• Title/Summary/Keyword: Salt bridge

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An Analysis of Conception Types of High School Students, Chemistry Teachers, and Pre-service Science Teachers about Salt Bridge of Daniel Electronic Cell (다니엘 전지를 구성하는 염다리의 역할에 대한 고등학생, 화학교사, 그리고 예비 과학 교사들의 개념 유형 분석)

  • Park, Jin-Hee;Kim, Dong-Uk;Paik, Seoung-Hey
    • Journal of The Korean Association For Science Education
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    • v.24 no.3
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    • pp.544-555
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    • 2004
  • This study examined the conception types of high school students, chemistry teachers, and pre-service teachers about the salt bridge in Daniel cell by a questionnaire and follow-up interviews. High school chemistry II textbooks were analyzed for finding the cause of the understanding difficulties of the teachers and students. Pre-service teachers' thoughts examined for the problems of pre-service teacher programs. From the analysis, it was found that teachers only thought that the role of salt bridge is for ion movement of two solutions involving electrodes. But they didn't have the conception that salt bridge has a roll of connection a circuit. This result was similar to students' and pre-service teachers' results. It was possible that insufficient and different explanations of the textbooks were attributed the teachers' and students' conceptual difficulties.

The Analysis of Chloride Penetration at Concrete and Repair Material under Tidal and Splash Zone (조간대와 비말대의 콘크리트와 보수재의 염분침투 특성분석)

  • Lee, Joon-Gu;Cho, Young-Kwoun;Kim, Meyong-Won;Kim, Kwan-Ho;Joo, Jae-Hong;Kim, Han-Joung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.207-208
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    • 2010
  • The building that supply tidal and splash zone was constructed near Seamangeum Gate Bridge. The specimens that will be tested for maintenance of gate bridge were exposed on the tidal and splash zone, totally about 650. The characteristics of strength, salt penetration profile, field application of surface repair material and section recover material will be acquired by periodical test. The program was developed to obtain optimal maintenance strategy of gate bridge as a marine concrete structure and to deposit experimental data, lab. test result, field test result, on its D/B. On this paper, the comparison of concrete and recover material in the salt penetration characteristics was expressed. The quantitative analysis of salt contents in concrete surface was most important so the improvement for the machine of gathering power of concrete and the apparatus of measuring chloride contents was proceeded at this time. The two conclusions were summarized like as - The resistance of chloride attack of concrete was appeared 2.5 times bigger than that of recover material - The resistance of chloride attack of polymer series was appeared more higher than that of others.

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A Study on the Combined Deterioration of Concrete subjected to Freezing-Thawing and Chloride Attack (동해와 염해를 동시에 받는 콘크리트의 복합열화에 관한 연구)

  • Kim Eun-Kyum;Choi Sang-Deok
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.225-228
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    • 2005
  • This paper was accomplished for analyzing the reason of the above deterioration happened on the deck of concrete bridge. The bridge was constructed at 660m above the sea level having more freezing and snowing days. Therefore, it is placed on the particular condition sprinkling $CaCl_2$ enough for keeping up with moderate traffic condition. When it is considered to the former condition, the bridge can be assumed to potentialities for combined deterioration with freezing-thawing under sprinkling deicing chemical. Core specimens were gathered from the concrete deck for clearing the reason of the above deterioration exactly, and it is used for various tests for measuring the compressive strength, elastic modulus, content of $Cl^-$, freezing-thawing at the fresh and salt water. As a result of freezing-thawing test, the specimen at the fresh water has over 90$\%$ of durability factor, but another specimen at 1$\%$ of salt water has 0$\%$ of durability factor at 140 cycles of the freezing-thawing. The result means that frost damage is sccelerated at the salt water. Therefore, the deterioration of the concrete deck is estimated to be occured by combined effects of freezing-thawing and chloride ion attack.

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Penetration of De-icing Salt in Bare Concrete Bridge Decks in Highways (고속도로 콘크리트 노출 바닥판에서의 제설 염화물의 침투 특성)

  • Suh, Jin Won;Ku, Bon Sung;Rhee, Ji Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.11 no.2
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    • pp.85-92
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    • 2007
  • In 1980s, a number of bridges with bare concrete deck were constructed on the Korea highway. After 20 years service, many bare concrete decks are still in good condition without special maintenance activity. Therefore, the application of the bare concrete deck is being reestimated from the view of construction and maintenance. As a part of the program, the characteristic of penetration(surface chloride and apparent diffusion coefficient) of de-icing salt into bare concrete bridge deck was analyzed in order to predict the service life of bridge on Korea highway.

Proposal of Domestic Road Bridge Deck Deterioration Models and Forecast of Replacement Demand (국내 도로교량 바닥판 열화모델 제안 및 교체 수요 예측)

  • Kim, Jin-Kwang;Jang, Il-Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.4
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    • pp.61-68
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    • 2017
  • Bridge decks are members that rapidly deteriorated due to various environmental factors such as heavy vehicle and deicing salt, etc. As the lifespan of bridges built in Korea increases, it is expected that the demand for replacing the deteriorated bridge decks will increase. In other countries, Accelerated Bridge Construction technology using precast decks is already actively being used as a countermeasure for replacement demand of deteriorated bridge decks. In this study, bridge decks deterioration models are proposed by collecting and analysing the condition index data of domestic bridge decks. Also, the future replacement demands of deteriorated bridge decks in terms of replacement time and replacement scale are predicted.

A Study on the Evaluation of the Environmental Performance of Salt Damage in Concrete Bridges under Marine Environment (해양 환경하 콘크리트 교량의 염해환경 성능평가 연구)

  • Chai, Won-Kyu;Lee, Myeong-Gu;Son, Young-Hyun;Hong, Sung-Wook
    • Journal of the Korean Society of Safety
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    • v.33 no.5
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    • pp.60-69
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    • 2018
  • This study aims to investigate in the assessment of salt damage conditions in concrete structures under marine environment conditions. It aims also to improve the durability of new concrete bridge through applying the life prediction method of salt damaged bridges. As measuring chloride contents of these bridges on the southwest coastal area, it is shown that the average amount of chloride on these surfaces close to shore is $10.5kg/m^3$. This figure is much higher than that of the Standard Specification for Concrete($1.5kg/m^3{\sim}2.5kg/m^3$). In contrast, it is shown the average amount of chloride on these surfaces in tide zone is $13.1kg/m^3$. Its figure is much lower than that of the Standard Specification for Concrete($20kg/m^3$). And the life of bridges is estimated about 17 years. To improve the durability for salt damage, these bridges are applied to surface treatment method which the replacement rate of furnace slag is 60%. Under this condition, it is expected to be 110 years. Consequently, it is clear that the use of slag replacement rate, surface treatment agent, and anti-corrosion agent to control chloride penetration effects of a submerge-based concrete bridge will be required.

A Case Study of Degradation Characteristics for Rod-Insulator on Catenary System in Electric Railway (전기철도 전차선로 지지애자의 염해지역 열화특성 사례 연구)

  • Jung, Hosung;Park, Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.4
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    • pp.263-266
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    • 2019
  • In the Airport Railroad, the Yeongjong Bridge has a length of 4,420 m and connects Yeongjong Island with the mainland of Incheon City. The bridge is a two-level structure, consisting of a six-lane road at the upper level and a combination of a road and railroad at the lower level. The environmental conditions for the electric railway come mainly from the salt injury area and a heavy industry zone, and the maintenance cycles are determined differently depending on these conditions. This study analyzed the deterioration characteristics of long rod insulators produced with a movable ceramic bracket and polymer materials in the Yeongjong Bridge section of the Airport Railway operating in the salt injury area according to the material characteristics. Comparison of the corona measurements when the insulators were cleaned at the same time showed that the polymer insulator had a higher insulation performance than the ceramic insulator.

Selectivity of the α6 nAChR Subunit on α-conotoxin BuIA Studied by Molecular Dynamics Simulations (분자동역학 전산모사에 의한 α6 nAChR Subunit의 α-conotoxin BuIA에 대한 선택성 연구)

  • Tham, Phan Thi Hong;Yi, Myunggi
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.48 no.1
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    • pp.71-75
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    • 2015
  • Nicotinic acetylcholine receptors (nAChRs) are essential for neurotransmission and important therapeutic targets of diseases related to neurotransmission. A recent experimental study identified three residues (Lys185, Asp187, and Ile188) of the ${\alpha}6$ nAChR subunit as determinants of ${\alpha}$-conotoxin BuIA selectivity, yet how these residues confer toxin selectivity remains unclear. In this study, we performed all-atom molecular dynamics simulations with two toxin-bound ${\alpha}4{\beta}2$ nAChR systems: the wild-type ${\alpha}4{\beta}2$ and one in which we replaced the three ${\alpha}4$ subunit residues with three ${\alpha}6$ subunit residues identified in an experimental study (Tyr185Lys, Thr187Asp, and Arg188Ile). After mutation, Asp199 lost the salt bridge formed with Arg188 in the wild type located around loop C. Then, the loop C conformation changed and became more flexible than that of the wild type. We also detected reduced space between the toxin and the binding site in the mutant simulation, resulting in increased binding affinity to the toxin. Therefore, we propose a new Asp199 mutation that breaks the salt bridge and may produce similar selectivity to that of the Arg188 mutation.

Role of the Salt Bridge Between Arg176 and Glu126 in the Thermal Stability of the Bacillus amyloliquefaciens ${\alpha}$-Amylase (BAA)

  • Zonouzi, Roseata;Khajeh, Khosro;Monajjemi, Majid;Ghaemi, Naser
    • Journal of Microbiology and Biotechnology
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    • v.23 no.1
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    • pp.7-14
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    • 2013
  • In the Bacillus amyloliquefaciens ${\alpha}$-amylase (BAA), the loop (residues 176-185; region I) that is the part of the calcium-binding site (CaI, II) has two more amino acid residues than the ${\alpha}$-amylase from Bacillus licheniformis (BLA). Arg176 in this region makes an ionic interaction with Glu126 from region II (residues 118-130), but this interaction is lost in BLA owing to substitution of R176Q and E126V. The goal of the present work was to quantitatively estimate the effect of ionic interaction on the overall stability of the enzyme. To clarify the functional and structural significance of the corresponding salt bridge, Glu126 was deleted (${\Delta}$E126) and converted to Val (E126V), Asp (E126D), and Lys (E126K) by site-directed mutagenesis. Kinetic constants, thermodynamic parameters, and structural changes were examined for the wild-type and mutated forms using UV-visible, atomic absoption, and fluorescence emission spectroscopy. Wild-type exhibited higher $k_{cat}$ and $K_m$ but lower catalytic efficiency than the mutant enzymes. A decreased thermostability and an increased flexibility were also found in all of the mutant enzymes when compared with the wild-type. Additionally, the calcium content of the wild-type was more than ${\Delta}E126$. Thus, it may be suggested that ionic interaction could decrease the mobility of the discussed region, prevent the diffusion of cations, and improve the thermostability of the whole enzyme. Based on these observations, the contribution of loop destabilization may be compensated by the formation of a salt bridge that has been used as an evolutionary mechanism or structural adaptation by the mesophilic enzyme.

Penetration of De-icing Salt in Bare Concrete Bridge Decks on Highways (고속도로 콘크리트 노출 바닥판에서의 제설 염화물의 침투 특성)

  • Suh, Jin-Won;Rhee, Ji-Young;Ku, Bon-Sung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.165-168
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    • 2006
  • The major cause of deterioration for the bare concrete bridge decks exposed to de-icing chemicals would be chloride-induced reinforcement corrosion. Thus, in this paper, in order to predict time to corrode for concrete bridge decks on highways, the chloride concentration was measured with depth from the surface. Then, the surface chloride concentration and apparent diffusion coefficient were calculated by regression. The premature failure of bare concrete decks were mostly related with thin cover depth and poor concrete property(high permeability). The good protection of deck surface might contribute to the prolongation of the service life of bare concrete bridge decks.

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