• Title/Summary/Keyword: Spin-on method

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The Crystallinity and Electrical Properties of SrBi2Ta2O9 Thin Films Fabricated by New Low Temperature Annealing (새로운 저온 열처리 공정으로 제조된 SrBi2Ta2O9 박막의 결정성 및 전기적 특성)

  • Lee, Kwan;Choi, Hoon-Sang;Jang, Yu-Min;Choi, In-Hoon
    • Korean Journal of Materials Research
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    • v.12 no.5
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    • pp.382-386
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    • 2002
  • We studied growth and characterization of $SrBi_2Ta_2O_9$ (SBT) thin films fabricated by low temperature process under vacuum and/or oxygen ambient. A metal organic decomposition (MOD) method based on a spin-on technique and annealing process using a rapid thermal annealing (RTA) method was used to prepare the SBT films. The crystallinity of a ferroelectric phase of SBT thin films is related to the oxygen partial pressure during RTA process. Under an oxygen partial pressure higher than 30 Torr, the crystallization temperature inducing the ferroelectric SBT phase can be lowered to $650^{\circ}C$. Those films annealed at $650^{\circ}C$ in vacuum and oxygen ambient showed good ferroelectric properties, that is, the memory window of 0.5~0.9 V at applied voltage of 3~7 V and the leakage current density of 1.80{\times}10^{-8}$ A/$\textrm{cm}^2$ at an applied voltage of 5V. In comparison with the SBT thin films prepared at 80$0^{\circ}C$ in $O_2$ ambient by furnace annealing process, the SBT thin films prepared at $650^{\circ}C$ in vacuum and oxygen ambient using the RTA process showed a good crystallization and electrical properties which would be able to apply to the virtul device fabrication precess.

The study on the military utilization of weather modification techniques and inducing their research priority (기상조절기술의 군사적 활용방안과 연구 우선순위 도출에 관한 연구)

  • Han, Seung Jo;Shin, Jin
    • Convergence Security Journal
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    • v.18 no.2
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    • pp.77-88
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    • 2018
  • The purposes of this paper are to research the military utilization of weather modification techniques and to induce their research priority when considering the Korean Peninsular environment and technical level. To achieve these goals, the advantages and disadvantages of weather modification technologies have been discussed, and the evaluation index evaluation was derived through the Delphi method, and the weight of the evaluation index and the final research priority were induced through analytic hierarchical process. Analysis shows that the ionospheric modulation technology has the highest priority in terms of effectiveness as a weapon system and compatibility in the Korean Peninsula environment. It is expected that Korean ionosphere modification can disturb C4ISR function of the enemy and guarantee ours reliably when operating PGM, military satellite, surveillance & reconnaissance equipments, etc. Other weather modification technologies except for ionosphere modification should be developed gradually in that potential threat can be expanded to neighboring countries after the Unification of the Korea.

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The Structural and Optical Properties with Composition Variation of CdxZn1-xO Thin Films Prepared by Sol-Gel Method (Sol-Gel 방법으로 제작된 CdxZn1-xO 박막의 조성비에 따른 구조적 및 광학적 특성)

  • Cheon, Min Jong;Kim, Soaram;Nam, Giwoong;Yim, Kwang Gug;Kim, Min Su;Leem, Jae-Young
    • Korean Journal of Metals and Materials
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    • v.49 no.7
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    • pp.583-588
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    • 2011
  • $Cd_xZn_{1-x}O$ thin films were grown on quartz substrates by using the sol-gel spin-coating method. The mole fraction, x, of the $Cd_xZn_{1-x}O$ thin films was controlled from 0 to 1 by changes in the content ratio of the cadmium acetate dehydrate [$Cd{(CH_3COO)}_2{\cdot}2H_2O$] and zinc acetate dehydrate [$Zn{(CH_3COO)}_2{\cdot}2H_2O$]. The effects of the mole fraction on the morphological, structural, and optical properties of the $Cd_xZn_{1-x}O$ thin films were investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), and UV-visible spectroscopy. The $Cd_xZn_{1-x}O$ thin films exhibited the polygonal surface morphology and their grain size was increased ranging from 42.1 to 63.9 nm with the increase in the mole fraction. It was observed that the absorption bandgap of the $Cd_xZn_{1-x}O$ thin films decreased from 3.25 to 2.16 eV as the mole fraction increased and the Urbach energy ($E_U$) values changed inversely to the optical bandgap of the $Cd_xZn_{1-x}O$ thin films.

Magnetic Properties of Cr-Doped Inverse Spinel Fe3O4 Thin Films (Cr 치환된 역스피넬 Fe3O4 박막의 자기적 특성)

  • Lee, Hee-Jung;Choi, Seung-Li;Lee, Jung-Han;Kim, Kwang-Joo;Choi, Dong-Hyeok;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.17 no.2
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    • pp.51-54
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    • 2007
  • By substituting Cr in inverse-spinel $Fe_3O_4,\;Cr_xFe_{3-x}O_4$ thin film samples were prepared by sol-gel spin-coating method and their structural electronic, and magnetic properties were analyzed. X-ray diffraction indicates that the lattice constant decrease with increasing Cr composition (x). This result can be explained in terms of occupation of octahedral sites by $Cr^{3+}$ ions with smaller ionic radius than that of $Fe^{3+}$ Vibrating sample magnetometry measurements on the samples at room temperature revealed that saturation magnetization ($M_s$) decrease by Cr substitution, explainable by comparing spin magnetic moment among the related transition-metal ions. A decrease of magnetoresistence effect with x was observed, similar to that of $M_s$. The coercivity of the $Cr_xFe_{3-x}O_4$ films was found to increase with x, attributed to the increase of magnetic anisotropy by the existence of octahedral $Cr^{3+}(d^3)$.

Magnetic Properties of Cr Substituted SiTe Compounds (SiTe에 Cr을 치환한 화합물의 자기적 성질)

  • Landge, Kalpana;Bialek, Beata;Lee, Jae-Il
    • Journal of the Korean Magnetics Society
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    • v.21 no.4
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    • pp.127-131
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    • 2011
  • In this paper, we study the electronic and magnetic properties of Cr substituted SiTe in the rock-salt structure compound using the full potential linearized augmented plane wave method within the generalized gradient approximation to the exchange correlation potential. Two stoichiometries are studied: $CrSi_3Te_4$ with 25 %, and $CrSiTe_2$ with 50 % Cr substitution. We found, from the total energy calculations, that the equilibrium lattice constant for cubic $CrSi_3Te_4$ is 11.64 a.u. and a = 7.89 a.u. and c = 11.13 a.u. for tetragonal $CrSiTe_2$. The integer value of the calculated magnetic moment per unit cell, $4{\mu}_B$ for $CrSiTe_2$ suggests that this compound is halfmetallic. The magnetic moment per unit cell for $CrSi_3Te_4$ is slightly larger than $4{\mu}_B$. The magnetic moment on Cr atoms are 3.61 and $3.62{\mu}_B$ in the $CrSi_3Te_4$ and $CrSiTe_2$, respectively. The presence of Cr atoms causes that the other atoms become slightly magnetized in both compounds. The electronic properties and the magnetism are discussed with the calculated spin-polarized density of states.

Half-metallicity and Magnetism of Co2ZrSi/ZnTe(001) Interface: A First-principles Study (Co2ZrSi/ZnTe(001)계면의 자성과 반쪽금속성에 대한 제일원리 연구)

  • Jin, Y.J.;Lee, J.I.
    • Journal of the Korean Magnetics Society
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    • v.17 no.4
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    • pp.147-151
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    • 2007
  • We have investigated the half-metallicity and magnetism for the Heusler ferromagnet $Co_2$ZrSi interfaced with semiconductor ZnTe along the (001) plane by using the full-potential linearized augmented plane wave (FLAPW) method. We considered low types of possible interfaces: ZrSi/Zn, ZrSi/Te, Co/Zn, and Co/Te, respectively. From the calculated density of states, it was found that the half-metallicity was lost at all the interfaces, however for the Co/Te system the value of minority spin density of states was close to zero at the Fermi level. These facts are due to the interface states, appeared in the minority spin gap in bulk $Co_2$ZrSi, caused by the changes of the coordination and symmetry and the hybridizations between the interface atoms. At the Co/Te interface, the magnetic moments of Co atoms are 0.68 and $0.78{\mu}_B$ for the "bridge" and "antibridge" sites, respectively, which are much reduced with respect to that ($1.15{\mu}_B$) of the bulk $Co_2$ZrSi. In the case of Co/Zn, Co atoms at the "bridge" and "antibridge" sites have magnetic moments of 1.16 and $0.93{\mu}_B$, respectively, which are almost same or slightly decreased compared to that of the bulk $Co_2$ZrSi. On the other hand, for the ZrSi/Zn and ZrSi/Te systems, the magnetic moments of Co atoms at the sub-interface layers are in the range of $1.13{\sim}1.30\;{\mu}_B$, which are almost same or slightly increased than that of the bulk $Co_2$ZrSi.

Growth and Optical Conductivity Properties for BaAl2Se4 Single Crystal Thin Film by Hot Wall Epitaxy (Hot Wall Epitaxy(HWE)법에 의한 BaAl2Se4 단결정 박막 성장과 광전도 특성)

  • Jeong, Junwoo;Lee, Kijung;Hong, Kwangjoon
    • Journal of Sensor Science and Technology
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    • v.24 no.6
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    • pp.404-411
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    • 2015
  • A stoichiometric mixture of evaporating materials for $BaAl_2Se_4$ single crystal thin films was prepared from horizontal electric furnace. To obtain the single crystal thin films, $BaAl_2Se_4$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the Hot Wall Epitaxy (HWE) system. The source and substrate temperatures were $610^{\circ}C$ and $410^{\circ}C$, respectively. The crystalline structure of the single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction (DCXD). The carrier density and mobility of $BaAl_2Se_4$ single crystal thin films measured from Hall effect by van der Pauw method are $8.29{\times}10^{-16}cm^{-3}$ and $278cm^2/vs$ at 293 K, respectively. The temperature dependence of the energy band gap of the $BaAl_2Se_4$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g(T)=3.4205eV-(4.3112{\times}10^{-4}eV/K)T^2/(T+232 K)$. The crystal field and the spin-orbit splitting energies for the valence band of the $BaAl_2Se_4$ have been estimated to be 249.4 meV and 263.4 meV, respectively, by means of the photocurrent spectra and the Hopfield quasicubic model. These results indicate that the splitting of the ${\Delta}so$ definitely exists in the ${\Gamma}_5$ states of the valence band of the $BaAl_2Se_4/GaAs$ epilayer. The three photocurrent peaks observed at 10 K are ascribed to the $A_1$-, $B_1$-exciton for n =1 and $C_{31}$-exciton peaks for n=31.

Development of Fire Detection Model for Underground Utility Facilities Using Deep Learning : Training Data Supplement and Bias Optimization (딥러닝 기반 지하공동구 화재 탐지 모델 개발 : 학습데이터 보강 및 편향 최적화)

  • Kim, Jeongsoo;Lee, Chan-Woo;Park, Seung-Hwa;Lee, Jong-Hyun;Hong, Chang-Hee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.12
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    • pp.320-330
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    • 2020
  • Fire is difficult to achieve good performance in image detection using deep learning because of its high irregularity. In particular, there is little data on fire detection in underground utility facilities, which have poor light conditions and many objects similar to fire. These make fire detection challenging and cause low performance of deep learning models. Therefore, this study proposed a fire detection model using deep learning and estimated the performance of the model. The proposed model was designed using a combination of a basic convolutional neural network, Inception block of GoogleNet, and Skip connection of ResNet to optimize the deep learning model for fire detection under underground utility facilities. In addition, a training technique for the model was proposed. To examine the effectiveness of the method, the trained model was applied to fire images, which included fire and non-fire (which can be misunderstood as a fire) objects under the underground facilities or similar conditions, and results were analyzed. Metrics, such as precision and recall from deep learning models of other studies, were compared with those of the proposed model to estimate the model performance qualitatively. The results showed that the proposed model has high precision and recall for fire detection under low light intensity and both low erroneous and missing detection capabilities for things similar to fire.

A Study on X-ray Radiography for the Diagnosis of Screw Insertion Operation of Odontoid Fracture Patients in Cervical (목뼈 치아돌기 골절 환자의 나사못 삽입수술 진단을 위한 X-Ray 촬영법 연구)

  • Byung-Ju-Ahn;In-Soo Kim;Jong-Nam Song;Jae-Bok Han
    • Journal of the Korean Society of Radiology
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    • v.18 no.3
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    • pp.309-315
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    • 2024
  • The Study In order to obtain a Clear Image of fractures in Atlas and Axis of Cervical Spin, this Study obtained Images examined using a Cervical Spin Pantom and a Radiation device, and then Commissioned five Radiologists and three Orthopedic Regent Doctors for Subjective Psychological ROC (Receiver, Operation, Characteristic) Evaluation. As aRresult, the X-ray Tube was Tilted 15° toward the leg to Receive a high score of 29 Points during the Eamination, and the Objective Evaluation Signal-to-noise Ratio (SNR) was 6.032 points, which was high. In Addition, by Tilting the X-ray tube 10° toward the head, it received a high score of 33 points during the Examination, and a high score of 7.840 Points in the objective evaluation. And as a result of Subjectively and Objectively Statistically Evaluating the Examined Images, the Cronbach Alpha value was Calculated as 0.791. Since the Cronbach Alpha value was 0.7 or higher, the Reliability could be Evaluated as 'very good', and the significance probability (p) was Statistically Significant at 0.042 points.

LC Orientation Characteristics of NLC on Polyimide Surface According to Ion-beam Irradiation Angles (이온빔 조사각도에 따른 네마틱 액정의 액정 배향 특성)

  • Lee, Kang-Min;Oh, Byeong-Yun;Park, Hong-Gyu;Lim, Ji-Hun;Lee, Won-Kyu;Na, Hyun-Jae;Kim, Byoung-Yong;Han, Jeong-Min;Lee, Sang-Keuk;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.329-329
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    • 2008
  • To date, rubbing has been widely used to align LC molecules uniformly. Although rubbing can be simple, it has fundamental problems such as the generation of defects by dust and static electricity, and difficulty in achieving a uniform LC alignment on a large substrate. Therefore, noncontact alignment has been investigated. Ion beam induced alignment method, which provides controllability, nonstop process, and high resolution display. In this study, we investigated liquid crystal (LC) alignment with ion beam (IB) that non contact alignment technique on polyimide and electro-optical characteristics of twisted nematic (TN)-liquid crystal display (LCD) on the poly imide under various ion beam angles. In this experiment, Polyimide layer was coated on glass by spin-coating and Voltage-transmittance(VT) and response time characteristics of the TN cell were measured by a LCD evaluation system. The good characteristics of the nematic liquid crystal (NLC) alignment with the ion beam exposure poly imide surface was observed. The tilt angle of NLC on the PI surface with ion beam exposure can be measured under $1^{\circ}4 for all of irradiation angles. In addition, it can be achieved the good ED properties, and residual DC property of the ion beam aligned TN cell on polyimide surface.

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