• Bulletin of the Korean Chemical Society
• /
• 제35권2호
• /
• pp.587-596
• /
• 2014

A new ${\pi}$-stacked donor-acceptor (D-A) system, [Ru(1-([2,2'-bipyridine]-6-yl-methyl)-3-(2-cyclohexa-2',5'-diene-1,4-dionyl)-1H-imidazole)(2,2':6',2"-terpyridine)]$[PF_6]_2$ (ImQ_T), has been synthesized and characterized. Similar to its precedent, [Ru(6-(2-cyclohexa-2',5'-diene-1,4-dione)-2,2':6',2"-terpyridine)(2,2':6',2"-terpyridine)]$[PF_6]_2$ (TQ_T), this system has a cofacial alignment of terpyridine (tpy) ligand and quinonyl (Q) group, which facilitates an electron transfer through ${\pi}$-stacked manifold. Despite the presence of lowest-energy charge transfer transition from the Ru-based-HOMO-to-Q-based-LUMO (MQCT) predicted by theoretical calculations by using time-dependent density functional theory (TD-DFT), the experimental steady-state absorption spectrum does not exhibit such a band. The selective excitation to the Ru-based occupied orbitals-to-tpy-based virtual orbital MLCT state was thus possible, from which charge separation (CS) reaction occurred. The photo-induced CS and thermal charge recombination (CR) reactions were probed by using ultrafast visible-pump/mid-IR-probe (TrIR) spectroscopic method. Analysis of decay kinetics of Q and $Q^-$ state CO stretching modes as well as aromatic C=C stretching mode of tpy ligand gave time constants of <1 ps for CS, 1-3 ps for CR, and 10-20 ps for vibrational cooling processes. The electron transfer pathway was revealed to be Ru-tpy-Q rather than Ru-bpy-imidazol-Q.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1999년도 하계학술대회 논문집 F
• /
• pp.2481-2483
• /
• 1999

This paper proposed the p-q-r coordinate system where the instantaneous active power p, and the two instantaneous reactive powers $q_{q}$, $q_{r}$ were defined. The three power components are linearly independent, so the compensation for the two instantaneous reactive powers leads to control the two components of the current space vector. With the theory, the neutral current of a three-phase four-wire system can be eliminated by only compensating the instantaneous reactive power using no energy storage element.

• 정보처리학회논문지A
• /
• 제8A권1호
• /
• pp.1-8
• /
• 2001

This paper describes the design and implementation of C standard library for real-time operating system Q+, that is being developed for the internet appliance. The C library in the real-time operating system should be defined according to the standard interface and support the concurrent execution of threads. The implemented C standard library is reentrant and follows POSIX.l standard interface. And, the C standard library functions, which are adequate to the Q+ application and commonly provided by commercial real-time operating systems, are selected among POSIX.l standard functions. The C standard library is implemented on the Q+ kernel and D-TV set-top box according to the implementation sequence, which is determined by analyzing the relation of function calls.

• 대한수학회보
• /
• 제50권1호
• /
• pp.37-56
• /
• 2013

This paper deals with the behavior of positive solutions to the following nonlocal polytropic filtration system $$\{u_t=(\mid(u^{m_1})_x{\mid}^{{p_1}^{-1}}(u^{m_1})_x)_x+u^{l_{11}}{{\int_0}^a}v^{l_{12}}({\xi},t)d{\xi},\;(x,t)\;in\;[0,a]{\times}(0,T),\\{v_t=(\mid(v^{m_2})_x{\mid}^{{p_2}^{-1}}(v^{m_2})_x)_x+v^{l_{22}}{{\int_0}^a}u^{l_{21}}({\xi},t)d{\xi},\;(x,t)\;in\;[0,a]{\times}(0,T)}$$ with nonlinear boundary conditions $u_x{\mid}{_{x=0}}=0$, $u_x{\mid}{_{x=a}}=u^{q_{11}}u^{q_{12}}{\mid}{_{x=a}}$, $v_x{\mid}{_{x=0}}=0$, $v_x|{_{x=a}}=u^{q21}v^{q22}|{_{x=a}}$ and the initial data ($u_0$, $v_0$), where $m_1$, $m_2{\geq}1$, $p_1$, $p_2$ > 1, $l_{11}$, $l_{12}$, $l_{21}$, $l_{22}$, $q_{11}$, $q_{12}$, $q_{21}$, $q_{22}$ > 0. Under appropriate hypotheses, the authors establish local theory of the solutions by a regularization method and prove that the solution either exists globally or blows up in finite time by using a comparison principle.

• 한국정보과학회논문지:소프트웨어및응용
• /
• 제29권1_2호
• /
• pp.30-41
• /
• 2002

분산 이형 환경에서 대용량의 정보를 검색하는 새로운 패러다임으로 이동 에이전트가 주목받고 있다. 검색을 수행하기 위해 많은 양의 데이터를 전송하는 대신 검색을 수행하는 에이전트를 검색을 수행할 서버로 직접 전달하는 방식을 이용하는 것이다. 본 논문에서는 분산 이형 환경에 독립적으로 존재하는 정보를 효율적으로 검색할 수 있는 이동 에이전트 기반의 정보 검색 모델을 제시하고 질의응답(Q&A)을 검색하는 시스템을 다지인하고 구현한다. 제안된 모델인 이동 에이전트 기반의 질의응답 검색 시스템(QASSMA : Q&A Search System using Mobile Agents)은 이형 분산의 환경에 존재하는 질의응답 게시판 및 뉴스그룹을 검색할 수 있는 모델이다. QASSMA의 특징을 요약하면, 우선, 최적의 검색 위치로 검색 코드 자체가 이동하여 검색을 수행하므로 기존의 정적인 검색 로봇에 비하여 고정된 네트워크 거리를 극복할 수 있고 단축된 원격 서버와의 네트워크 거리만큼 검색시간을 단축시킬 수 있다. 또한 출발서버에서 검색할 위치로 검색코드가 이동하여 실행되므로 중앙 집중적인 네트워크 트래픽 형성을 막고 출발서버의 부담을 줄일 수 있다. 마지막으로, QASSMA의 이동 검색 에이전트는 검색 환경에 맞는 클래스를 능동적으로 탑재하여 효율적으로 검색 환경의 변화에 대처할 수 있고 다양한 검색 방법을 지원할 수 있다. 본 논문에서는 실험을 통해 제안된 이동 에이전트 기반의 질의응답 시스템의 검색 방법이 기존의 정적인 검색 방법에 비해 효율적임을 보인다.

• 공업화학
• /
• 제7권2호
• /
• pp.379-386
• /
• 1996

광 이량화 특성을 나타내는 1-methyl-4-[2-(4-diethylacetylphenyl)ethenyl] pridinium methosulfate(SbQ-A염)를 dimethyl sulfate, terephthalaldehyde mono-(diethyl acetal) 및 4-picoline을 이용하여 합성하였다. 합성된 SbQ-A염을 PVA와 반응시켜 동일(MW=77,000-79,000g/mol) 분자량을 가진 PVA내 SbQ의 함량이 다른 PVA-SbQ-H 시료 및 SbQ의 함량은 약 1.3mol%로 같으나 PVA의 분자량이 다른 PVA-SbQ-L들을 합성하였다. Gray scale(GS)법을 이용하여 측정된 PVA-SbQ 수용성 감광성 고분자의 상대감도는 PVA내 SbQ의 함량이 증가함에 따라 증가하였으며, PVA의 분자량이 낮아질수록 감소하였다. PVA-SbQ-H의 경우 SbQ 함량이 2.63mol%인 시료는 PVA에 ammonium dichromate가 혼합된 기존시료보다 90배 증가된 감도를 나타내었다. PVA-SbQ를 사용하여 형광체 슬러리를 제조하고 사진식각공정을 거쳐 형광체의 미세패턴을 형성하였다. 형광체 슬러리 제조시 양이온 계면활성제인 cetyltrimethyl ammonium chloride를 첨가제로 사용하면 형광면의 해상도가 증가됨을 알았다.

• 한국전자거래학회:학술대회논문집
• /
• 한국전자거래학회 2001년도 International Conference CALS/EC KOREA
• /
• pp.503-510
• /
• 2001

Q+-reader, an E-Book reader system for XML based contents is introduced. The system is developed for the embedded platform, called Q+, which targets for the digital home electronics systems. The system supports XML contents and CSS based styling as described in Open e-Book standard. The system renders the e-book contents for users, so the contents are secured for a proper use. This will found an essential part of business infra for electronic books with copyright protection. The system was developed in Java language to be used in various platforms, and has an open architecture to be reusable for other standards as well.

• Kyungpook Mathematical Journal
• /
• 제47권3호
• /
• pp.381-392
• /
• 2007

In 1906, da Rios, a student of Leivi-Civita, wrote a master's thesis modeling the motion of a vortex in a viscous fluid by the motion of a curve propagating in $R^3$, in the direction of its binormal with a speed equal to its curvature. Much later, in 1971 Hasimoto showed the equivalence of this system with the non-linear Schr$\ddot{o}$dinger equation (NLS) $$q_t=i(q_{ss}+\frac{1}{2}{\mid}q{\mid}^2q$$. In this paper, we use the same idea as Terng used in her lecture notes but different technique to extend the above relation to the case of $R^3$, and obtained an analogous equation that $$q_t=i[q_{ss}+(\frac{1}{2}{\mid}q{\mid}^2+1)q]$$.

• 대한전기학회논문지:전력기술부문A
• /
• 제48권3호
• /
• pp.278-285
• /
• 1999

This paper utilizes the method of Q-parameterization control to design a controller which solves the problem of imbalance in magnetic bearing systems. There are two methods to solve this problem using feedback controal. The first method is to compensate for the imbalance forces by generating opposing forces on the bearing surface (imbalance compensation). The second method is to make the rotor rotate around its axis of inertia (automatic balancing);in this case no imbalance forces will be generated. In this paper we deal with only imbalance compensation. The free parameter of the Q-parameterization controller is chosen such that these goals are achieved. After the introduction of a model of the magnetic bearing system, we explain the Q-parameterization controller design of the magnetic bearing system with emphasis on the rejection of sinusoidal disturbance for imbalance compensation design. The design objectives are formulated as a linear equations in the controller free paramete Q. Finally, simulation and experimental results are presented and showed the robustness and effectiveness of the proposed controllers.

• 대한수학회지
• /
• 제40권5호
• /
• pp.769-788
• /
• 2003

In this paper, we study the optimal control for the damped semilinear hyperbolic systems with unknown parameters (C(t)y')'＋ $A_2$(t, q)y'＋ $A_1$(t, q)y = f(t, q, y, u). We will prove the existence of weak solution of this system and is to find the optimal control pair (q, u) $\in$ $Q_{t}$ ${\times}$ $U_{ad}$ such that in $f_{u}$$\in$ $Q_{t}$/ J(q, u) = J(q, u).$_{t}$/ J(q, u) = J(q, u).