• 제목/요약/키워드: Salt bridge

검색결과 56건 처리시간 0.031초

다니엘 전지를 구성하는 염다리의 역할에 대한 고등학생, 화학교사, 그리고 예비 과학 교사들의 개념 유형 분석 (An Analysis of Conception Types of High School Students, Chemistry Teachers, and Pre-service Science Teachers about Salt Bridge of Daniel Electronic Cell)

  • 박진희;김동욱;백성혜
    • 한국과학교육학회지
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    • 제24권3호
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    • pp.544-555
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    • 2004
  • 이 연구에서는 고등학교 학생들, 화학교사들, 그리고 예비 교사들을 대상으로 하여 다니엘 전지에서의 염다리 역할에 대한 개념 유형을 설문과 면담을 통하여 알아보았다. 또한 교사와 학생들이 가지는 개념의 어려움에 대한 원인을 알아보기 위하여 고등학교 화학 II 교과서의 서술내용에 대한 분석도 병행하였다. 예비 교사들의 생각은 교사교육 프로그램의 문제점을 점검하기 위하여 조사되었다. 연구 결과, 교사들은 염다리를 통한 이온의 이동에 관한 관점은 가지고 있었으나,염다리가 닫힌 회로를 완성하는 역할을 한다는 사실에 대한 관점을 가지고 있지 않은 것으로 나타났다. 이러한 경향은 학생들과 예비교사의 경우에도 유사한 것으로 나타났다. 교사들과 학생들이 염다리에 대한 정확한 개념을 형성하는데 어려움을 겪는 원인은 교과서의 불충분하고 다양한 설명 때문일 가능성이 있었다.

조간대와 비말대의 콘크리트와 보수재의 염분침투 특성분석 (The Analysis of Chloride Penetration at Concrete and Repair Material under Tidal and Splash Zone)

  • 이준구;조영권;김명원;김관호;조재용;김한중
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2010년도 춘계 학술대회 제22권1호
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    • pp.207-208
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    • 2010
  • The building that supply tidal and splash zone was constructed near Seamangeum Gate Bridge. The specimens that will be tested for maintenance of gate bridge were exposed on the tidal and splash zone, totally about 650. The characteristics of strength, salt penetration profile, field application of surface repair material and section recover material will be acquired by periodical test. The program was developed to obtain optimal maintenance strategy of gate bridge as a marine concrete structure and to deposit experimental data, lab. test result, field test result, on its D/B. On this paper, the comparison of concrete and recover material in the salt penetration characteristics was expressed. The quantitative analysis of salt contents in concrete surface was most important so the improvement for the machine of gathering power of concrete and the apparatus of measuring chloride contents was proceeded at this time. The two conclusions were summarized like as - The resistance of chloride attack of concrete was appeared 2.5 times bigger than that of recover material - The resistance of chloride attack of polymer series was appeared more higher than that of others.

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동해와 염해를 동시에 받는 콘크리트의 복합열화에 관한 연구 (A Study on the Combined Deterioration of Concrete subjected to Freezing-Thawing and Chloride Attack)

  • 김은겸;최상덕
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2005년도 봄학술 발표회 논문집(II)
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    • pp.225-228
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    • 2005
  • This paper was accomplished for analyzing the reason of the above deterioration happened on the deck of concrete bridge. The bridge was constructed at 660m above the sea level having more freezing and snowing days. Therefore, it is placed on the particular condition sprinkling $CaCl_2$ enough for keeping up with moderate traffic condition. When it is considered to the former condition, the bridge can be assumed to potentialities for combined deterioration with freezing-thawing under sprinkling deicing chemical. Core specimens were gathered from the concrete deck for clearing the reason of the above deterioration exactly, and it is used for various tests for measuring the compressive strength, elastic modulus, content of $Cl^-$, freezing-thawing at the fresh and salt water. As a result of freezing-thawing test, the specimen at the fresh water has over 90$\%$ of durability factor, but another specimen at 1$\%$ of salt water has 0$\%$ of durability factor at 140 cycles of the freezing-thawing. The result means that frost damage is sccelerated at the salt water. Therefore, the deterioration of the concrete deck is estimated to be occured by combined effects of freezing-thawing and chloride ion attack.

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고속도로 콘크리트 노출 바닥판에서의 제설 염화물의 침투 특성 (Penetration of De-icing Salt in Bare Concrete Bridge Decks in Highways)

  • 서진원;구본성;이지영
    • 한국구조물진단유지관리공학회 논문집
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    • 제11권2호
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    • pp.85-92
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    • 2007
  • 콘크리트 노출 바닥판은 88 고속도로, 호남고속도로 확장, 제1중부고속도로 등의 1980년대에 건설된 고속도로 교량에 널리 적용되었다. 약 20년 정도 공용한 후에 콘크리트 노출 바닥판의 상태를 평가한 결과, 상당수의 교량들이 특별한 유지관리비가 소요되지 않고 공용중이다. 이러한 이유로 시공성, 유지관리 그리고 구조적인 관점에서 기존 콘크리트 노출 바닥판에 대한 공용성에 대한 재평가가 이루어지고 있다. 이러한 일환으로 콘크리트 노출 바닥판의 주요 손상원인 중의 하나인 철근 부식에 의한 박락을 유발시키는 제설 염화물에 침투 특성을 파악하고 바닥판의 수명을 평가하고자 고속도로 상에 공용중인 콘크리트 노출 바닥판에서 코어를 채취하여 깊이별 염화물을 측정하여 표면 염화물량 및 겉보기 확산계수를 구하였다.

국내 도로교량 바닥판 열화모델 제안 및 교체 수요 예측 (Proposal of Domestic Road Bridge Deck Deterioration Models and Forecast of Replacement Demand)

  • 김진광;장일영
    • 한국구조물진단유지관리공학회 논문집
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    • 제21권4호
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    • pp.61-68
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    • 2017
  • 교량 바닥판은 대형 차량 및 제설제와 같은 다양한 환경 요인으로 인해 급속히 악화되는 부재이다. 한국에 건설된 교량의 수명이 길어짐에 따라 교량 바닥판의 교체 수요가 증가 할 것으로 예상된다. 다른 국가에서는 프리 캐스트 바닥판을 이용한 급속 교량 건설 기술이 열화된 교량 바닥판의 교체 수요 대응을 위해 적극적으로 사용되고 있다. 본 연구에서는 국내 교량 바닥판의 상태평가 데이터를 수집 및 분석하여 교량 바닥판 열화 모델을 제안 하였다. 또한 교량 규모의 관점에서 열화된 교량 바닥판의 미래 대체 수요를 예측하였다.

해양 환경하 콘크리트 교량의 염해환경 성능평가 연구 (A Study on the Evaluation of the Environmental Performance of Salt Damage in Concrete Bridges under Marine Environment)

  • 채원규;이명구;손영현;홍성욱
    • 한국안전학회지
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    • 제33권5호
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    • pp.60-69
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    • 2018
  • This study aims to investigate in the assessment of salt damage conditions in concrete structures under marine environment conditions. It aims also to improve the durability of new concrete bridge through applying the life prediction method of salt damaged bridges. As measuring chloride contents of these bridges on the southwest coastal area, it is shown that the average amount of chloride on these surfaces close to shore is $10.5kg/m^3$. This figure is much higher than that of the Standard Specification for Concrete($1.5kg/m^3{\sim}2.5kg/m^3$). In contrast, it is shown the average amount of chloride on these surfaces in tide zone is $13.1kg/m^3$. Its figure is much lower than that of the Standard Specification for Concrete($20kg/m^3$). And the life of bridges is estimated about 17 years. To improve the durability for salt damage, these bridges are applied to surface treatment method which the replacement rate of furnace slag is 60%. Under this condition, it is expected to be 110 years. Consequently, it is clear that the use of slag replacement rate, surface treatment agent, and anti-corrosion agent to control chloride penetration effects of a submerge-based concrete bridge will be required.

전기철도 전차선로 지지애자의 염해지역 열화특성 사례 연구 (A Case Study of Degradation Characteristics for Rod-Insulator on Catenary System in Electric Railway)

  • 정호성;박영
    • 한국전기전자재료학회논문지
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    • 제32권4호
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    • pp.263-266
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    • 2019
  • In the Airport Railroad, the Yeongjong Bridge has a length of 4,420 m and connects Yeongjong Island with the mainland of Incheon City. The bridge is a two-level structure, consisting of a six-lane road at the upper level and a combination of a road and railroad at the lower level. The environmental conditions for the electric railway come mainly from the salt injury area and a heavy industry zone, and the maintenance cycles are determined differently depending on these conditions. This study analyzed the deterioration characteristics of long rod insulators produced with a movable ceramic bracket and polymer materials in the Yeongjong Bridge section of the Airport Railway operating in the salt injury area according to the material characteristics. Comparison of the corona measurements when the insulators were cleaned at the same time showed that the polymer insulator had a higher insulation performance than the ceramic insulator.

분자동역학 전산모사에 의한 α6 nAChR Subunit의 α-conotoxin BuIA에 대한 선택성 연구 (Selectivity of the α6 nAChR Subunit on α-conotoxin BuIA Studied by Molecular Dynamics Simulations)

  • ;이명기
    • 한국수산과학회지
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    • 제48권1호
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    • pp.71-75
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    • 2015
  • Nicotinic acetylcholine receptors (nAChRs) are essential for neurotransmission and important therapeutic targets of diseases related to neurotransmission. A recent experimental study identified three residues (Lys185, Asp187, and Ile188) of the ${\alpha}6$ nAChR subunit as determinants of ${\alpha}$-conotoxin BuIA selectivity, yet how these residues confer toxin selectivity remains unclear. In this study, we performed all-atom molecular dynamics simulations with two toxin-bound ${\alpha}4{\beta}2$ nAChR systems: the wild-type ${\alpha}4{\beta}2$ and one in which we replaced the three ${\alpha}4$ subunit residues with three ${\alpha}6$ subunit residues identified in an experimental study (Tyr185Lys, Thr187Asp, and Arg188Ile). After mutation, Asp199 lost the salt bridge formed with Arg188 in the wild type located around loop C. Then, the loop C conformation changed and became more flexible than that of the wild type. We also detected reduced space between the toxin and the binding site in the mutant simulation, resulting in increased binding affinity to the toxin. Therefore, we propose a new Asp199 mutation that breaks the salt bridge and may produce similar selectivity to that of the Arg188 mutation.

Role of the Salt Bridge Between Arg176 and Glu126 in the Thermal Stability of the Bacillus amyloliquefaciens ${\alpha}$-Amylase (BAA)

  • Zonouzi, Roseata;Khajeh, Khosro;Monajjemi, Majid;Ghaemi, Naser
    • Journal of Microbiology and Biotechnology
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    • 제23권1호
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    • pp.7-14
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    • 2013
  • In the Bacillus amyloliquefaciens ${\alpha}$-amylase (BAA), the loop (residues 176-185; region I) that is the part of the calcium-binding site (CaI, II) has two more amino acid residues than the ${\alpha}$-amylase from Bacillus licheniformis (BLA). Arg176 in this region makes an ionic interaction with Glu126 from region II (residues 118-130), but this interaction is lost in BLA owing to substitution of R176Q and E126V. The goal of the present work was to quantitatively estimate the effect of ionic interaction on the overall stability of the enzyme. To clarify the functional and structural significance of the corresponding salt bridge, Glu126 was deleted (${\Delta}$E126) and converted to Val (E126V), Asp (E126D), and Lys (E126K) by site-directed mutagenesis. Kinetic constants, thermodynamic parameters, and structural changes were examined for the wild-type and mutated forms using UV-visible, atomic absoption, and fluorescence emission spectroscopy. Wild-type exhibited higher $k_{cat}$ and $K_m$ but lower catalytic efficiency than the mutant enzymes. A decreased thermostability and an increased flexibility were also found in all of the mutant enzymes when compared with the wild-type. Additionally, the calcium content of the wild-type was more than ${\Delta}E126$. Thus, it may be suggested that ionic interaction could decrease the mobility of the discussed region, prevent the diffusion of cations, and improve the thermostability of the whole enzyme. Based on these observations, the contribution of loop destabilization may be compensated by the formation of a salt bridge that has been used as an evolutionary mechanism or structural adaptation by the mesophilic enzyme.

고속도로 콘크리트 노출 바닥판에서의 제설 염화물의 침투 특성 (Penetration of De-icing Salt in Bare Concrete Bridge Decks on Highways)

  • 서진원;이지영;구본성
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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    • pp.165-168
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    • 2006
  • The major cause of deterioration for the bare concrete bridge decks exposed to de-icing chemicals would be chloride-induced reinforcement corrosion. Thus, in this paper, in order to predict time to corrode for concrete bridge decks on highways, the chloride concentration was measured with depth from the surface. Then, the surface chloride concentration and apparent diffusion coefficient were calculated by regression. The premature failure of bare concrete decks were mostly related with thin cover depth and poor concrete property(high permeability). The good protection of deck surface might contribute to the prolongation of the service life of bare concrete bridge decks.

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