• 제목/요약/키워드: Reaction diffusion system

검색결과 170건 처리시간 0.021초

GLOBAL EXISTENCE AND BLOW-UP FOR A DEGENERATE REACTION-DIFFUSION SYSTEM WITH NONLINEAR LOCALIZED SOURCES AND NONLOCAL BOUNDARY CONDITIONS

  • LIANG, FEI
    • 대한수학회지
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    • 제53권1호
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    • pp.27-43
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    • 2016
  • This paper deals with a degenerate parabolic system with coupled nonlinear localized sources subject to weighted nonlocal Dirichlet boundary conditions. We obtain the conditions for global and blow-up solutions. It is interesting to observe that the weight functions for the nonlocal Dirichlet boundary conditions play substantial roles in determining not only whether the solutions are global or blow-up, but also whether the blowing up occurs for any positive initial data or just for large ones. Moreover, we establish the precise blow-up rate.

외부 및 내부 확산을 적용한 인도네시아 석탄촤의 연소 반응율 분석 (Reaction Rate Analysis of Combustion for Indonesian Coal Char Applied by External/Internal Diffusion)

  • 황찬원;김량균;류광일;오택림;전충환
    • Korean Chemical Engineering Research
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    • 제52권1호
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    • pp.133-140
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    • 2014
  • 본 연구의 목적은 국내 화력발전소에서 사용중인 인도네시아 석탄촤의 연소반응율을 연구하는 것이다. 석탄촤의 반응율은 External, Internal effectiveness factor를 고려하여 입자 내부 및 외부확산을 정량적으로 정리하였으며, Random pore model을 사용하여 탄소변환율에 따른 입자내부비표면적의 변화를 반영하였다. 가열 및 측정이 가능한 WHR(Wire Heating Reactor)를 활용하여 반응시간을 측정함으로써 석탄촤의 반응율을 도출하였고 BET(Brunauer-Emmett-Teller) 및 TGA(Thermo-Gravimetric Analysis) 장비를 활용하여 석탄촤의 물리적인 특성인 내부비표면적과 Random pore model의 구조변수(${\Psi}$)를 측정하였다. 석탄 종에 따른 활성화에너지 및 빈도인자를 도출하기 위해 아역청탄인 BARAMULTI, ENERGYMAN, AGM탄을 사용하였다. 본 연구 결과에서 External, Internal effectiveness factors를 통해 확산에 따른 kinetics를 비교한 결과 외부 확산 보다 내부 확산의 영향이 지배적임을 확인하였다. 최종적으로 내부 및 외부 확산에 대한 영향을 고려한 3종의 석탄촤 Intrinsic kinetics의 활성화에너지는 110~118 kJ/mol의 값을 보였다.

용융 Si-C-SiC계에서 $\beta$-SiC 생성기구 ($\beta$-SiC Formation Mechanisms in Si Melt-C-SiC System)

  • 서기식;박상환;송휴섭
    • 한국세라믹학회지
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    • 제36권6호
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    • pp.655-661
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    • 1999
  • ${\beta}$-SiC formation mechanism in Si melt-C-SiC system with varying in size of carbon source was investigated. A continuous reaction sintering process using Si melt infiltration method was adopted to control the reaction sintering time effectively. It was found that ${\beta}$-SiC formation mechanism in Si melt-C-SiC system was directly affected by the size of carbon source. In the Si melt-C-SiC system with large carbon source ${\beta}$-SiC formation mechanism could be divided into two stages depending on the reaction sintering time: in early stage of reaction sintering carbon dissolution in Si melt and precipitation of ${\beta}$-SiC was occurred preferentially and then SIC nucleation and growth was controlled by diffusion of carbon throughy the ${\beta}$-SiC layer formed on graphite particle. Furthmore a dissolution rate of graphite particles in Si melt could be accelerated by the infiltration of Si melt through basal plane of graphite crystalline.

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BIFURCATIONS IN A HUMAN MIGRATION MODEL OF SCHEURLE-SEYDEL TYPE-II: ROTATING WAVES

  • Kovacs, Sandor
    • Journal of applied mathematics & informatics
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    • 제16권1_2호
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    • pp.69-78
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    • 2004
  • This paper treats the conditions for the existence of rotating wave solutions of a system modelling the behavior of students in graduate programs at neighbouring universities near each other which is a modified form of the model proposed by Scheurle and Seydel. We assume that both types of individuals are continuously distributed throughout a bounded two-dimension spatial domain of two types (circle and annulus), across whose boundaries there is no migration, and which simultaneously undergo simple (Fickian) diffusion. We will show that at a critical value of a system-parameter bifurcation takes place: a rotating wave solution arises.

Correlation between rare earth elements in the chemical interactions of HT9 cladding

  • Lee, Eun Byul;Lee, Byoung Oon;Shim, Woo-Yong;Kim, Jun Hwan
    • Nuclear Engineering and Technology
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    • 제50권6호
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    • pp.915-922
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    • 2018
  • Metallic fuel has been considered for sodium-cooled fast reactors because it can maximize the uranium resources. It generates rare earth elements as fission products, where it is reported by aggravating the fuel-cladding chemical interaction at the operating temperature. Rare earth elements form a multicomponent alloy (Ce-Nd-Pr-La-Sm-etc.) during reactor operation, where it shows a higher reaction thickness than a single element. Experiments have been carried out by simplifying multicomponent alloys for mono or binary systems because complex alloys have difficulty in the analysis. In previous experiments, xCe-yNd was fabricated with two elements, Ce and Nd, which have a major effect on the fuel-cladding chemical interaction, and the thickness of the reaction layer reached maximum when the rare earth elements ratio was 1:1. The objective of this study is to evaluate the effect and relationship of rare earth elements on such synergistic behavior. Single and binary rare earth model alloys were prepared by selecting five rare earth elements (Ce, Nd, Pr, La, and Sm). In the single system, Nd and Pr behaviors were close to diffusion, and Ce showed a eutectic reaction. In the binary system, Ce and Sm further increased the reaction layer, and La showed a non-synergy effect.

WELL-POSEDNESS AND ASYMPTOTIC BEHAVIOR OF PARTLY DISSIPATIVE REACTION DIFFUSION SYSTEMS WITH MEMORY

  • Vu Trong Luong;Nguyen Duong Toan
    • 대한수학회보
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    • 제61권1호
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    • pp.161-193
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    • 2024
  • In this paper, we consider the asymptotic behavior of solutions for the partly dissipative reaction diffusion systems of the FitzHugh-Nagumo type with hereditary memory and a very large class of nonlinearities, which have no restriction on the upper growth of the nonlinearity. We first prove the existence and uniqueness of weak solutions to the initial boundary value problem for the above-mentioned model. Next, we investigate the existence of a uniform attractor of this problem, where the time-dependent forcing term h ∈ L2b(ℝ; H-1(ℝN)) is the only translation bounded instead of translation compact. Finally, we prove the regularity of the uniform attractor A, i.e., A is a bounded subset of H2(ℝN) × H1(ℝN) × L2µ(ℝ+, H2(ℝN)). The results in this paper will extend and improve some previously obtained results, which have not been studied before in the case of non-autonomous, exponential growth nonlinearity and contain memory kernels.

하이브리드 연소의 수치 모델링 전략에 관한 연구 (Study on the Strategy of Numerical Modeling for Hybrid Combustion)

  • 윤창진;김진곤;문희장
    • 항공우주시스템공학회지
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    • 제1권2호
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    • pp.37-42
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    • 2007
  • This paper proposes a numerical modeling approach to simulate the hybrid combustion phenomena. From the physical understandings of hybrid combustion, the computational domain was separated into three regions: the solid fuel, gas phase reactive flow, and the interface between solid and fluid. Moreover, for the accurate calculation, computational grids for these regions was generated at every time step considering the instantaneous moving interface which are governed by the balance equations using thermal pyrolysis. In the domain of reactive flow, by virtue of diffusion flame structure, turbulent combustion modeling was introduced using either mixture fraction approach or mean reaction rate approach.

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Geometric and mechanical properties evaluation of scaffolds for bone tissue applications designing by a reaction-diffusion models and manufactured with a material jetting system

  • Velasco, Marco A.;Lancheros, Yadira;Garzon-Alvarado, Diego A.
    • Journal of Computational Design and Engineering
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    • 제3권4호
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    • pp.385-397
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    • 2016
  • Scaffolds are essential in bone tissue engineering, as they provide support to cells and growth factors necessary to regenerate tissue. In addition, they meet the mechanical function of the bone while it regenerates. Currently, the multiple methods for designing and manufacturing scaffolds are based on regular structures from a unit cell that repeats in a given domain. However, these methods do not resemble the actual structure of the trabecular bone which may work against osseous tissue regeneration. To explore the design of porous structures with similar mechanical properties to native bone, a geometric generation scheme from a reaction-diffusion model and its manufacturing via a material jetting system is proposed. This article presents the methodology used, the geometric characteristics and the modulus of elasticity of the scaffolds designed and manufactured. The method proposed shows its potential to generate structures that allow to control the basic scaffold properties for bone tissue engineering such as the width of the channels and porosity. The mechanical properties of our scaffolds are similar to trabecular tissue present in vertebrae and tibia bones. Tests on the manufactured scaffolds show that it is necessary to consider the orientation of the object relative to the printing system because the channel geometry, mechanical properties and roughness are heavily influenced by the position of the surface analyzed with respect to the printing axis. A possible line for future work may be the establishment of a set of guidelines to consider the effects of manufacturing processes in designing stages.

A Kinetic Study of Biphenyl Type Epoxy-Xylok Resin System with Different Kinds of Catalysts

  • 한승;김환근;윤호규;문탁진
    • Bulletin of the Korean Chemical Society
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    • 제18권11호
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    • pp.1199-1203
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    • 1997
  • The investigation of cure kinetics of biphenyl epoxy (4,4-diglycidyloxy-3,3,5,5-tetramethyl biphenyl)-xylok resin system with four different catalysts was performed by differential scanning calorimeter using an isothermal approach. All kinetic parameters of the curing reaction including the reaction order, activation energy and rate constant were calculated and reported. The results indicate that the curing reaction of the formulations using triphenylphosphine (TPP) and 1-benzyl-2-methylimidazole (1B2MI) as a catalyst proceeds through a first order kinetic mechanism, whereas that of the formulations using diazabicyloundecene (DBU) and tetraphenyl phosphonium tetraphenyl borate (TPP-TPB) proceeds by an autocatalytic kinetic mechanism. To describe the cure reaction in the latter stage, we have used the semiempirical relationship proposed by Chern and Poehlein. By combining an nth order kinetic model or an autocatalytic model with a diffusion factor, it is possible to predict the cure kinetics of each catalytic system over the whole range of conversion.

Verification of Kinetic Theoretical Prediction of Diffusion-influenced Reversible

  • 양민오;신국재
    • Bulletin of the Korean Chemical Society
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    • 제21권1호
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    • pp.93-96
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    • 2000
  • A diffusion-influenced pseudo-first order reversible reaction A + B ⇔C + B is investigated by the molecular dynamics (MD) simulation method. Theoretical finding that the temporal evolution of reactants [conditional probabilities] in the reversible system can be expressed by the irreversible survival probability with an effective rate parameter is confirmed even in the presence of solvent particles. We carry out molecular dynamics simulations for both the irreversible and the reversible cases to evaluate the survival and the conditional probabilities for each cases. When the resultant irreversible survival probability is inserted into the proposed relation, the conditional probabilities given by the simulation are exactly reproduced.