• Title/Summary/Keyword: Si 분포

Search Result 1,177, Processing Time 0.026 seconds

Poly Si Buffer-layer 도입에 의한 실리콘 양자점층 두께 증가에 따른 실리콘 양자점 태양전지 효율 향상

  • Baek, Hyeon-Jeong;Park, Jae-Hui;Kim, Tae-Un;Kim, Gyeong-Jung
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2012.08a
    • /
    • pp.354-354
    • /
    • 2012
  • 실리콘 양자점 태양전지는 실리콘이 nm 크기의 양자점으로 될 경우 밴드갭이 증가하여 태양광 중의 가시광선을 광전변환에 활용함으로써 효율을 향상시키는 차세대 태양전지이다. 그러나 실리콘 양자점이 SiO2 매질 내에 분포하므로 양자점층의 두께가 증가할 경우 박막의 직렬저항이 증가하여 일정 두께 이상이 되면 효율이 감소하는 결과를 가져온다. 본 연구에서는 두께증가에 따른 효율저하 문제를 해결하기 위해 다결정 실리콘으로 이루어진 완충층을 도입 하였다. 이를 위해 본 연구에서는 두 가지 형태의 실리콘 양자점 태양전지를 제작하여 광전변환 특성을 비교하였다. 첫 번재 구조는 B이 도핑된 단일 실리콘 양자점층 태양전지이다. 양자점층은 2 nm SiOx 층과 2 nm SiO2 층을 적층한 후 $1,100^{\circ}C$에서 20분간 질소 분위기에서 급속 열처리하여 제작하였다. 실리콘 양자점 층의 두께를 40 nm에서 200 nm까지 변화시키면서 효율을 측정한 결과 100 nm 정도에서 효율이 감소하기 시작하였다. 이러한 효율감소는 양자점층의 저항 증가에 따른 전류감소에 의함이 확인되었다. 이와는 대조적으로 실리콘 양자점 층의 저항을 줄이기 위해 실리콘 양자점층 내에 50 nm 간격으로 10 nm 두께의 B이 도핑된 다결정 실리콘층을 배치하는 실리콘 양자점 태양전지를 개발하였다. 이러한 실리콘 양자점 층의 두께를 증가시킬 경우 효율이 지속적으로 증가함을 관찰하였다. 이러한 두 가지 형태의 양자점층을 이차이온질량분석법으로 분석한 결과 단일 실리콘 양자점층의 경우 두께가 약 70 nm 정도부터 이온빔 스퍼터링에 의한 저항증가에 따른 대전현상 (charging)이 관찰되었으나 다결정 실리콘 층이 배치된 실리콘 양자점층에서는 전혀 대전현상이 발생하지 않았다. 이는 다결정 실리콘 층이 캐리어를 이동시키는 매개체 역할을 하는 것으로 해석될 수 있다.

  • PDF

An analytical modeling for the two-dimensional field effect of a short channel GaAs MESFET and SOI-structured Si JFET (단채널 GaAs MESFET 및 SOI 구조의 Si JFET의 2차원 전계효과에 대한 해석적 모델에 대한 연구)

  • Choi Jin-Wook;Ji Soon-Koo;Choi Soo-Hong;Suh Chung-Ha
    • Journal of the Institute of Electronics Engineers of Korea SD
    • /
    • v.42 no.1
    • /
    • pp.25-32
    • /
    • 2005
  • In this paper, it is attempted to provide a unified explanation for typical short channel GaAs MESFET’s and SOI-structured Si JFET's behaviors such as: i) drain voltage-induced threshold voltage roll-off, ii) finite output ac resistance beyond the saturation, and iii) weak dependence of the drain saturation current on the channel length. Replacing the conventional GCA with a new assumption that is suggested in order to include the longitudinal field variation, and taking into account the channel current continuity and the field-dependent mobility, we can derive the two-dimensional potential in both depletion region and undepleted conducting channel. Obtained expressions for the threshold voltage and the drain current will be considerably accurate over the entire operating region. Moreover, in comparison with the conventional channel length shortening models, our model seems to be more reasonable in explaining the Early effect.

A Study on the Change of Regional Specialized Industries in Chungcheongbuk-do (충청북도의 지역별 특화 산업의 변화에 대한 연구)

  • Shin, Yeong-Jae
    • Journal of the Economic Geographical Society of Korea
    • /
    • v.17 no.2
    • /
    • pp.349-365
    • /
    • 2014
  • Chungcheongbuk-do can be said that it is not developed well because its surface accounts for 7.5% of Korea's whole land surface, and it accounts for 3.1% of population and main economical index from those of whole Korea. However, Chungcheongbuk-do should develop itself more by integrating of Cheongju-si and Cheongwon-gun, transfer of government facilities to Sejong city, and dispersing manufacturing companies of Seoul Metropolitan area. The factor which affects Chungcheongbuk-do's regional specialized industries is the distance from Cheongju-si and Gyeonggi-do. Service industries are specialized in urban area; manufacturing industries are specialized in regions which are close to Cheongju-si or Gyeonggi-do; and primary industries and consumer service industries are specialized in areas that is far from Cheongju-si. This study can be a foundation for studies on regional and industrial change of Chungcheongbuk-do by looking at its population and location quotient.

  • PDF

A Study on the Fabrication of Surface Heating Panel Using SiC Ceramics (SiC계 세라믹을 이용한 면상발열 판넬 개발에 관한 연구)

  • Cho, Hyun-Seob
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
    • /
    • v.9 no.6
    • /
    • pp.604-608
    • /
    • 2016
  • In recent years, research and development has been carried out in order to increase the economical efficiency and stability in terms of efficient use of energy for the heating apparatus. Especially, technology development for high performance and new functional materials is actively being carried out. This paper focuses on the development of exothermic products with excellent energy transfer characteristics. The heating element used for bedding or mattress uses a heating wire. Since the heating wire is thin, the distribution of heat is concentrated only around the heating wire,. In addition, electromagnetic induction is harmful to the human body and energy consumption is high. Therefore, it is aimed to develop a planar heating panel using SiC ceramics which can radiate far-infrared rays and anions to be harmless to the human body, but also has excellent heat conduction to enhance energy efficiency.

Effects of Surface Defect Distribution of $SiO_x(x{\le}2)$ Plates on Chemical Quenching ($SiO_x(x{\le}2)$ 플레이트의 표면 결함 분포가 화학 소염에 미치는 영향)

  • Kim, Kyu-Tae;Kwon, Se-Jin
    • 한국연소학회:학술대회논문집
    • /
    • 2005.10a
    • /
    • pp.328-336
    • /
    • 2005
  • Effects of surface defect distribution on flame instability during flame-surface interaction are experimentally investigated. To examine the chemical quenching phenomenon, we prepared thermally grown silicon oxide plates with well-defined defect density. Ion implantation was used to control the number of defects, i.e. oxygen vacancies. In an attempt to preferentially remove the oxygen atoms from silicon dioxide surface, argon ions with low energy level from 3keV to 5keV were irradiated at the incident angle of $60^{\circ}C$. Compositional and structural modification of $SiO_2$ induced by low-energy $Ar^+$ ion irradiation has been characterized by Atomic Force Microscopy (AFM) and X-ray Photoelectron Spectroscopy (XPS). The analysis shows that as the ion energy increases, the number of structural defect also increases and non-stoichiometric condition of $SiO_x(x{\le}2)$ plates is enhanced. From the quenching distance measurements, we found out that when the surface temperature is under $300^{\circ}C$, the quenching distance decreases on account of reduced heat loss; as the surface temperature increases over $300^{\circ}C$, however, quenching distance increases despite reduced heat loss effect. Such aberrant behavior is caused by heterogeneous chemical reaction between active radicals and surface defect sites. The higher defect density, the larger quenching distance. This results means that chemical quenching is governed by radical adsorption and can be parameterized by the oxygen vacancy density on the surface.

  • PDF

Low Temperature Recrystallization of Self-Implanted Amorphous Silicon Films (저온공정에 의한 자기이온주입된 비정질 실리콘 박막의 재결정화)

  • Lee, Man-Hyeong;Choe, Deok-Gyun;Kim, Jeong-Tae
    • Korean Journal of Materials Research
    • /
    • v.2 no.6
    • /
    • pp.417-427
    • /
    • 1992
  • Silicon ion implantation was performed to LPCVD amorphous Si films and the low temperature annealing process followed with various conditions to find the optimal physical properties by studying recrystallization behavior. The uniformity of the recrystallized films was inspected by optical microscopy and for this purpose, new KOH: (IPA) : $H_2$O: $K_2$C${r_2}{O_7}$, etchant was developed. XRD and TEM results showed that the crystallites were grown as a form of dendrite with (111) preferred orientation, and the grain size was increased with dose concentration. The maximum grain size was obtained when the 3${\times}{10^{15}}$c$m^2$ implanted amorphous Si film was recrystallized at 55 $0^{\circ}C$for more than 40 hrs and at this condition the grain size was 3.2${\mu}$m.

  • PDF

Preparation and Characterization of Opacified Silica Aerogels Doped by TiO$_2$ (TiO$_2$ 첨가에 의한 불투명한 실리카 에어로겔의 합성 및 특성화)

  • 손봉희;현상훈
    • Journal of the Korean Ceramic Society
    • /
    • v.36 no.2
    • /
    • pp.159-166
    • /
    • 1999
  • The physical properties and microstructural changes with heat-treatment of opacified silica aerogels doped by TiO2 were investigated. Monolithic SiO2-TiO2 aerogels were prepared by supercritical drying (25$0^{\circ}C$, 1250 psig) of wet gel obtained by adding titanium isopropoxide to prehydrolyzed TEOS-isopropanol solutions. The density and the porosity of SiO2-10 mol% TiO2 aerogels were 0.23 g/㎤ and 90%, respectively. During supercritical drying, the linear shrinkage of aerogels increased with increase in the titanium content an TiO2 was transformed to the anatase phase as well as particls agglomerates led to TiO2 clusters of 100~800 nm dispersed homogeneoulsy in the silica matrix. The IR transmittance of opacified silica aerogels was very low in the region of wavelengths below 8 ${\mu}{\textrm}{m}$ compared with pure silica aerogels and SiO2-TiO2 aerogels showed the high thermal stability of microstructures up to $600^{\circ}C$.

  • PDF

Determining Mechanical Properties of ZrO2 Composite Ceramics by Weibull Statistical Analysis (와이블 통계 해석에 의한 ZrO2 복합 세라믹스의 기계적 특성)

  • Kim, Seon Jin;Kim, Dae Sik;Nam, Ki Woo
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.39 no.10
    • /
    • pp.955-962
    • /
    • 2015
  • The Vickers test can be used for all types of materials, and it has one of the widest scales among hardness tests. The hardness may be considered as a probability variable when evaluating the mechanical properties of materials. In this study, we investigate the statistical properties of the bending strength and Vickers hardness in $ZrO_2$ monolithic and $ZrO_2/SiC$ composites depending on the amount of $TiO_2$ additives. The bending strength and Vickers hardness were found to agree well with the Weibull probability distribution. We evaluate the scale parameter and shape parameter in as-received $ZrO_2$ and $ZrO_2/SiC/TiO_2$ ceramics, as well as their heat treated ceramics. We also evaluate the parameters in accordance with the increase in in the indentation load.

Changes of Characteristic of Terpolymers according to the Chain Length of Incorporated High α-olefins (도입된 High α-olefin의 사슬길이 변화에 따른 삼원공중합체 특성 변화)

  • Jeon, Dong Gyu;Kim, Tae Wan;Kim, Jung Soo;Kim, Hyun Ki;Chang, Young Wook;Kim, Dong Hyun
    • Elastomers and Composites
    • /
    • v.48 no.4
    • /
    • pp.269-275
    • /
    • 2013
  • In this study, we prepared poly(ethylene-ter-1-hexene-ter-divinylbenzene) using various metallocene catalysts with trityl tetrakis(pentafluorophenyl)borate/triisobutylaluminium cocatalysts system. We tried rac-$Et(Ind)_2ZrCl_2$, rac-$SiMe_2(Ind)_2ZrCl_2$, and rac-$SiMe_2(2-Me-Ind)_2ZrCl_2$ to choose optimum metallocene catalyst, comparing with catalytic activity, molecular weight, molecular weight distribution of the terpolymers. To study the effects of chain length of high ${\alpha}$-olefins on the terpolymerization, we synthesized the terpolymers using 1-hexene, 1-octene, 1-decene or 1-dodecene. We characterized chemical composition, thermal properties, and mechanical properties of the terpolymers.

Measurement of Thickness Distribution of $Si_3N_4$ Membrane Using Phase-Shifting Interferometer (위상이동 간섭계를 이용한 $Si_3N_4$ 박막의 두께 분포 측정)

  • Lee, Jung-Hyun;Jeong, Seung-Jun;Kang, Jeon-Woong;Jeon, Yun-Seong;Hong, Chung-Ki
    • Journal of the Korean Society for Nondestructive Testing
    • /
    • v.25 no.2
    • /
    • pp.67-73
    • /
    • 2005
  • The thickness of a Si3N4 thin film with a 100m nominal thickness was measured by use of a Mach-Zehnder interferometer. The map of the phase-delay through the thin film was obtained by an interframe intensity-correlation-matrix method that could elliminate phase-shifting errors. After the spatial phase-shifting errors were treated with a least-squares method, the reference to surface of the phase map was estimated. The overall accuracy of the method was found to be 5nm.