• Polymer(Korea)
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• v.39 no.1
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• pp.56-63
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• 2015

The object of this study is to prepare microcapsules containing a diisocyanate compound, apply them to self-healing protective coating, and evaluate the self-healing capability of the coating by atmospheric moisture. Isophorone diisocyanate (IPDI) polymerized under humid atmosphere, indicating that IPDI can be used as a healing agent. Microencapsulations of IPDI were conducted via interfacial polymerization of a polyurethane prepolymer with diol compounds. The formation of microcapsules was confirmed by Fourier-transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR) spectroscopy. The mean diameter, size distribution, morphology and shell wall thickness of microcapsules were investigated by optical microscopy and scanning electron microscopy (SEM). The properties of microcapsules were studied by varying agitation rates and diol structure. The self-healing coatings were prepared on test pieces of CRC board. When scratch was generated in the coatings, the core material flew out of the microcapsules and filled the scratch. The self-healing coatings were damaged and healed under atmosphere with 68~89% relative humidity for 48 h, and SEM and impermeability test for the specimens showed that the scratch could be healed by atmospheric moisture.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.26 no.3
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• pp.254-264
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• 1990

Using the meteorological data, surface weather map, and oceanographic data for 5 years(1984-1988). I investigated the characteristics of the fog occurrence and the role of the inshore in Pusan about the fog occurrence. And the meteorological data and sea surface temperature(SST), which were observed in July, 1989 in Suyoung Bay, were compared with those in Pusan. The fogs in Pusan concentrate in May, June and July. And at fog occurrence time the principal wind directions are Southwest(SW) winds, which easily supply with water vapor, and a series of Northeast(NE) wind. At the fog days pressure patterns are pattern 7 in spring time (March, April, and May) and pattern 10 and pattern 13 in summer time (June, July, and August). Also the advection fog(sea fog) is closely related with the relationship between warm and cold advection in 850~700mb and cold and warm SST rather than the increase of the instability of atmosphere in 850~500mb. The fogs in Taegu, which is the inland region, mainly occur at dawn in fall time due to the strong night radiation fog. On the other hand in Pusan the coastal region, the fogs occur from late spring time to summer time (May, June, and July). Because there is the abundant supply of the water vapor from the ocean owing to a series of South(S) wind at this time. Then the atmosphere, which has high relative humidity, reaches easily the supersaturation by the radiation cooling. In Suyoung Bay and Pusan the meteorological observation data, SST and fog days are almost similar. And I think that the mechanism of the fog occurrence nearly accords with both regions.

• Journal of Practical Agriculture & Fisheries Research
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• v.18 no.1
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• pp.63-70
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• 2016

This study was conducted to investigate the effect of atmosphere-leaf vapor pressure deficit (VPD) in Heracleum moellendorffii and Aruncus dioicus var. kamtschaticus. The VPD was rapidly increased with increasing temperature and decreasing relative humidity. Taken as a whole, the stomatal transpiration reaction was slightly late with increasing of VPD. Maximum photosynthetic rate at high-VPD condition was 6.49 µmol CO₂·m^-2·s^-1 in Heracleum moellendorffii Hance, which was a little lower than 5.57 µmol CO₂·m^-2·s^-1 in Aruncus dioicus var. kamtschaticus, respectively. After 2 p.m, stomatal transpiration of Heracleum moellendorffii at the high VPD condition was rapidly decreased. The results indicated that physiological activities in Heracleum moellendorffii are more limited from high VPD conditions.

• Atmosphere
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• v.25 no.1
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• pp.185-191
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• 2015

Ambient measurements of aerosol light absorption (${\sigma}_a$) and scattering coefficients (${\sigma}_s$) were done at Gosan climate observatory during summer 2008 using a 3-wavelength photoacoustic soot spectrometer (PASS). PASS was deployed photoacoustic method for light absorption and integrated nephelometry for light scattering measurements. The ${\sigma}_a$ and ${\sigma}_s$ from PASS were compared with those from co-located aethalometer and nephelometer measurements. The aethalometer measurements of ${\sigma}_a$ correlated reasonably well with photoacoustic measurements, but the slope of the linear fitting line indicated the PASS measurement values of ${\sigma}_a$ were larger by a factor of 1.53. The nephelometer measurement values of ${\sigma}_s$ correlated very well with PASS measurements of ${\sigma}_s$, with a slope of 1.12 and a small offset. Comparing to the aethalometer measurements, the photoacoustic measurements of ${\sigma}_a$ didn't exhibit a significant (i.e., the ratio between aethalometer and PASS increased) change with increasing relative humidity (RH). The ratio of ${\sigma}_s$ between nephelometer and PASS increased with increasing RH, especially when the RH increased beyond 80%. This apparent increase in ${\sigma}_s$ with RH may be due to the contribution of hygroscopic growth of aerosols.

• Journal of Korean Society for Atmospheric Environment
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• v.21 no.4
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• pp.439-458
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• 2005

An automated analysis system for water soluble constituents in $PM_{2.5}$ has been developed. The system consists of a high capacity multi tube diffusion scrubber (MTDS), a low temperature particle impactor (LTPI), and two ion (anion and cation) chromatography (IC) systems. Atmospheric particles have been collected by passing sample air through a thermostated MTDS followed by a LTPI. This system allows simultaneous measurements of soluble ions in $PM_{2.5}$ at 30 minutes interval. At the air sampling flow rate of 1.0L/min, the detection limits of the overall system are in the order of tens of $ng/m^3$. This system has been successfully used for the measurement of particulate components of Seoul air from April 2003 to January 2004. $SO_4^{2-},\;NO_3^-,\;NH_4^+,\;NO_2^-,\;Cl^-,\;Na^+,\;K^+,\;Ca^{2+},\;and\;Mg^{2+}$ are the major ionic species for $PM_{2.5}$ at Seoul. Among them, $SO_4^{2-},\;NO_3^-\;and\;NH_4^+$ are the most abundant ions, contributed up to $86\%$ of the total and the concentrations were higher than those in any other urban sites in the world except for Chinese cities. There are high pollutant episodes which contribute about $15\~20\%$ of annual average values of the major ions. During the episode, the all parcels were transported from the asian continent and $PM_{2.5}$ were significantly neutralized. This suggests that aged and long range transported pollutants caused the high pollutant episodes. They showed a distinct daily and seasonal variations:they showed a peak in the early morning caused by the night-time accumulation of particulate matters. Atmospheric reactions including gas-to-particle reactions and inter-particle reactions and meteorological parameters including relative humidity and ambient temperature were described with related to the $PM_{2.5}$ 5 concentrations. All of the ionic species showed higher concentrations during the spring than those for summer and winter.

• Korean Journal of Remote Sensing
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• v.36 no.6_1
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• pp.1407-1419
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• 2020

Long time-series gridded data is crucial for the analyses of Earth environmental changes. Climate reanalysis and satellite images are now used as global-scale periodical and quantitative information for the atmosphere and land surface. This paper examines the feasibility of DCT-PLS (penalized least square regression based on discrete cosine transform) for the spatial gap filling of gridded data through the experiments for multiple variables. Because gap-free data is required for an objective comparison of original with gap-filled data, we used LDAPS (Local Data Assimilation and Prediction System) daily data and MODIS (Moderate Resolution Imaging Spectroradiometer) monthly products. In the experiments for relative humidity, wind speed, LST (land surface temperature), and NDVI (normalized difference vegetation index), we made sure that randomly generated gaps were retrieved very similar to the original data. The correlation coefficients were over 0.95 for the four variables. Because the DCT-PLS method does not require ancillary data and can refer to both spatial and temporal information with a fast computation, it can be applied to operative systems for satellite data processing.

• Economic and Environmental Geology
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• v.46 no.4
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• pp.339-344
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• 2013

Water vapor isotopes can be excellent tools for understanding complex mechanisms in the water cycle and atmospheric hydrological cycle and they can be applied to various fields of paleoclimatology, atmospheric science, hydrogeology, oceanography, and ecohydrology. Thus, studies of global or local transport of water vapor may be able to provide a very useful clue to better understand the movements of water and energy in the atmosphere, hydrosphere and biosphere. In this study, the isotopic compositions of water vapor have been observed for moisture transport during the passage of Typhoon Bolaven at Korea Polar Research Institute (KOPRI), Incheon, in the western part of Korea, from August 27 to August 29, 2012. In the clear sky, the isotopic compositions of water vapor at KOPRI exhibited relatively higher isotopic ratios, which were near isotopic equilibrium with sea surface water (${\delta}^{18}O$=-14‰). On the other hand, a largely depleted isotopic ratios in surface water vapor were observed in association with the passage of Typhoon Bolaven (approximately 10‰ depleted compared to the clear sky). The fact that the isotopic minima in water vapor are encountered during the onset period of the Typhoon Bolaven with increases of relative humidity, which is consistent with, so called, "the amount effect".

• Atmosphere
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• v.21 no.1
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• pp.35-44
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• 2011

We investigated characteristics of new particle formation and growth events observed at Gosan climate observatory using Scanning Mobility Particle Sizer (SMPS) measurements of particle number size distribution with 54 size ranges from 10 to 487 nm in October 2009. Four days (17~20 October) and five days (22~26 October) were classified into strong new particle formation and growth event ($N_S$) and weak particle formation and growth event ($N_W$), respectively. $N_S$ and $N_W$ divided by increase of aerosol number concentration in nucleation mode and continuity of growth from nucleation to Aitken mode. Particle growth rates of $N_S$ (5.34~$9.19nm\;h^{-1}$) were greater than that of $N_W$ (2.15~$3.53nm\;h^{-1}$). $N_S$ and $N_W$ were analyzed with synoptic pattern over East Asia, meteorological elements, and sulfur dioxide ($SO_2$) measured at Gosan. We found that $N_S$ was characterized by a fast and northwesterly wind accompanied cold and dry airmass, but $N_W$ was affected airmass originated from South China and come through the Korea Peninsula. The events ($N_S$ and $N_W$) occurred at conditions of high solar flux ($&gt;700W\;m^{-2}$) and low relative humidity (< 60%). The $SO_2$ concentration on $N_S$ and $N_W$ was higher than that on case of non observed new particle formation.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.40 no.3
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• pp.285-294
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• 2020

This study investigated the use of Ground Penetrating Radar (GPR) over a two-decade period on public roads, focusing on the electromagnetic characteristics of the pavement dielectrics and attenuation. From the results, a typical range of characteristic value, influencing factors, and a correction method were suggested. The typical dielectrics of asphalt pavements were 4-7, as measured by an air-coupled 1 GHz GPR antenna. The dielectrics of concrete pavements were very large in the early age, but were drastically reduced with ageing. Ten years on, collection was in the range of 6-12. The dielectrics were proportional to the relative humidity (R.H.) of the atmosphere. The effects were reduced to one eighth with an overlay. Attenuation generally increased with thickness of the road layer, and also increased where there was damage. The GPR results could also vary depending on the weather conditions as well as on the characteristics of the GPR equipment, even at the same frequency. Therefore, GPR surveys should be performed on road surfaces without debris on a single, fine day. The reliability of the GPR analysis could be improved by cores and equipment calibration with other non-destructive test surveys.

• Atmosphere
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• v.26 no.1
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• pp.111-126
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• 2016

In the numerical weather model, surface properties can be defined by various parameters such as terrain height, landuse, surface albedo, soil moisture, surface emissivity, roughness length and so on. And these parameters need to be improved in the Seoul metropolitan area that established high-rise and complex buildings by urbanization at a recent time. The surface roughness length map is developed from digital elevation model (DEM) and it is implemented to the high-resolution numerical weather (WISE-WRF) model. Simulated results from WISE-WRF model are analyzed the relationship between meteorological variables to changes in the surface roughness length. Friction speed and wind speed are improved with various surface roughness in urban, these variables affected to temperature and relative humidity and hence the surface roughness length will affect to the precipitation and Planetary Boundary Layer (PBL) height. When surface variables by the WISE-WRF model are validated with Automatic Weather System (AWS) observations, NEW experiment is able to simulate more accurate than ORG experiment in temperature and wind speed. Especially, wind speed is overestimated over $2.5m\;s^{-1}$ on some AWS stations in Seoul and surrounding area but it improved with positive correlation and Root Mean Square Error (RMSE) below $2.5m\;s^{-1}$ in whole area. There are close relationship between surface roughness length and wind speed, and the change of surface variables lead to the change of location and duration of precipitation. As a result, the accuracy of WISE-WRF model is improved with the new surface roughness length retrieved from DEM, and its surface roughness length is important role in the high-resolution WISE-WRF model. By the way, the result in this study need various validation from retrieved the surface roughness length to numerical weather model simulations with observation data.