• Title/Summary/Keyword: Spinning process

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The Effect of Misch Metal Addition on the Microstructure and Mechanical Property of Rapidly Solidified AZ91 Alloy (급속응고한 AZ91 합금의 미세조직 및 기계적 특성에 미치는 Misch metal 첨가의 영향)

  • Eum, Seung-Yeul;Park, Hoon-Mo;Nam, Tae-Woon
    • Journal of Korea Foundry Society
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    • v.20 no.1
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    • pp.29-37
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    • 2000
  • The purpose of this study is to investigate the effect of misch metal addition on the microstructure and mechanical property of rapidly solidified AZ91 alloy by melt spinning process. As the contents of misch metal(rare earth element:Ce,La, Nd, Pr)was increased, the microstructure of RS ribbons and extrudates became finer than those of AZ91, and RE related phases($Al_{11}RE_3$, $Al_2RE$) were formed. At room temperature, the rapidly solidified AZ91+1 wt%Mm alloy showed the highest tensile strength, 430 MPa due to precipitation strengthening of${\beta}(Mg_{17}Al_{12})$ phase and Al11RE3 phase. At the elevated temperature, the mechanical property of AZ01+3 wt%Mm alloy was higher than those of other Mg alloys. The reasons were that $Al_{11}La_3$ phase was thermally stable and suppressed the grain growth. In contrast with $Al_{11}La_3$ phase, ${\beta}$ phase was thermally unstable and could not suppress the grain growth at the elevated temperature. Therefore, Al11RE3 phase contributed to improve the thermal stability of RS AZ91 Alloy.

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Daily Unit Commitment Scheduling of Power System with Energy Storage System (전력저장장치를 고려한 일간 최적 기동정지계획 수립연구)

  • Song, Ha-Na;Jang, Se-Hwan;Kim, Hyeong-Jung;Roh, Jae-Hyung;Park, Jong-Bae
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.4
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    • pp.717-725
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    • 2011
  • In the power system with an electric storage system that can increase utilization rate of the source of such new renewable energy, this paper introduces the approach on the daily unit commitment scheduling that determines simultaneously optimum operational condition and output of thermal generators and electric storage device. The unit commitment is one of the most important issues in economic operation and security of short-term operational plan of the power system. It is to determine on/off status of generator to minimize operational cost during the given period. The committed generator should satisfy various operational limitation such as estimated demand by system, spinning reserve condition within minimum operational cost. In order to determine on/off or charge/discharge/idle condition and output level of units and electric storage system, the MILP(Mixed Integer Linear Programming) is suggested. The proposed approach is the mixed method between LP(Linear Programming) and IP(integer programming) which seeks the value of real number and integer that maximize or minimize function objective within given condition. The daily unit commitment problem with the electric storage system is applied to MILP algorithm through linearization and formulation process. The proposed approach is applied to the test system.

Surface Hydrolysis of Fibrous Poly(${\epsilon}$-caprolactone) Scaffolds for Enhanced Osteoblast Adhesion and Proliferation

  • Park, Jeong-Soo;Kim, Jung-Man;Lee, Sung-Jun;Lee, Se-Geun;Jeong, Young-Keun;Kim, Sung-Eun;Lee, Sang-Cheon
    • Macromolecular Research
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    • v.15 no.5
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    • pp.424-429
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    • 2007
  • A procedure for the surface hydrolysis of an electrospun poly(${\epsilon}$-caprolactone) (PCL) fibrous scaffold was developed to enhance the adhesion and proliferation of osteoblasts. The surface hydrolysis of fibrous scaffolds was performed using NaOH treatment for the formation of carboxyl groups on the fiber surfaces. The hydrolysis process did not induce deformation of the fibers, and the fibers retained their diameter. The cell seeding density on the NaOH-treated PCL fibrous scaffolds was more pronounced than on the non-treated PCL fibers used as a control. The alkaline phosphatase activity, osteocalcin and a mineralization assay strongly supported that the surface-hydrolyzed PCL fibrous scaffolds provided more favorable environments for the proliferation and functions of osteoblasts compared to the non-treated PCL fibrous scaffolds use as a control.

The Effect of Dissolution Condition on the Yield, Molecular Weight, and Wet- and Electro-spinnability of Regenerated Silk Fibroins Prepared by LiBr Aqueous Solution

  • Cho, Hee-Jung;Um, In-Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • v.20 no.2
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    • pp.99-105
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    • 2010
  • In this paper, the regenerated silk fibroins were dissolved in LiBr aqueous solution with different dissolution temperature and time, and the effects of the dissolution condition on the regeneration yield, molecular weight, wet spinnability, and electrospinnability of regenerated silk fibroin were investigated. The regeneration yield, molecular weight distribution, and wet spinnability of regenerated silk fibroin were nearly affected by the dissolution temperature and time. However, the electrospinning performance of silk fibroin was influenced by the dissolution condition implying the electrospinning of silk fibroin is more sensitive process than the wet spinning in the range tested in this study. While $25^{\circ}C$ of dissolution temperature resulted in a good electrospinnability of regenerated silk fibroin, the electrospinnability was slightly deteriorated when silk fibroin was dissolved at $60^{\circ}C$ for 6 hours. Also, though the fiber diameters of electrospun silk fibroin produced by the dissolution at $25^{\circ}C$ for 6 hours and 24 hours were 443 and 451 nm, respectively, that at $60^{\circ}C$ for 5 min was reduced to 411 nm. The fiber diameter was more decreased to 393 nm when the dissolution time increased up to 6 hours at $60^{\circ}C$.

Development of Pilot-Scale Manufacturing Process of SiC Fiber from Polycarbosilane Precursor with Excellent Mechanical Property at Highly Oxidation Condition and High Temperature (폴리카보실란 전구체로부터 고온 산화성분위기서 기계적물성이 우수한 파이롯-규모의 탄화규소섬유 제조공정 개발)

  • Yoon, B.I.;Choi, W.C.;Kim, J.I.;Kim, J.S.;Kang, H.G.;Kim, M.J.
    • Composites Research
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    • v.30 no.2
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    • pp.116-125
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    • 2017
  • The purpose of this study is to develop silicon carbide fiber showing an excellent mechanical properties under highly oxidative conditions at high temperature. Polycarbosilane(PCS) as a preceramic precursor was used for making the SiC fiber. PCS fiber was taken by melt spinning method followed by melting the PCS at $300{\sim}350^{\circ}C$ in N2 gas. The Curing of PCS fiber was carried out in air oxygen chamber, prior to high temperature pyrolysis. Degree of cure was calculated by characteristic peak's ratio of Si-H to $Si-CH_3$ in FT-IR spectra before and after curing of PCS fiber. The properties of SiC fiber was affected greatly by the degree of cure. The SiC fiber produced by controlling fiber tension during heat treatment showed good properties. The SiC fiber exposed to $1000^{\circ}C$ at air from 1 min. up to maximum 50 hrs showed around 60% reduction in tensile strength. We found that large amount of carbon content on the fiber surface after long-term exposure has resulted in lower tensile strength.

Evaluation of the Effect of Flocculator Rotation Direction in Floccualation Basin on Hydrodynamic Behavior using CFD (CFD를 이용한 플록큐레이터 회전방향에 따른 플록형성지 유동 평가)

  • Cho, Young-Man;Yoo, Soo-Jeon;Roh, Jae-Soon;Kim, taek-Jun;Kim, Chang-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.5
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    • pp.364-370
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    • 2009
  • With time, the stable management of turbidity is becoming more important in the water treatment process. So optimization of flocculation is important for the improvement of the sedimentation efficiency. we evaluated the hydrodynamic behavior in the rotation direction (clock-wise, counterclock-wise) of the flocculator in the flocculation basin using Computational Fluid Dynamics (CFD). The results of the CFD simulation, in cases where flocculators rotate in a clockwise direction, a stronger flow is formed near the surface of the water where the rotating direction and current of flow correspond. The variance and standard deviation of the flux are about 8.5 and 2.9 respectively. In contrast, in the case of a counterclockwise direction, a stronger flow is formed near the bottom of the basin. The variance and standard deviation of the flux are about 5.3 and 2.3, respectively. The effluent flux is affected more by the third flocculator spin than the first and second flocculator spins. The third flocculator spinning in the counterclockwise direction is better for the uniform flow of the sedimentation basin than the third flocculator spinning in the clockwise direction

Fine Structural Study on the Capture Thread-Producing Organs in Nephila clavata L.Kocn (Aranese: Araneidae) I. Aggregate Gladns (무당거미(Nephila clavata L.Koch) 포획사 생성기관의 미세구조에 관한 연구 I. 수상선)

  • 문명진;김우갑
    • The Korean Journal of Zoology
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    • v.32 no.3
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    • pp.211-220
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    • 1989
  • The fine structure of the aggregate glands-one of the capture thread producing organs-in the orb web spider, Nephila clavata L.Koch, is studied with light and electron microscopes. Gluey capture threads or sticky spirals of the orb web are originated from the silks of two flagelliform glands and four aggregate glands which are connected to the posterior spinnerets, and the arrangement fo their spigots(large spinning tubes) shows a charaterstic form called "triad". The aggregate galnd is composed of large and multilobed secretory portion and thick excretory duct surrounded by large irregular nodules. The excretory duct of the aggregate galnds basically consists of three superposed types of cells which are inner columnar epithelium, nodule-forming cells and outer connestives. The cuticles of the proximal duct near the secretory portion are composed of endocuticle and exocuticle, whereas ghe distal duct near the spinning tubes has a electron lucent subcuticle which had the functions of water removal and orientation of silk fibers. In the cytoplasmic process of the large and irregular nodule-forming cells surrounded by invaginations of the plasma membranes, numerous mitochondria and glycogen particles are contained. The maturational level of the nodule cells is perceived from the appearence of these cell inclusions. The secretory portion of the glands which porduce the secretory silk material shows two layers of the cells which are simple cuboidal epithelium and several connective layers. In the cytoplasm of the glandular epithelial cell, rough endoplasmic reticulums are well developed, and two types of secretory granules are observed. Between the adjacent epithelial cells, specialized septate junctions are formed along the plasma membranes.membranes.

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Preparation of Asymmetric Folyethersulfone Hollow Fiber Membranes for Flue Gas Separation (온실기체 분리용 폴리이서설폰 비대칭 중공사 막의 제조)

  • Kim Jeong-Hoon;Sohn Woo-Ik;Choi Seung-Hak;Lee Soo-Bok
    • Membrane Journal
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    • v.15 no.2
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    • pp.147-156
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    • 2005
  • It is well-known that polyethersulfone (PES) has high $CO_2$ selectivity over $N_2\;(or\;CH_4)$ and excellent pressure resistance of $CO_2$ plasticization among muy commercialized engineering plastics[1-4]. Asymmetric PES hollow fiber membranes for flue gas separation were developed by dry-wet spinning technique. The dope solution consists of PES, NMP and acetone. Water and water/NMP mixtures are used in outer and inner coagulants, respectively. Gas permeation rate (i.e., permeance) and $CO_2/N_2$ selectivity were measured with pure gas, respectively and the micro-structure of hollow fiber membranes was characterized by scanning electron microscopy. The effects of polymer concentration, ratio of NMP to acetone, length of air gap, evaporation condition and silicone coating were investigated on the $CO_2/N_2$ separation properties of the hollow fibers. Optimized PES hollow fiber membranes exhibited high permeance of $25\~50$ GPU and $CO_2/N_2$ selectivity of $30\~40$ at room temperature and have the apparent skin layer thickness of about $0.1\;{\mu}m$. The developed PES hollow fiber membranes, would be a good candidate suitable for the flue gas separation process.

Polymeric Membrane Modules for Substituting the $CO_2$ Absorption Column in the DME Plant Process (DME 플랜트 $CO_2$흡수탑 대체용 고분자 분리막 모듈)

  • Chung, Jong-Tae;Lee, Choong-Seop;Koh, Hyung-Chul;Ha, Seong-Yong;Nam, Sang-Yong;Jo, Won-Jun;Baek, Young-Soon
    • Membrane Journal
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    • v.22 no.2
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    • pp.142-154
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    • 2012
  • In order to remove $CO_2$ from the DME plant process, we investigated the composite membrane with rubbery polymers as the separation layer and its separation performance of $CO_2$ and $H_2$. Hollow fiber membranes for supporting layer were prepared by solution spinning method. In case of using PDMS as a separation layer, the composite membranes showed the permeation rates of $CO_2$ were over 300 GPU and minimum $CO_2/H_2$ selectivitties were 4.3 and in case of using PEBAX as a separation layer, the composite membranes showed the permeation rates of $CO_2$ were over 120 GPU and minimum $CO_2/H_2$ selectivities were 5.

Preparation and Characterization of NiZn-Ferrite Nanofibers Fabricated by Electrospinning Process (전기방사법에 의한 NiZn 페라이트 나노섬유의 제조 및 특성 연구)

  • Joo, Yong-Hui;Nam, Joong-Hee;Cho, Jeong-Ho;Chun, Myoung-Pyo;Kim, Byung-Ik;Ko, Tae-Gyung
    • Journal of the Korean Ceramic Society
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    • v.46 no.1
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    • pp.74-80
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    • 2009
  • Electrospinning process is the useful and unique method to produce nanofibers from metal precursor and polymer solution by controlled viscosity. In this study, the NiZn ferrite nanofibers were prepared by electrospinning with a aqueous metal salts/polymer solution that contained polyvinyl pyrrolidone and Fe (III) chloride, Ni (II) acetate tetrahydrate and zinc acetate dihydrate in N,N-dimethylformamide. The applied electric field and spurting rate for spinning conditions were 10 kV, 2 ml/h, respectively. The obtained fibers were treated at $250^{\circ}C$ for 1 h to remove the polymer. Finally, the NiZn ferrite fibers were calcined at $600^{\circ}C$ for 3 h and annealed at $900{\sim}1200^{\circ}C$ in air. By tuning the viscosity of batch solution before electrospinning, we were able to control the microstructure of NiZn ferrite fiber in the range of $150{\sim}500\;nm$ at 770 cP. The primary particle size in $600^{\circ}C$ calcined ferrite fiber was about 10 nm. The properties of those NiZn ferrite fibers were determined from X-ray diffraction analysis, electron microscopy, energy dispersive spectroscopy, Fourier transform infrared spectroscopy, thermal analysis, and magnetic measurement.