• Title/Summary/Keyword: Reactive dyes

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Manufacturing and Characterization of N-doped TiO2 Photocatalytic Thin Film (N 도핑된 TiO2 광촉매 박막의 제조 및 특성분석)

  • Park, Sang-Won;Nam, Soo-Kyung;Heo, Jae-Eun
    • Journal of Environmental Science International
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    • v.16 no.6
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    • pp.683-688
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    • 2007
  • In this study, N doped $TiO_2$ (TiO-N) thin film was prepared by DC magnetron sputtering method to show the photocatalytic activity in a visible range. Various gases (Ar, $O_2\;and\;N_2$) were used and Ti target was impressed by 1.2 kW -5.8 kW power range. The hysteresis of TiO-N thin film as a function of discharge voltage wasn't observed in 1.2 and 2.9kW of applied power. Cross sections and surfaces of thin films by FE-SEM were tiny and dense particle sizes of both films with normal cylindrical structures. XRD pattern of $TiO_2$ and TiO-N thin films was appeared by only anatase peak. Red shift in UV-Vis adsorption spectra was investigated TiO-N thin film. Photoactivity was evaluated by removal rate measurement of suncion yellow among reactive dyes. The photodegradation rate of $TiO_2$ thin film on visible radiation was shown little efficiency but TiO-N was about 18%.

Methacrylamide graft polymerization on silk fibroin dyed with reactive dyestuffs (반응염색견(反應染色絹)의 Methacrylamide graft 중합(重合))

  • Rhee, In Jeon;Lee, Dong Soo
    • Current Research on Agriculture and Life Sciences
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    • v.12
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    • pp.83-95
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    • 1994
  • Fixation rate of reactive dyes on silk fibroin showed the same tendency to absorption rate. Fixation rate of Yellow 179 and Blue 71 was quite slow and Black 5, Blue 49, Blue 4, Blue 19 and Blue 21 was relatively fast. Weight increase by MAA graft polymerization onto filk fibroin was decreased, on the whole, according to the the increase of dye fixation, but weight increase of silk fibroin dyed with Blue 71 and Blue 21 was much higher than that of silk fibroin. And weight increase of silk fibroin dyed with Yellow 179 was similar to that of silk fibroin and in case of Blue 19, weight increase was about 12%, constantly. Weight increase of silk fibroin dyed with Blue 71 and Blue 21 was higher and the others were lower than of silk fibroin. And weight increase was diminished according as the dyeing temperature rises. The color was a little changed by MAA graft polymerization.

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The Color Fading and Staining of Fabrics by Drum-type Washer (드럼세탁기 사용시 세탁물의 변.퇴색 방지에 관한 연구)

  • Ryu, Hyo-Seon;Kim, Eun-Ah;Yun, Chang-Sang
    • Journal of the Korean Society of Clothing and Textiles
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    • v.32 no.6
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    • pp.947-958
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    • 2008
  • To study the effect of a washing machine with silver nano technology on its detergency, the discoloring of the dyed clothes and the staining of standards adjacent fabrics were examined. As the laundry specimen, cotton fabric dyed with reactive dyes and Polyester fabric dyed with disperse dyes were chosen; and as the adjacent fabrics, undyed cotton. polyester and nylon fabrics were chosen. The colorfastness was evaluated after washing under conditions that those washing temperature, liquor ratio, detergency concentration and the type of water were varied. When the clothes were washed with the tap water contains silver ion, the deposition of silver compounds into the washed clothes was measured. As a results, after the washing in the various conditions, discoloring of the dyed clothes was not intense. The higher the washing temperature and the lower the liquor ratio, the larger the staining appeared on the white fabrics; especially for the white nylon fabrics. The concentration of detergent and the type of water affected hardly the colorfastness. After the repeated washing with the water contains silver, whiteness of the cotton and the nylon fabrics were lower than the result after the washing with the tap water, and a quantity of silver ions was found on the washed clothes.

Dyeing and Photochromic Properties of Golden Yellow Reactive Dyes (Golden yellow 반응성 염료의 염색성 및 광변색 특성)

  • Lee, Jung-Jin;Kim, Hyun-Sung;Shin, Eun-Suk
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.32-32
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    • 2011
  • 염료의 포토크로미즘은 빛을 받았을 때, 염료의 분자구조가 변환되어 흡수파장이 달라지고 결과적으로 원래 색과 다른 색상을 나타내는 현상을 말한다. 대부분의 Golden yellow 색상을 나타내는 아조계 반응성염료는 Trans-Cis 간의 이성질체 전환을 통해 포토크로미즘 현상을 나타내며, 가역적으로 복색되기는 하지만 상업적으로 많은 문제와 불편을 초래한다. 한편 pyrazolone계 아조염료는 azo form 보다는 hydrazone form으로 더 많이 존재하는 것으로 알려져 있으며, 이로인해 상대적으로 Trans-Cis 이성질화가 잘 일어나지 않아 포토크로미즘 현상이 잘 일어나지 않을 것으로 기대된다. 이 연구에서는 3종의 pyrazolone계 golden yellow 반응성 염료를 합성하고, 합성한 염료를 면직물에 염색하여 염색성 및 견뢰도를 평가하였다. 또한 시판되고 있는 아조계 golden yellow 반응성 염료 4종을 선정하여 역시 염색성과 견뢰도 특성을 알아보았다. 그리고 7가지 염료의 광변색 특성을 조사하기 위해 포토크로미즘 평가방법인 ISO 105-B05법 및 이전 연구에서 제안된 광변색 평가방법을 사용하였다. ISO 105-B05법은 표준청색염포가 grey scale 4등급이 되는 시간을 구한 다음 이 시간의 1/4시간동안 조사한 후 포토크로미즘을 평가하는 것이며, 후자의 경우는 4시간동안 광조사된 시험편을 측색하고 시간에 따른 복색되는 정도를 평가한다. 합성한 pyrazolone계 염료들은 394-408nm의 최대흡수파장은 나타내었다. 7종의 yellow 반응성 염료들은 모두 면직물에 우수한 염색성 및 build-up성을 나타내었으며, 대체적으로 양호한 견뢰도를 얻었다. 또한 광변색 특성 평가결과 모든 염료들은 ISO 평가방법에 대하여 non-photochromic 특성으로 나타났으나, 다른 광변색 평가 결과 일부 염료들에 있어서 photochromic 특성이 있는 것으로 나타나 평가방법에 따라 차이를 보였다.

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Silibinin Induces Apoptotic Cell Death Via ROS-dependent Mitochondrial Pathway in Human Glioma Cells

  • Shin, Won-Yong;Jeong, Ji-Cheon
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.23 no.4
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    • pp.888-894
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    • 2009
  • It has been reported that silibinin, a natural polyphenolic flavonoid, induces cell death in various cancer cell types. However, the underlying mechanisms by which silibinin induces apoptosis in human glioma cells are poorly understood. The present study was therefore undertaken to examine the effect of silibinin on glioma cell apoptosis and to determine its underlying mechanism in human glioma cells. Apoptosis was estimated by FACS analysis. Reactive oxygen species (ROS) generation and mitochondrial membrane potential (${\Psi}m$) were measured using fluorescence dyes DCFH-DA and $DiOC_6$(3), respectively. Cytochrome c release from mitochondria and caspase-3 activation were estimated by Western blot analysis using specific antibodies. Exposure of cells to 30 mM silibinin induced apoptosis starting at 6 h, with increasing effects after 12-48h in a time-dependent manner. Silibinin caused ROS generation and disruption of ym, which were associated with the silibinin-induced apoptosis. The silibinin-induced ROS generation and disruption in ym were prevented by inhibitors of mitochondrial electron transport chain. The hydrogen peroxide scavenger catalase blocked ROS generation and apoptosis induced by silibinin. Silibinin induced cytochrome c release into cytosolic fraction and its effect was prevented by catalase and cyclosporine A. Silibinin treatment caused caspase-3 activation, which was inhibited by DVED-CHO and cyclosporine A. Pretreatment of caspase inhibitors also protected against the silibinin-induced apoptosis. These findings indicate that ROS generation plays a critical role in the initiation of the silibinin-induced apoptotic cascade by mediation of the mitochondrial apoptotic pathway including the disruption of ${\Psi}m$, cytochrome c release, and caspase-3 activation.

Protective Effect of Vitis amurensis Stems and Leaves Extract on Hydrogen Peroxide-induced Oxidative Neuronal Cell Damage in Cultured Neurons (과산화수소수로 유도된 배양 뇌신경세포손상에 대한 왕머루 잎과 줄기 추출물의 보호효과)

  • Kim, Joo-Youn;Ju, Hyun-Soo;Ban, Ju-Yeon;Song, Kyung-Sik;Bae, Ki-Hwan;Seong, Yeon-Hee
    • Korean Journal of Medicinal Crop Science
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    • v.17 no.1
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    • pp.68-74
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    • 2009
  • Vitis amurensis (VA; Vitaceae) has long been used in oriental herbal medicine. It has been reported that roots and seeds of VA have anti-inflammatory and antioxidant effects. In the present study, the protective effect of ethanol extract from stems and leaves of VA on hydrogen peroxide (${H_2}{O_2}$) (100 ${\mu}M$)-induced neuronal cell damage was examined in primary cultured rat cortical neurons. VA (10-100 ${\mu}g$/ml) concentration-dependently inhibited ${H_2}{O_2}$-induced apoptotic neuronal cell death measured by 3-[4,5-Dimethylthiazol-2-yl]-2,5-diphenyl-tetrazolium bromide (MTT) assay and Hoechst 33342 staining. VA inhibited ${H_2}{O_2}$-induced elevation of intracellular $Ca^{2+}$ concentration (${[Ca^{2+}]}_i$) and generation of reactive oxygen species (ROS), which were measured by fluorescent dyes. Pretreatment of VA also prevented glutamate release into medium induced by 100 ${\mu}M$ ${H_2}{O_2}$, which was measured by HPLC. These results suggest that VA showed a neuroprotective effect on ${H_2}{O_2}$-induced neuronal cell death by interfering with ${H_2}{O_2}$-induced elevation of ${[Ca^{2+}]}_i$, glutamate release, and ROS generation. This has a significant meaning of finding a new pharmacological activity of stems and leaves of VA in the CNS.

Moutan Cortex Extract Inhibits Amyloid ${\beta}$ Protein (25-35)-induced Neurotoxicity in Cultured Rat Cortical Neurons (Amyloid ${\beta}$ 2 Protein (25-35) 유도 배양신경세포 독성에 대한 목단피의 억제효과)

  • Kim, Joo-Youn;Ju, Hyun-Soo;Ban, Ju-Yeon;Song, Kyung-Sik;Seong, Yeon-Hee
    • Korean Journal of Medicinal Crop Science
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    • v.16 no.6
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    • pp.409-415
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    • 2008
  • Moutan cortex, the root bark of Paeonia suffruticosa Andrews (Paeoniaceae), has pharmacological effects such as anti-inflammatory, antiallergic, analgesic and antioxidant activities. We investigated a methanol extract of Moutan cortex for neuroprotective effects on neurotoxicity induced by amyloid ${\beta}$ protein ($A{\beta}$) (25-35) in cultured rat cortical neurons. Exposure of cultured cortical neurons to $10\;{\mu}M\;A{\beta}$ (25-35) for 24 h induced neuronal apoptotic death. Moutan cortex inhibited $10\;{\mu}M\;A{\beta}$ (25-35)-induced neuronal cell death at 30 and $50\;{\mu}g/m{\ell}$, which was measured by a 3-[4,5-dimethylthiazol-2-yl]-2,5-diphenyl-tetrazolium bromide (MTT) assay and Hoechst 33342 staining. Moutan cortex inhibited $10\;{\mu}M\;A{\beta}$ (25-35)-induced elevation of intracellular calcium concentration ($[Ca^{2+}]_i$), and generation of reactive oxygen species (ROS) which were measured by fluorescent dyes. Moutan cortex also inhibited glutamate release into medium induced by $10\;{\mu}M\;A{\beta}$ (25-35), which was measured by HPLC. These results suggest that Moutan cortex prevents $A{\beta}$ (25-35)-induced neuronal cell damage by interfering with the increase of $[Ca^{2+}]_i$, and then inhibiting glutamate release and ROS generation. Moutan cortex may have a therapeutic role in preventing the progression of Alzheimer's disease.

Analysis of Characteristics and Optimization of Photo-degradation condition of Reactive Orange 16 Using a Box-Behnken Method (실험계획법 중 Box-Behnken(박스-벤켄)법을 이용한 반응성 염료의 광촉매 산화조건 특성 해석 및 최적화)

  • Cho, Il-Hyoung;Lee, Nae-Hyun;Chang, Soon-Woong;An, Sang-Woo;Yonn, Young-Han;Zoh, Kyung-Duk
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.9
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    • pp.917-925
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    • 2006
  • The aim of our research was to apply experimental design methodology in the optimization of photocatalytic degradation of azo dye(Reactive orange 16). The reactions were mathematically described as a function of parameters amount of $TiO_2(x_1)$, and dye concentration($x_2$) being modeled by the use of the Box-Behnken method. The results show that the responses of color removal(%)($Y_1$) in photocatalysis of dyes were significantly affected by the synergistic effect of linear term of $TiO_2(x_1)$ and dye concentration($x_2$). Significant factors and synergistic effects for the $COD_{Cr}$, removal(%)($Y_2$) were the linear term of $TiO_2(x_1)$ and dye concentration($x_2$). However, the quadratic term of $TiO_2(x_1^2)$ and dye concentration($x_2^2$) had an antagonistic effect on $Y_1$ and $Y_2$ responses. Canonical analysis indicates that the stationary point was a saddle point for $Y_1$ and $Y_2$, respectively. The estimated ridge of maximum responses and optimal conditions for $Y_1:(X_1,\;X_2)$=(1.11 g/L, 51.2 mg/L) and $Y_2:(X_1,\;X_2)$=(1.42 g/L, 72.83 mg/L) using canonical analysis was 93% and 73%, respectively.

Studies on the Rapid Discrimination of Yellow Pigments Colored on Yellow Croakers and Natural Yellow Pigment of Croakers (참조기의 천연색소와 인위적으로 착색된 황색색소류 판별법에 관한 연구)

  • Kim, Hee-Yun;Hong, Jin-Hwan;Kim, Dong-Sul;Han, Sang-Bae;Lee, Eun-Ju;Lee, Jeung-Seung;Kang, Kil-Jin;Chung, Hyung-Wook;Song, Kyung-Hee;Park, Hye-Kyung;Park, Jong-Seok;Kwon, Yong-Kwan;Chin, Myung-Shik;Park, Hee-Ok;Oh, Sae-Hwa;Shin, Il-Shik;Lee, Chang-Kook;Park, Hee-Yul;Ha, Sang-Chul;Jo, Jae-Sun
    • Korean Journal of Food Science and Technology
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    • v.34 no.6
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    • pp.977-983
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    • 2002
  • This study was performed to establish the precise and rapid method to distinguish croakers through the pigment analysis of colored imported white croakers for adultration. We surveyed the coloring behaviors, extraction test by water and organic solvent and using pigments such as targeting, curcumine, and azo dye products. The pigment of yellow croaker is not stained on wet cloth or tissue which is rubbed on epidermis of yellow croaker and was not eluted in water extraction test, while adulterated pigments were easily extracted by water and acetone, but edible diluted yellow, Yellow No. 4 and Yellow No. 5 were not extracted. Reactive pigment was detected easily by extraction with water and dispersed pigment was also detected by extraction test. As a result of discoloring characteristics of carotene having similar structure to yellow croaker and azo dye by oxidation and reduction, azo dyes were not discolored by oxidation with sodium percarbonate or peracetic acid but that were discolored by oxidation with Fenton reagent after 1hr and by hypochlorite promptly. On the other hand, carotenes were not discolored by sodium precarbonate and Fenton reagent but discolored by sodium hypochlorite after 2 hr and by peracetic acid promptly. Azo dyes were discolored by reduction with sodium hydrosulfite and sodium carbonate but carotenes were not discolored by these reagents. This discoloring test was applicable to detect adulterated pigments and other marine product.

Studies on Photocatalytic Thin Films($TiO_2$, TiO-N) Manufactured by DC Magnetron Sputtering Method and it's Characteristics for Removal of Pollutants (DC 마그네트론 스퍼터링법을 이용한 광촉매박막($TiO_2$, TiO-N)제조 및 오염물질 제거에 관한 연구)

  • Jeong, Weon-Sang;Park, Sang-Weon
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.1
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    • pp.59-66
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    • 2005
  • [ $TiO_2$ ] was deposited by DC magnetron sputtering on glass surface under various sputtering parameters such as discharge power($0.6{\sim}5.2\;kW$, substrate temperature($R.T{\sim}350^{\circ}C$), Ar and $O_2$ flow ratio with $0{\sim}50\;sccm$($Ar+O_2$ 90 sccm) and about 1 mtorr of pressure. TiO-N thin film was prepared under same sputtering conditions for $TiO_2$ thin film except flow ratio($Ar+O_2+N_2$ 90 sccm). The sheet resistance of thin films deposited under these parameters was measured to analyze electronic characteristic and thin film's thickness(${\alpha}$-step), surface roughness(AFM) and formation construction(FE-SEM, XRD) were also measured to draw optimal sputtering parameters. In order to evaluate photo-activity of thin film($TiO_2$, TiO-N) made in optimal parameters for removal of pollutants, toluene among VOCs and Suncion Yellow among reactive dyes were chosen to probe organic compounds for photo-degradation. It was shown that the photo-catalytic thin films had a significant photo-activation for the chosen contaminants and especially TiO-N thin film showed maximum efficiency of 33% for toluene(5 ppm) removal in visible-light range.