• 제목/요약/키워드: R-curve behavior

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Heavy metal adsorption of a novel membrane material derived from senescent leaves: Kinetics, equilibrium and thermodynamic studies

  • Zhang, Yu;Tang, Qiang;Chen, Su;Gu, Fan;Li, Zhenze
    • Membrane and Water Treatment
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    • v.9 no.2
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    • pp.95-104
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    • 2018
  • Copper pollution around the world has caused serious public health problems recently. The heavy metal adsorption on traditional membranes from wastewater is limited by material properties. Different adsorptive materials are embedded in the membrane matrix and act as the adsorbent for the heavy metal. The carbonized leaf powder has been proven as an effective adsorbent material in removing aqueous Cu(II) because of its relative high specific surface area and inherent beneficial groups such as amine, carboxyl and phosphate after carbonization process. Factors affecting the adsorption of Cu(II) include: adsorbent dosage, initial Cu(II) concentration, solution pH, temperature and duration. The kinetics data fit well with the pseudo-first order kinetics and the pseudo-second order kinetics model. The thermodynamic behavior reveals the endothermic and spontaneous nature of the adsorption. The adsorption isotherm curve fits Sips model well, and the adsorption capacity was determined at 61.77 mg/g. Based on D-R model, the adsorption was predominated by the form of physical adsorption under lower temperatures, while the increased temperature motivated the form of chemical adsorption such as ion-exchange reaction. According to the analysis towards the mechanism, the chemical adsorption process occurs mainly among amine, carbonate, phosphate and copper ions or other surface adsorption. This hypothesis is confirmed by FT-IR test and XRD spectra as well as the predicted parameters calculated based on D-R model.

The Effect of Genibo Program Based Robot Learning on a Pre-Schoolers' Emotional Development (로봇학습에 기반한 제니보 프로그램이 유아의 정서발달에 미치는 효과)

  • Lee, Jae-Cheol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.1
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    • pp.165-172
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    • 2015
  • The purpose of this study was to identify the effect of Genibo program robot-based learning(R-Learning) on a pre-schooler's mental state. To achieve above study purpose, the subject of this study was selected 46(teacher 2, five years old pre-schooler 44) from pre-school childrens in Kyongki Y city(R-Learning activity participants group 21: boys 10, girls 11. non-participants 25: boys 13, girls 12). R-Learning program is consist of 5 field about 20 contents using Genibo robot, were applied to the experimental group and the pre-post test was conducted using the EQ assessment tool and observations. The data were analyzed by t-test using the SPSS(ver 18.0) program. The results were as follows: First, the exposure of robots to pre-schoolers in practical situation has shown positive influence to the children's emotional well-being. Positive improvements were observed in the four sub categories of the EQ assessment after exposure. Second, the Genibo used for this study, is a biomimetic AI based robot mimicking the behavior of a pet dog. This is related more or less to the specifications of a pre-school education where animals are used as a 'friendly medium' to facilitate the learning process. Third, the robot exposure gave benefit to all the ones in the sample, regardless of sex. Furthermore, It is suggested that promising potential for robots to be utilized as a new educational media plus facilitator, R-Learning is related more or less to the specifications of a pre-school education where animals are used as a 'friendly medium' to facilitate the learning process, and when applying them for education, stereotyping the likes of sex is overrated - instead, the focus should be more on the pre-schoolers' / childrens' individual traits, learning curve differences and alike.

Development of the Korean Developmental Screening Test for Infants and Children (K-DST)

  • Chung, Hee Jung;Yang, Donghwa;Kim, Gun-Ha;Kim, Sung Koo;Kim, Seoung Woo;Kim, Young Key;Kim, Young Ah;Kim, Joon Sik;Kim, Jin Kyung;Kim, Cheongtag;Sung, In-Kyung;Shin, Son Moon;Oh, Kyung Ja;Yoo, Hee-Jeong;Yu, Hee Joon;Lim, Seoung-Joon;Lee, Jeehun;Jeong, Hae-Ik;Choi, Jieun;Kwon, Jeong-Yi;Eun, Baik-Lin
    • Clinical and Experimental Pediatrics
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    • v.63 no.11
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    • pp.438-446
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    • 2020
  • Background: Most developmental screening tools in Korea are adopted from foreign tests. To ensure efficient screening of infants and children in Korea, a nationwide screening tool with high reliability and validity is needed. Purpose: This study aimed to independently develop, standardize, and validate the Korean Developmental Screening Test for Infants and Children (K-DST) for screening infants and children for neurodevelopmental disorders in Korea. Methods: The standardization and validation conducted in 2012-2014 of 3,284 subjects (4-71 months of age) resulted in the first edition of the K-DST. The restandardization and revalidation performed in 2015-2016 of 3.06 million attendees of the National Health Screening Program for Infants and Children resulted in the revised K-DST. We analyzed inter-item consistency and test-retest reliability for the reliability analysis. Regarding the validation of K-DST, we examined the construct validity, sensitivity and specificity, receiver operating characteristic curve analysis, and a criterion-related validity analysis. Results: We ultimately selected 8 questions in 6 developmental domains. For most age groups and each domain, internal consistency was 0.73-0.93 and test-retest reliability was 0.77-0.88. The revised K-DST had high discriminatory ability with a sensitivity of 0.833 and specificity of 0.979. The test supported construct validity by distinguishing between normal and neurodevelopmentally delayed groups. The language and cognition domain of the revised K-DST was highly correlated with the K-Bayley Scales of Infant Development-II's Mental Age Quotient (r=0.766, 0.739), while the gross and fine motor domains were highly correlated with Motor Age Quotient (r=0.695, 0.668), respectively. The Verbal Intelligence Quotient of Korean Wechsler Preschool and Primary Scales of Intelligence was highly correlated with the K-DST cognition and language domains (r=0.701, 0.770), as was the performance intelligence quotient with the fine motor domain (r=0.700). Conclusion: The K-DST is reliable and valid, suggesting its good potential as an effective screening tool for infants and children with neurodevelopmental disorders in Korea.

Soil Modelling Method to Design Bent Foundation with Drilled Shaft Pier (단일 현장타설말뚝의 설계시 지반 모델링 방법)

  • Jeon, Kyung-Soo;Han, Kyoung-Bong;Song, Pil-Young
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.09a
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    • pp.368-376
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    • 2010
  • The bent foundation with single drilled shafts is suitable and economical in South Korea, which has good rock in a shallow depth. This foundation has been designed with an elastic design concept. To apply a plastic design concept written in Korea Bridge Design Criteria, a detail design regulation, which includes the method for a plastic hinge point to occur above the ground, rebar arrangement and soil modelling, should be defined. Soil modelling should be considered in the respect of structural engineer's practicality. In this paper, single drilled shaft piers with 1m diameter are constructed, and cyclic lateral load tests loaded at 4m above the ground are taken to examine the behavior. Reduced diameter shaft above the ground and remaining the steel casing under the ground were used to induce plastic hinge to occur above the ground. Simplified soil models such as elastic relation and p-y curve are adapted, and the prediction results are compared with test results. Prediction results of a model bridge were compared according to soil models with time domain analyses, and design criteria of soil were proposed.

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Evaluation of Mechanical Properties and Fatigue Behavior of STS 304L due to Plastic Working (소성가공에 따른 STS 304L 재료의 기계적 특성 및 피로평가)

  • Shim, Hyun-Bo;Kim, Young-Kyun;Suh, Chang-Min
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.41 no.7
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    • pp.635-643
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    • 2017
  • The purpose of this study is to investigate the influence of the cold reduction rate and an ultrasonic fatigue test (UFT) on the fatigue behaviors of STS 304L. The tensile strength, yield strength, hardness value and fatigue limit in the UFT fatigue test linearly increased as thickness decreased from 1.5 mm to 1.1 mm, as the cold reduction rate of STS 304L increased. As a result of the UFT fatigue test (R = -1) of four specimens, the fatigue limit of the S-N curve formed a knee point in the region of $10^6$, and the 2nd fatigue limit caused by giga cycle fatigue did not appeared. In the case of t = 1.1 mm, the highest fatigue limit was 345 MPa, which was 64.3% higher than the original material (t = 1.5 mm). As a result of the UFT fatigue test of STS 304L, many small surface cracks occurred, grown, coalesced while tearing.

Degradation Behavior of Eutectic and Pb-free Solder Plated Ribbon in Crystalline Silicon Photovoltaic Module (유무연 용융도금 리본에 따른 결정질 실리콘 태양전지 모듈 열화거동)

  • Kim, Ju-Hee;Kim, A Yong;Park, Nochang;Ha, Jeong Won;Lee, Sang Guon;Hong, Won Sik
    • Journal of Welding and Joining
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    • v.32 no.6
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    • pp.75-81
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    • 2014
  • Usage of heavy metal element (Pb, Hg and Cd etc.) in electronic devices have been restricted due to the environmental banning of the European Union, such as WEEE and RoHS. Therefore, it is needed to develop the Pb-free solder plated ribbon in photovoltaic (PV) module. This study described that degradation characteristics of PV module under damp heat (DH, $85^{\circ}C$ and 85% R.H.) condition test for 1,000 h. Solar cell ribbons were utilized to hot dipping plate with Pb-free solder alloys. Two types of Pb-free solder plated ribbons, Sn-3.0Ag-0.5Cu (SAC305) and Sn-48Bi-2Ag, and an electroless Sn-40Pb solder hot dipping plated ribbon as a reference sample were prepared to evaluate degradation characteristics. To detect the degradation of PV module with the eutectic and Pb-free solder plated ribbons, I-V curve, electro-luminescence (EL) and cross-sectional SEM analysis were carried out. DH test results show that the reason of maximum power (Pm) drop was mainly due to the decrease fill factor (FF). It was attributed to the crack or oxidation of interface between the cell and the ribbon. Among PV modules with the eutectic and Pb-free solder plated ribbon, the PV module with SAC305 ribbon relatively showed higher stability after DH test than the case of PV module with Sn-40Pb and Sn-48Bi-2Ag solder plated ribbons.

Dynamic Analysis of Gimbal Structure System Including Nonlinear Elastic Rubber Vibration Isolator with Shock Acceleration (비선형 탄성 방진 고무부에 충격 가속도를 받는 짐발 구조 시스템의 동적 해석)

  • Lee, Sang Eun;Lee, Tae Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.4
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    • pp.415-422
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    • 2016
  • When shock acceleration is applied to a mechanical system, it may cause malfunctioning and damage to the system. Hence, to prevent these problems when developing a gimbal structure system for observation reconnaissance, the MIL-STD-810G shock standard must be satisfied as a design specification. Rubber vibration isolators are generally assembled on the base of the system in order to reduce the shock transferred from the aircraft. It is difficult to analyze the transient behavior of the system accurately, because rubber has a nonlinear load-deformation curve. To treat the nonlinear characteristic of the rubber, bilinear approximation was introduced. Using this assumption, transient responses of the system under base shock acceleration were calculated by the finite element method. In addition, experiments with a true prototype were performed using the same conditions as the analytical model. Compared with experimental data, the proposed numerical method is useful for the transient analysis of gimbal structure systems, including rubber vibration isolators with nonlinear stiffness and damping.

Analytical Study on Ductility Index of Reinforced Concrete Flexural Members (철근 콘크리트 휨부재의 연성지수에 관한 해석적 연구)

  • Lee, Jae Hoon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.14 no.3
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    • pp.391-402
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    • 1994
  • One of the most important design concept for reinforced concrete structures is to achieve a ductile failure mode, and also moment redistribution for economic design is possible in case that adequate ductility is provided. Flexural ductility index is, therefore, used as a reference for possibility of moment redistribution as well as for prediction of flexural behavior of designed R.C. structures. Ductility index equations, however, provide approximate values due to the linear concrete compressive stress assumption at the tension steel yielding state. Theoretically more exact ductility index is calculated by a numerical analysis with the realistic stress-strain curves for concrete and steel to be compared with the result from tire ductility index equations. Variation of ductility index for the selected variables and the reasonable maximum tension steel ratio for doubly reinforced section are investigated. A moment-curvature curve model is also proposed for future research on moment redistribution.

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Definition and measurement of S-curve based technological discontinuity : case of technological substitution of logic semiconductors (S곡선 기반 기술적 불연속성(Technological discontinuity)의 정의 및 측정 : 로직 반도체의 기술대체 사례)

  • Park, Changhyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.7
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    • pp.102-108
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    • 2017
  • The phenomenon of technological discontinuity which occurs during technological diffusion and substitution between incumbents and new technology is important to understand the behavior of technology diffusion and substitution of single and multiple technologies. Our research defined the concept of technological discontinuity and developed a model capable of measuring the region of technological discontinuity. Based on a literature review and a model development, we proposed a definition and a model regarding technological discontinuity.The accuracy of the model is verified by applying it on a semiconductor industry case. The technological discontinuity is defined as the region in which both the incumbent and new technology co-exist and the performance of the incumbent technology is better than that of the new technology. In addition, we can model the technological discontinuity using discontinuous time and discontinuous performance. This research will be very useful to understand not only technological discontinuity but also technology diffusion or substitution.

Calculation of Damping Ratio Using Non-Linear Soil Models and Comparison between Measured and Predicted Data (흙의 비선형 모델을 이용한 감쇠비 산정 및 비교)

  • Lee, Hyoung-Kyu;Bae, Yoon-Shin
    • Journal of the Korean Geosynthetics Society
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    • v.10 no.2
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    • pp.21-28
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    • 2011
  • Several theoretical soil nonlinear models to predict damping ratio, which is one of the typical dynamic properties of soils, it is impractical to predict damping ratio. The resonant column and torsional shear test(RC-TS) is used to represent the dynamic behavior of soils from intermediate to medium shear strains. A limitation of RC-TS is measure precise shear strain in large strains and the modified equivalent radius($R_{eq}$) was obtained using both modified hyperbolic model and Ramberg-Osgood model. Bonneville clays were tested using RC-TS test to obtain rotation and torque. The measured rotation and torque were then compared with calculated rotation and torque using curve-fitting method. Then, the nonlinear soil model parameters were obtained and the equivalent radius was calculated using the model parameters.