• Title/Summary/Keyword: Solid solutions

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Solid-liquid 2phase flow in a concentric annulus with rotation of the inner cylinder (안쪽축이 회전하는 동심환형관내 고-액 2상 유동연구)

  • Kim, Young-Ju;Han, Sang-Mok;Woo, Nam-Sub;Hwang, Young-Kyu
    • Journal of Energy Engineering
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    • v.18 no.2
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    • pp.87-92
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    • 2009
  • An experimental investigation is conducted to study a 2-phase vertically upward hydraulic transport of solid particles by water and non-Newtonian fluids in a slim hole concentric annulus with rotation of the inner cylinder. Rheology of particulate suspensions in viscoelastic fluids is of importance in many applications such as particle removal from surfaces, transport of proppants in fractured reservoir and cleaning of drilling holes, etc. In this study, a clear acrylic pipe was used in order to observe the movement of solid particles. Annular velocities varied from 0.3 m/s to 2.0 m/s. The mud systems included fresh water and CMC solutions. Main parameters considered in the study were inner-pipe rotation speed, fluid flow regime and particle injection rate. A particle rising velocity and pressure drop in annulus have been measured for fully developed flows of water and of aqueous solutions. For both water and 0.2% CMC solutions, the higher the concentration of the solid particles is, the larger the pressure gradients become.

Microstructural Characterization and Dielectric Properties of Barium Titanate Solid Solutions with Donor Dopants

  • Kim, Yeon-Jung;Hyun, June-Won;Kim, Hee-Soo;Lee, Joo-Ho;Yun, Mi-Young;Noh, S.J.;Ahn, Yong-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.30 no.6
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    • pp.1267-1273
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    • 2009
  • The correlation between the sintering temperature and dielectric properties in the $Nb^{5+}\;and\;Ta^{5+}$ doped BaTi$O_3$ solid solutions have been investigated. The samples were sintered at temperatures ranging from 1250 to 1350 ${^{\circ}C}$ for 4 h in air. SEM, XRD and SEM/EDS techniques were used to examine the structure of the samples with particular focus on the incorporation of $Nb^{5+}\;and\;Ta^{5+}$ ions into the BaTi$O_3$ crystal lattice. The X-ray diffraction peaks of (111), (200) and (002) planes of BaTi$O_3$ solid solution doped with different fractions of $Nb^{5+}\;and\;Ta^{5+}$ were investigated. The dielectric properties were analyzed and the relationship between the properties and structure of doped BaTi$O_3$ was established. The fine-grain and high density of the doped BaTi$O_3$ ceramics resulted in excellent dielectric properties. The dielectric properties of this solid solutions were improved by adding a small amount of dopants. The transition temperature of the 1.0 mole% $Ta^{5+}$ doped BaTi$O_3$ solid solution was $\sim$110 ${^{\circ}C}$ with a dielectric constant of 3000 at room temperature. At temperatures above the Curie temperatures, the dielectric constant followed the Curie-Weiss law.

Structure and Elastic Properties of (Nb1-xTax)C, (Nb1-xHfx)C, Ultra-High Temperature Solid Solution Ceramics using the First Principles Calculation (제1원리계산을 이용한 (Nb1-xTax)C, (Nb1-xHfx)C 초고온 세라믹 고용체의 구조 및 탄성특성)

  • Kim, Myungjae;Kim, Jiwoo;Kim, Jiwoong;Kim, Kyung-Nam
    • Korean Journal of Materials Research
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    • v.31 no.12
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    • pp.682-689
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    • 2021
  • NbC, HfC, TaC, and their solid solution ceramics have been identified as the best materials for ultrahigh-temperature ceramics. However, their structural stability and elastic properties are mostly unclear. Thus, we investigated structure and elastic properties of (Nb1-xTax)C and (Nb1-xHfx)C solid solutions via ab initio calculations. Our calculated results show that the stability of (Nb1-xTax)C and (Nb1-xHfx)C increases with the increase of Hf and Ta content, and (Nb1-xHfx)C is more stable than (Nb1-xTax)C at the same content of Hf and Ta. The lattice constants decrease with increasing of Hf and Ta content. (Nb1-xTax)C and (Nb1-xHfx)C carbides are mechanically stable and brittle. Bulk modulus of (Nb1-xTax)C increases with increasing Ta content. In contrast, bulk modulus of (Nb1-xHfx)C decreases with increasing Hf content. Hardness of solid solutions shows the highest values at the (Nb0.25Ta0.75)C and (Nb0.75Hf0.25)C. In particular, (Nb0.75Hf0.25)C shows the highest hardness for the current system. The results indicate that the overall mechanical properties of (Nb1-xHfx)C solid solutions are superior to those of (Nb1-xTax)C solid solutions. Therefore, controlling the Hf and Ta element and content of the (Nb1-xTax)C and (Nb1-xHfx)C Solid solution is crucial for optimizing the material properties.

Preparation of Highly Concentrated Alumina Suspension through Investigstion of Proton Adsorption Density (수소이온 흡착밀도의 고찰을 통한 고농도 알루미나 현탁액의 제조)

  • Kim, Duk-Jun;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.33 no.2
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    • pp.163-168
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    • 1996
  • Measurements of proton adsorption density have been conducted in preparing alumina suspensions with aqueous solutions of HCL, HNO3, H2SO4 and H3PO4 And effects of anion acid concentration proton adsorption density and solid loading on the viscosity of the alumina suspensions have been investigated. Aqueous solutions of HCl. or HNO3 were suitable for the preparation of highly concentrated suspensions as the generation of surface charge on alumina particles was depressed by the specific adsorption of {{{{ {SO }`_{4 } ^{2- } }} and {{{{ { PO}`_{4 } ^{3- } }} Optimum conditions for maximizing solid loading were dependent upon proton adsorption density and acid concentration.

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Ionic Conductivity of Solid Solution Ceramics in The System of Stabilized ZrO2 Prepared by Self-Propagating High-Temperature Synthesis

  • Soh, Deawha;Korobova, N.
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.4
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    • pp.349-355
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    • 2002
  • The ionic conductivity of cubic solid solutions in the systems of CaO-$ZrO_2$, $Y_2O_3-ZrO_2$ prepared by SHS was examined. The higher conductivity appears to be related to a lower activation energy rather than to the number of oxygen vacancies dictated by composition. Conductivity-temperature data was obtained at 1000 $^{\circ}C$ in atmosphere of low oxygen partial pressure (~$10^{-40}$ atm) for $Y_2O_3-ZrO_2$ cubic solid solutions. The data indicated that these materials could be reduced, and the decree of reduction would be related with the measuring electric field.

Interactions in a homogeneous isotropic modified couple stress thermoelastic solid with multi-dual-phase-lag heat transfer and two temperature

  • Lata, Parveen;Kaur, Harpreet
    • Steel and Composite Structures
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    • v.38 no.2
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    • pp.213-221
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    • 2021
  • The objective of this paper is to study the deformation in a homogeneous isotropic thermoelastic solid using modified couple stress theory subjected to ramp-type thermal source with two temperature. The advantage of this theory is the involvement of only one material length scale parameter which can determine the size effects. Laplace and Fourier transform technique is applied to obtain the solutions of the governing equations. The components of displacement, conductive temperature, stress components and couple stress are obtained in the transformed domain. A numerical inversion technique has been used to obtain the solutions in the physical domain. The effect of two temperature is depicted graphically on the resulted quantities. Numerical results show that the proposed model can capture the size effects of microstructures.

Effects of Partial Substitution of W for Ti in Titanium Dioxide

  • Lee, Eun-Seok
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.2
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    • pp.68-71
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    • 2011
  • [ $Ti_{1-x}W_xO_{2-y}$ ]solid solutions with compositions of x = 0.01(TW-1), x = 0.02(TW-2), x = 0.03(TW-3) and x = 0.04(TW-4) were prepared at 1,073 K in air under atmospheric pressure. All the solutions exhibited tetragonal symmetries. Nonstoichiometric chemical formulas have been obtained from oxidation-reduction titration and the partial substitution of $W^{6+}$ ions mainly caused the formation of $Ti^{3+}$ ion, rather than oxygen excess. Resistivities of the samples were highly dependent on humidity. The increase of the W amount resulted in an increase of $Ti^{3+}$ content, decrease of resistivity values and finally degradation of photocatalytic activities.

SINGULAR PERIODIC SOLUTIONS OF A CLASS OF ELASTODYNAMICS EQUATIONS

  • Yuan, Xuegang;Zhang, Yabo
    • Journal of applied mathematics & informatics
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    • v.27 no.3_4
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    • pp.501-515
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    • 2009
  • A second order nonlinear ordinary differential equation is obtained by solving the initial-boundary value problem of a class of elas-todynamics equations, which models the radially symmetric motion of a incompressible hyper-elastic solid sphere under a suddenly applied surface tensile load. Some new conclusions are presented. All existence conditions of nonzero solutions of the ordinary differential equation, which describes cavity formation and motion in the interior of the sphere, are presented. It is proved that the differential equation has singular periodic solutions only when the surface tensile load exceeds a critical value, in this case, a cavity would form in the interior of the sphere and the motion of the cavity with time would present a class of singular periodic oscillations, otherwise, the sphere remains a solid one. To better understand the results obtained in this paper, the modified Varga material is considered simultaneously as an example, and numerical simulations are given.

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Collision Behavior of Molten Metal Droplet by Laser Beam (레이저 빔에 의해 생성된 금속액적의 충돌거동)

  • 김용욱;양영수
    • Laser Solutions
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    • v.6 no.1
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    • pp.1-8
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    • 2003
  • A molten metal droplets are deposited onto solid substrate for solid freeform fabrication, Collision dynamic and substrate heat transfer associated with solidification determine the final shape of molten metal droplets. In this study, the experimental model, based on the variational condition with substrate temperature and falling height, was produced reliable optimal data of droplet pattern.

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A Study on the pressure loss of sloid-liquid 2 phase flow in an annulus (환형관내 고-액 2상 유동의 압력손실 변화특성에 대한 연구)

  • Woo, Nam-Sub;Han, Sang-Mok;Hwang, Young-Kyu;Yoon, Chi-Ho;Kim, Young-Ju
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2720-2724
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    • 2007
  • Field measurements have revealed that the pressure drop over a borehole during drilling of a slim oil well or a well with a long reach can depend significantly on the rotation speed of the drill pipe. An accurate prediction of the annular frictional pressure drop is therefore important for conditions where the annular clearance is small. An experimental study was carried out to study solid-liquid two phase flow in a slim hole annulus. Annular velocities of carrier fluids varied from 0.2 m/s to 1.5 m/s. The carrier fluids which were utilized included tap water and CMC water solutions. Pressure drops and average flow rates were measured for the parameters such as inner-pipe rotary speed, carrier fluid velocity, hole inclination and particle injection rate. For both water and CMC solutions, the higher the concentration of the solid particles is, the larger the pressure gradients become.

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