Macromolecular Research

The Polymer Society of Korea (한국고분자학회)
권호 표지

Synthesis and Characterization of ${\omega}-Sulfonated$ Polystyrene-stabilized Cadmium Sulfide Nanoclusters

  • Jin Yong Hyun (Polymer Hybrids Center, Korea Institute of Science and Technology) ;
  • Kim Jungahn (Polymer Hybrids Center, Korea Institute of Science and Technology) ;
  • Im Seung Soon (Department of Textile Engineering, Hanyang University)
  • Published : 2004.12.01
Download PDF
⟨ Previous Next ⟩

Abstract

We report an important and useful method for preparing ${\omega}-sulfonated$ polystyrene-stabilized cadmium sulfide (CdS) nanoclusters. The ${\omega}-sulfonated$ polystyrene $(M_n\;=\;5000\;g/mol)$ was prepared successfully through chain-end sulfonation of poly(styryl)lithium using 1,3-propanesultone; the resulting polymer was used successfully as a polymeric stabilizing agent for the preparation of semiconductor CdS nanoclusters by reduction of cadmium acetate in a mixture of toluene and methanol (9:1, v/v). The nanoclusters that formed were characterized by a combination of transmission electron microscopy, X-ray diffraction, and UVN is spectroscopic analysis. The ${\omega}-sulfonated$ polystyrene-stabilized CdS nanoclusters synthesized in this study exhibited the cubic phase (zinc-blende phase) structure in the range of 2-8 nm.

Keywords

References

  1. M. A. Kastner, Phys. Today, Jan., 24 (1993)
  2. D. Hom and J. Rieger, Angew. Chem. Int. Ed., 40, 4330 (2001)
  3. K. L. Kelly, E. Coronado, L. L. Zhao, and G. C Schatz, J. Phys. Chem. B, 107, 668 (2003)
  4. C. M. Niemeyer, Angew. Chem. Int. Ed., 40, 4128 (2001)
  5. S. Forster and T. Plantenberg, Angew. Chem. Int. Ed., 41, 688 (2002)
  6. W. J. Parak, D. Gerion, T. Pellegrino, D. Zanchet, C. Micheel, S. C. Williams, R. Boudreau, M. A. Le Gros, C. A. Larabell, and A. P. Alivisatos, Nanotechnology 14, R15 (2003)
  7. T. Teranishi, I. Kiyokawa, and M. Miyake, Adv. Mater., 10, 596 (1998)
  8. M. K. Corbierre, N. S. Cameron, M. Sutton, S. G. J. Mochrie, L. B. Lurio, A. Ruhm, and R. B. Lennox, J. Am. Chem. Soc., 123, 10411 (2001)
  9. A. B. Lowe, B. S. Sumerlin, M. S. Donovan, and C. L. McConnick, J. Am. Chem. Soc., 124, 11562 (2002)
  10. K. C. Graber, R. G. Freeman, M. B. Hommer, and M. J. Natan, Anal. Chem., 67, 735 (1995)
  11. A. C. Templeton, W. P. Wuelfing, and R. W. Murray, Acc. Chem. Res., 33, 27 (2000)
  12. S. Stoeva, K. J. Klabunde, C. M. Sorensen, and I. Dragieva, J. Am. Chem. Soc., 124, 2305 (2002)
  13. R. S. Tanke, S. M. Kauzlarich, T. E. Patten, K. A. Pettigrew, D. L. Murphy, M. E. Thompson, and H. W. H. Lee, Chem. Mater., 15, 1682 (2003)
  14. J. Kim, S. S. Kim, K. H. Kim, Y. H. Jin, S. M. Hong, S. S. Hwang, B.-G. Cho, D.-Y. Shin, and S. S. Im, Polyrner, 45, 3527 (2004)
  15. C. Lu, N. Wu, F. Wei, X. Zhao, X. Jiao, J. Xu, C. Luo, and W. Cao, Adv. Funct. Mater., 13, 548 (2003)
  16. S. Guo, L. Konopny, R. Popovitz-Biro, H. Cohen, H. Porteanu, E. Lifshitz, and M. Lahav, J. Am. Chem. Soc., 121, 9589 (1999)
  17. L. Qi, H. Colfen, and M. Antonietti, Nano Lett., 1, 61 (2001)
  18. M. Moffitt, H. Vali, and A. Eisenberg, Chem. Mater., 10, 1021 (1998)
  19. Y. Chen, X. Ji, S. Jiang, Q. Sun, and B. Jiang, Colloid Polym. Sci., 281, 386 (2003)
  20. S. Forsterand M. Antonietti, Adv. Mater., 10, 195 (1998)
  21. M. Morton and L. J. Fetters, Rubber Chem. Technol., 48, 359 (1975) https://doi.org/10.5254/1.3547458
  22. R. P.Quirk and J. Kim, Macrornolecules, 24, 4515 (1991)
  23. R. P. Quirk, T. Yoo, Y. Lee, J. Kim, and B. Lee , Adv. Polym. Sci., 153, 67 (2000)
  24. T. Hirai, T. Watanabe, and I. Komasawa, J. Phys. Chem. B, 104,8962 (2000)
  25. S.-Y. Lu, M. L. Wu, and H.-L. Chen, J. Appl. Phys., 93, 5789 (2003)
  26. N. Herron, Y. Wang, and H. Eckert, J. Am. Chem. Soc., 112, 1322 (1990)
  27. D. Diaz, M. Rivera, T. Ni, J.-C. Rodriguez, S.-E. Castillo-Blum, D. Nagesha, J. Robles, O.-J. Alvarez-Fregoso, and N. A. Kotov, J. Phys. Chem. B, 103, 9854 (1999)
  28. K. Sooklal, L. H. Hanus, H. J. Ploehn, and C. J. Murphy, Adv. Mater., 10, 1083 (1998)
  29. G. Carrot, S. M. Scholz, C. J. G. Plummer, J. G. Hilborn, and J. L. Hedrick, Chem. Mater., 11, 3595 (1999)
  30. H. Wangand N. Herron, J. Phys. Chem., 92, 4988 (1988)
  31. P. V. Kamat and N. M. Dimitrijevic, J. Phys. Chem., 93, 4259 (1989)
  32. P. S. Nair, N. Revaprasadu, T. Radhakrishnan, and G. A. Kolawole, J. Mater. Chem., 11, 1555 (2001)
  33. N. Chestnoy, T. D. Harris, R. Hull, and L. E. Brus, J. Phys. Chem., 90, 3393 (1986)
  34. M. Moffitt and A. Eisenberg, Chem. Mater., 7, 1178 (1995)
  35. C. B. Murray, D. J. Norris, and M. G. Bawendi, J. Am. Chem. Soc., 115, 2278 (1993)
  36. M. Moffitt, L. McMahon, V. Pessel, and A. Eisenberg, Chem. Mater., 7, 1185 (1995)
  37. Y. Wang, A. Suna, W. Mahler, and R. Kasowski, J. Chem. Phys., 87, 7315 (1987)