• Title/Summary/Keyword: Retention Ratio

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Interpretation of Contaminated Soil by Complex Oil (토양 내 복합유종에 의한 오염 해석 연구)

  • Lim, Young-Kwan;Kim, Jeong-Min;Kim, Jong-Ryeol;Ha, Jong-Han
    • Journal of Soil and Groundwater Environment
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    • v.22 no.1
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    • pp.13-17
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    • 2017
  • Over 30% of domestic soil contamination has occurred via petroleum products and complex oil. Moreover, contamination by complex oil is more intense than it is by a single petroleum product species. In this study, we analyzed sectional TPH (total petroleum hydrocarbon) pattern and sectional ratio of current domestically distributed petroleum products, such as kerosene, diesel, bunker C, and lubricant and complex oils, to determine pollution characteristics of the soil. In the TPH pattern, kerosene, which is a light distillate, had an early retention time, and lubricant oil, which is a heavy distillate, had a late retention time in the gas chromatogram. In addition, we obtained a complexly contaminated soil via diesel and lubricant oil from the Navy and inspected it for its ratio of complex oil species. The inspection results showed that this soil was contaminated with 85% diesel and 15% lubricant oil. The method developed in this study could be used to determine complex petroleum sources and ratios at sites with accidentally contaminated soil.

Nutrient Removal Using Fermented Organic Acids Derived from the Primary Sludge in the Intermittent Aeration Activated Sludge Process

  • Weon, Seung-Yeon;Lee, Sang-Il;Lee, Chan-Won
    • Environmental Engineering Research
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    • v.16 no.4
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    • pp.213-218
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    • 2011
  • The two-stage intermittent aeration activated sludge process (IAP) and dynamic-flow intermittent aeration activated sludge process (DFP) were investigated for the nutrient removal of domestic wastewater. Three sets of IAP and one set of DFP were operated. The fermented settled sludge taken from the primary settling tank was added to two IAP and one DFP as an external electron donor, with one IAP, in which an external carbon source was not added, as a control. All the systems were operated at a sludge retention time of 20 days and a hydraulic retention time of 12 hr. A Higher denitrification rate was observed with the fermented settled sludge for the denitrification compared to the process without the addition of the organic source. The result indicates that the fermented acid from the primary domestic sludge has been proved to be an excellent electron donor for denitrification and biological phosphorus removal with IAP and DFP in treating relatively low C/N ratio(Carbon / Nitrogen ratio) wastewater. Phosphate accumulating organisms have a capability of competing with denitrifiers in the presence of volatile organic acids under anoxic conditions.

Trace Analysis as TBDMS Derivatives of Organic Acids in Aqueous Samples (TBDMS 유도체로서 수용액 시료중의 유기산 미량분석 연구)

  • Kim, Gyeong Rye;Kim, Jeong Han;Park, Hyeong Guk
    • Journal of the Korean Chemical Society
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    • v.34 no.4
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    • pp.352-359
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    • 1990
  • An effecient gas chromatographic method is described to be used routinely for the rapid profiling and identification of biochemically important organic acids. It involves the solid-phase extraction of organic acids from aqueous samples using Chromosorb P as the solid sorbent and diethyl ether as the eluting solvent, with subsequent triethylamine treatment. The resulting triethylammonium salts of acids were directly converted to volatile tert-butyldimethylsiyl derivatives, which were simultaneously analyzed by two capillary columns of different polarity, DB-5 and DB-1701, under the identical temperature programming condition. The retention index (RI) and area ratio (AR) values of each peak measured on DB-5 and DB-1701 enabled rapid identification of acids by computer RI library search and AR comparison. The application of the present method to the organic acid profiling of various complex samples is demonstrated.

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Influence factors and Efficiencies Characteristics for Treatment of Wastewater Containing Phenol (Phenol 함유폐수의 처리를 위한 영향인자와 성능특성)

  • Kang, Sun-Tae;Kim, Jeong-Mog
    • Journal of Korean Society of Water and Wastewater
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    • v.10 no.4
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    • pp.119-126
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    • 1996
  • Influence factors and efficiency characteristics for treatment of wastewater containing phenol were studied with using Pseudomonas sp. B3. It took 130 hours to remove phenol, when only activated sludge of terminal disposal palnt of sewage was innoculated in batch culture, but it was required just 36 hours, when bacteria degrading phenol and activated sludge were simultaneously innoculated. If only phenol an carbon source was used, it necessary 36 hours for biodegradation of phenol, while glucose was added to medium, it took 73 hours. It was revealed as excellent effluent and SVI, when the F/M ratio, COD and phenol concentration were 53mg/l and 1.2mg/l, respectively, and optimum F/M ratio was revealed 0.31. The reactor were seriously shocked as reducing hydraulic retention time at constant phenol concentration more than increasing phenol concentration at constant hydraulic retention time, when volumetric loading rate was increased to $0.8kg\;phenol/m^3{\codt}d$ from $1.6kg\;phenol/m^3{\codt}d$. And also the effluent phenol concentration was 34mg/l after starting 12 hours of shocking and reactor was recovered as steady state after 65 hours of changing in the former test. Although the effluent phenol concentration was maximum value with 12mg/l after starting 20 hours of shocking and reactor was recovered as steady state after 54 hours of changing in the later test.

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Reliable charge retention in nonvolatile memories with van der Waals heterostructures

  • Qiu, Dongri;Kim, Eun Kyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.282.1-282.1
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    • 2016
  • The remarkable physical properties of two-dimensional (2D) semiconducting materials such as molybdenum disulfide ($MoS_2$) and tungsten disulfide ($WS_2$) etc. have attracted considerable attentions for future high-performance electronic and optoelectronic devices. The ongoing studies of $MoS_2$ based nonvolatile memories have been demonstrated by worldwide researchers. The opening hysteresis in transfer characteristics have been revealed by different charge confining layer, for instance, few-layer graphene, $MoS_2$, metallic nanocrystal, hafnium oxide, and guanine. However, limited works built their nonvolatile memories using entirely of assembled 2D crystals. This is important in aspect view of large-scale manufacture and vertical integration for future memory device engineering. We report $WS_2$ based nonvolatile memories utilizing functional van der Waals heterostructure in which multi-layered graphene is encapsulated between $SiO_2$ and hexagonal boron nitride (hBN). We experimentally observed that, large memory window (20 V) allows to reveal high on-/off-state ratio (>$10^3$). Moreover, the devices manifest perfect retention of 13% charge loss after 10 years due to large graphene/hBN barrier height. Interestingly, the performance of our memories is drastically better than ever published work related to $MoS_2$ and black phosphorus flash memory technology.

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Thermophilic Sewage Sludge Digestion by Anaerobic Sequencing Batch Reactor (고온 협기성 연속회분식 공정에 의한 도시하수슬러지 소화)

  • 허준무;박종안;이종화;손부순;장봉기
    • Journal of environmental and Sanitary engineering
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    • v.14 no.3
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    • pp.130-138
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    • 1999
  • The feasibility of municipal sewage sludge digestion was investigated by using thermophilic anaerobic sequencing batch reactor(ASBR). One-day settle time was enough for the high performance of solid-liquid separation. The conversion of semi-continuous mode to sequencing batch mode is easily achieved without any adverse effects, although the large amount of sludge equal to the volume ratio of 0.3~06 to reactor volume was added in the feed step of the start-up. The ASBRs had higher conversion capability of organics to biogas than the control reactor. Gas yields of the ASBRs were increased by the average of 50% over the control reactor across a range of hydraulic retention time(HRT)s from 10days to 5days. The thermophilic reactors showed higher gas production than mesophilic reactor. Removal efficiencies of organic matter exceeded 80% on the basis of supernatants, except that at the reactor. Solid-liquid separation was essential in the performance of the ASBR, especially, at the lower HFT. The ASBRs were highly efficient in the retention of activated biomass within the reactor. thus compensating for increased equivalent organic loading rate through increased solids retention times followed by the increased solids, while maintaining shorter HRTs.

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Retention Mechanism of Caffeine and Tryptophan in Macroporous Poly[Methacrylic Acid-co-Ethylene Glycol Dimenthacrylate] Rods (매크로 다공성 Poly[Methacrylic Acid-co-Ethylene Glycol Dimenthacrylate] 막대에서 Caffeine과 Tryptophan의 체류 메카니즘)

  • Jin, Longmei;Yan, Hongyuan;Zheng, Jinzhu;Row, Kyung-Ho
    • KSBB Journal
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    • v.21 no.5
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    • pp.401-404
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    • 2006
  • Macroporous Poly(Methacrylic acid-co-Ethylene Glycol Dimethacrylate) Rods were in situ thermal initialized within a empty column($3.9{\times}150mm$) by free radical polymerization. The polymerization mixture was consisted of monomer, cross-linking monomer, porogenic solvent, initiator and control the ratio of these materials, column efficiency could be developed. Caffeine and tryptophan as separation substances and the retention mechanism of this kind of monolithic column was mainly hydrogen bond function.

A Study on Refresh Time Improvement of DRAM using the MEDICI Simulator (MEDICI 시뮬레이터를 이용한 DRAM의 Refresh 시간 개선에 관한 연구)

  • 이용희;이천희
    • Journal of the Korea Society for Simulation
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    • v.9 no.4
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    • pp.51-58
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    • 2000
  • The control of the data retention time is a main issue for realizing future high density dynamic random access memory. The novel junction process scheme in sub-micron DRAM cell with STI(Shallow Trench Isolation) has been investigated to improve the tail component in the retention time distribution which is of great importance in DRAM characteristics. In this' paper, we propose the new implantation scheme by gate-related ion beam shadowing effect and buffer-enhanced ${\Delta}Rp$ (projected standard deviation) increase using buffered N-implantation with tilt and 4X(4 times)-rotation that is designed on the basis of the local-field-enhancement model of the tail component. We report an excellent tail improvement of the retention time distribution attributed to the reduction of electric field across the cell junction due to the redistribution of N-concentration which is Intentionally caused by ion Beam Shadowing and Buffering Effect using tilt implantation with 4X-rotation. And also, we suggest the least requirements for adoption of this new implantation scheme and the method to optimize the key parameters such as tilt angle, rotation number, Rp compensation and Nd/Na ratio. We used MEDICI Simulator to confirm the junction device characteristics. And measured the refresh time using the ADVAN Probe tester.

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Effects of Different Hydraulic Retention Times on Contaminant Removal Efficiency Using Aerobic Granular Sludge (HRT 변경에 따른 호기성 그래뉼 슬러지의 오염원 제거효율에 미치는 영향)

  • Kim, Hyun-Gu;Ahn, Dae-Hee
    • Journal of Environmental Science International
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    • v.28 no.8
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    • pp.669-676
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    • 2019
  • The purpose of this study was to evaluate the effects of different Hydraulic Retention Times (HRTs) on the contaminant removal efficiency using Aerobic Granular Sludge (AGS). A laboratory-scale experiment was performed using a sequencing batch reactor, and the Chemical Oxygen Demand (COD), nitrogen, orthophosphate removal efficiency, AGS/MLSS ratio, and precipitability in accordance with the HRT were evaluated. As a result, the COD removal efficiency was not significantly different with the reduction in HRT, and at a HRT of 6 h, the removal rate was slightly increased owing to the increase in organic loading rate. The nitrogen removal efficiency was improved by injection of influent division at a HRT of 6 h. As the HRT decreased, the MLSS and AGS tended to increase, and the sludge volume index finally decreased to 50 mL/g. In addition, the size of the AGS gradually increased to about 1.0 mm. Therefore, the control of HRT provides favorable conditions for the stable formation of AGS, and is expected to improve the contaminant removal efficiency with the selection of a proper operation strategy.

Nitrogen Removal in the Multi-stage Bed Attached Growth Process of $A^2/O$ System with Interanal Recycle Ratio (다단층 부착성장 공법($A^2/O$향)에서 순환비에 따른 질소제거)

  • 최규철;윤용수;정일현
    • Journal of environmental and Sanitary engineering
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    • v.12 no.3
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    • pp.95-102
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    • 1997
  • The process which can stabilize water quality of treatment and improve nitrogen removal rate under the condition of high organic loading was developed by charging fibrous HBC media to single sludge nitrification-denitrification process. This process was operated easier, minimized the treatment cost, and shortened the retention time. To improve T-N removal rate, a part of nitrifing liquid at aerobic zone was recycled to anoxic zone by approximate internal recycle ratio. The experimental results are as follows ; T-N removal efficiency in the organic volumetric loading 0.14-0.19 kg/COD/m$^{3}$·d was obtained asmaxium of 85% at internal recycle ratio 2.5 and in more ratio than this it was decreased. Organic removal efficiency was about 91% under the overall experimental conditions and not influenced by recycle ratio.

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