized Cadmium Sulfide Nanoclusters  

Jin Yong Hyun (Polymer Hybrids Center, Korea Institute of Science and Technology)
Kim Jungahn (Polymer Hybrids Center, Korea Institute of Science and Technology)
Im Seung Soon (Department of Textile Engineering, Hanyang University)
Publication Information
Macromolecular Research / v.12, no.6, 2004 , pp. 604-607 More about this Journal
Abstract
We report an important and useful method for preparing ${\omega}-sulfonated$ polystyrene-stabilized cadmium sulfide (CdS) nanoclusters. The ${\omega}-sulfonated$ polystyrene $(M_n\;=\;5000\;g/mol)$ was prepared successfully through chain-end sulfonation of poly(styryl)lithium using 1,3-propanesultone; the resulting polymer was used successfully as a polymeric stabilizing agent for the preparation of semiconductor CdS nanoclusters by reduction of cadmium acetate in a mixture of toluene and methanol (9:1, v/v). The nanoclusters that formed were characterized by a combination of transmission electron microscopy, X-ray diffraction, and UVN is spectroscopic analysis. The ${\omega}-sulfonated$ polystyrene-stabilized CdS nanoclusters synthesized in this study exhibited the cubic phase (zinc-blende phase) structure in the range of 2-8 nm.
Keywords
cadmium sulfide; chain-end sulfonation; nanoclusters; semiconductor;
Citations & Related Records

Times Cited By Web Of Science : 1  (Related Records In Web of Science)
Times Cited By SCOPUS : 0
연도 인용수 순위
  • Reference
1 S. Forster and T. Plantenberg, Angew. Chem. Int. Ed., 41, 688 (2002)
2 W. J. Parak, D. Gerion, T. Pellegrino, D. Zanchet, C. Micheel, S. C. Williams, R. Boudreau, M. A. Le Gros, C. A. Larabell, and A. P. Alivisatos, Nanotechnology 14, R15 (2003)
3 R. S. Tanke, S. M. Kauzlarich, T. E. Patten, K. A. Pettigrew, D. L. Murphy, M. E. Thompson, and H. W. H. Lee, Chem. Mater., 15, 1682 (2003)
4 L. Qi, H. Colfen, and M. Antonietti, Nano Lett., 1, 61 (2001)
5 Y. Chen, X. Ji, S. Jiang, Q. Sun, and B. Jiang, Colloid Polym. Sci., 281, 386 (2003)
6 S. Forsterand M. Antonietti, Adv. Mater., 10, 195 (1998)
7 M. Morton and L. J. Fetters, Rubber Chem. Technol., 48, 359 (1975)   DOI   ScienceOn
8 R. P.Quirk and J. Kim, Macrornolecules, 24, 4515 (1991)
9 R. P. Quirk, T. Yoo, Y. Lee, J. Kim, and B. Lee , Adv. Polym. Sci., 153, 67 (2000)
10 T. Hirai, T. Watanabe, and I. Komasawa, J. Phys. Chem. B, 104,8962 (2000)
11 N. Herron, Y. Wang, and H. Eckert, J. Am. Chem. Soc., 112, 1322 (1990)
12 D. Diaz, M. Rivera, T. Ni, J.-C. Rodriguez, S.-E. Castillo-Blum, D. Nagesha, J. Robles, O.-J. Alvarez-Fregoso, and N. A. Kotov, J. Phys. Chem. B, 103, 9854 (1999)
13 P. V. Kamat and N. M. Dimitrijevic, J. Phys. Chem., 93, 4259 (1989)
14 N. Chestnoy, T. D. Harris, R. Hull, and L. E. Brus, J. Phys. Chem., 90, 3393 (1986)
15 C. B. Murray, D. J. Norris, and M. G. Bawendi, J. Am. Chem. Soc., 115, 2278 (1993)
16 Y. Wang, A. Suna, W. Mahler, and R. Kasowski, J. Chem. Phys., 87, 7315 (1987)
17 P. S. Nair, N. Revaprasadu, T. Radhakrishnan, and G. A. Kolawole, J. Mater. Chem., 11, 1555 (2001)
18 S.-Y. Lu, M. L. Wu, and H.-L. Chen, J. Appl. Phys., 93, 5789 (2003)
19 J. Kim, S. S. Kim, K. H. Kim, Y. H. Jin, S. M. Hong, S. S. Hwang, B.-G. Cho, D.-Y. Shin, and S. S. Im, Polyrner, 45, 3527 (2004)
20 K. Sooklal, L. H. Hanus, H. J. Ploehn, and C. J. Murphy, Adv. Mater., 10, 1083 (1998)
21 M. Moffitt, L. McMahon, V. Pessel, and A. Eisenberg, Chem. Mater., 7, 1185 (1995)
22 D. Hom and J. Rieger, Angew. Chem. Int. Ed., 40, 4330 (2001)
23 G. Carrot, S. M. Scholz, C. J. G. Plummer, J. G. Hilborn, and J. L. Hedrick, Chem. Mater., 11, 3595 (1999)
24 H. Wangand N. Herron, J. Phys. Chem., 92, 4988 (1988)
25 A. B. Lowe, B. S. Sumerlin, M. S. Donovan, and C. L. McConnick, J. Am. Chem. Soc., 124, 11562 (2002)
26 M. A. Kastner, Phys. Today, Jan., 24 (1993)
27 C. Lu, N. Wu, F. Wei, X. Zhao, X. Jiao, J. Xu, C. Luo, and W. Cao, Adv. Funct. Mater., 13, 548 (2003)
28 M. Moffitt and A. Eisenberg, Chem. Mater., 7, 1178 (1995)
29 K. C. Graber, R. G. Freeman, M. B. Hommer, and M. J. Natan, Anal. Chem., 67, 735 (1995)
30 M. Moffitt, H. Vali, and A. Eisenberg, Chem. Mater., 10, 1021 (1998)
31 T. Teranishi, I. Kiyokawa, and M. Miyake, Adv. Mater., 10, 596 (1998)
32 S. Stoeva, K. J. Klabunde, C. M. Sorensen, and I. Dragieva, J. Am. Chem. Soc., 124, 2305 (2002)
33 K. L. Kelly, E. Coronado, L. L. Zhao, and G. C Schatz, J. Phys. Chem. B, 107, 668 (2003)
34 M. K. Corbierre, N. S. Cameron, M. Sutton, S. G. J. Mochrie, L. B. Lurio, A. Ruhm, and R. B. Lennox, J. Am. Chem. Soc., 123, 10411 (2001)
35 S. Guo, L. Konopny, R. Popovitz-Biro, H. Cohen, H. Porteanu, E. Lifshitz, and M. Lahav, J. Am. Chem. Soc., 121, 9589 (1999)
36 A. C. Templeton, W. P. Wuelfing, and R. W. Murray, Acc. Chem. Res., 33, 27 (2000)
37 C. M. Niemeyer, Angew. Chem. Int. Ed., 40, 4128 (2001)