• Title/Summary/Keyword: Process Chamber

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Development of Pilot-Scale Manufacturing Process of SiC Fiber from Polycarbosilane Precursor with Excellent Mechanical Property at Highly Oxidation Condition and High Temperature (폴리카보실란 전구체로부터 고온 산화성분위기서 기계적물성이 우수한 파이롯-규모의 탄화규소섬유 제조공정 개발)

  • Yoon, B.I.;Choi, W.C.;Kim, J.I.;Kim, J.S.;Kang, H.G.;Kim, M.J.
    • Composites Research
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    • v.30 no.2
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    • pp.116-125
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    • 2017
  • The purpose of this study is to develop silicon carbide fiber showing an excellent mechanical properties under highly oxidative conditions at high temperature. Polycarbosilane(PCS) as a preceramic precursor was used for making the SiC fiber. PCS fiber was taken by melt spinning method followed by melting the PCS at $300{\sim}350^{\circ}C$ in N2 gas. The Curing of PCS fiber was carried out in air oxygen chamber, prior to high temperature pyrolysis. Degree of cure was calculated by characteristic peak's ratio of Si-H to $Si-CH_3$ in FT-IR spectra before and after curing of PCS fiber. The properties of SiC fiber was affected greatly by the degree of cure. The SiC fiber produced by controlling fiber tension during heat treatment showed good properties. The SiC fiber exposed to $1000^{\circ}C$ at air from 1 min. up to maximum 50 hrs showed around 60% reduction in tensile strength. We found that large amount of carbon content on the fiber surface after long-term exposure has resulted in lower tensile strength.

Interactive Effects of Ozone and Light Intensity on Platanus occidentalis L. Seedlings

  • Kim, Du-Hyun;Han, Sim-Hee;Lee, Kab-Yeon;Kim, Pan-Gi
    • Journal of Korean Society of Forest Science
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    • v.97 no.5
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    • pp.508-515
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    • 2008
  • Sycamore (Platanus occidentalis L.) seedlings were grown under low light intensity and ozone treatments to investigate the role of the light environment in their response to chronic ozone stress. One-year-old seedlings of Platanus occidentalis L. were grown in pots for 3 weeks under low light (OL, $150{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$) and high light (OH, $300{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$) irradiance in combination with 150 ppb of ozone fumigation. After three weeks of ozone and light treatment, seedlings were placed in ozone free clean chamber for 3 weeks for recovery from ozone stress with same light conditions to compare recovery capacity. Ozone fumigation determined an impairment of the photosynthetic process. Reduction of leaf dry weight (14%) and shoo/root ratio (17%) were observed in OH treatment. OL treatment also showed severe reductions in leaf dry weight and shoot/root ratio by 48% and 36% comparing to control, respectively. At the recovery phase, OH-treated plants recovered their biomass, whereas OL-treated plant showed reduction in leaf dry weight (52%) and shoot/root ratio (49%). OH-treated plants reached similar relative growth rate (RGR) comparing to control, whereas OL-treated plants showed lower RGR in stem height. However, there were no significant differences in response to those treatments in stem diameter RGR at the recovery phase. Ozone treatment produced significant reduction of net photosynthesis in both high and low light treatments. Carboxylation efficiency and apparent quantum yield in OL-treated plants showed significant reductions rate to 10% and 45%, respectively. At the recovery stage, ozone exposed seedlings under high light had similar photosynthetic capacity comparing to control plants. Antioxidant enzymes activities such as superoxide dismutase (SOD), ascorbate peroxidase (APX), and glutathione reductase (GR) were increased in ozone fumigated plants only under low light. The present work shows that the physiological changes occur in photosynthesis-related parameters and growth due to ozone and low light stress. Thus, low light seems to enhance the detrimental effects of ozone on growth, photosynthesis, and antioxidant enzyme responses.

[O2/N2] Plasma Etching of Acrylic in a Multi-layers Electrode RIE System (다층 RIE Electrode를 이용한 아크릴의 O2/N2 플라즈마 건식 식각)

  • Kim, Jae-Kwon;Kim, Ju-Hyeong;Park, Yeon-Hyun;Joo, Young-Woo;Baek, In-Kyeu;Cho, Guan-Sik;Song, Han-Jung;Lee, Je-Won
    • Korean Journal of Materials Research
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    • v.17 no.12
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    • pp.642-647
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    • 2007
  • We investigated dry etching of acrylic (PMMA) in $O_2/N_2$ plasmas using a multi-layers electrode reactive ion etching (RIE) system. The multi-layers electrode RIE system had an electrode (or a chuck) consisted of 4 individual layers in a series. The diameter of the electrodes was 150 mm. The etch process parameters we studied were both applied RIE chuck power on the electrodes and % $O_2$ composition in the $N_2/O_2$ plasma mixtures. In details, the RIE chuck power was changed from 75 to 200 W.% $O_2$ in the plasmas was varied from 0 to 100% at the fixed total gas flow rates of 20 sccm. The etch results of acrylic in the multilayers electrode RIE system were characterized in terms of negatively induced dc bias on the electrode, etch rates and RMS surface roughness. Etch rate of acrylic was increased more than twice from about $0.2{\mu}m/min$ to over $0.4{\mu}m/min$ when RIE chuck power was changed from 75 to 200 W. 1 sigma uniformity of etch rate variation of acrylic on the 4 layers electrode was slightly increased from 2.3 to 3.2% when RIE chuck power was changed from 75 to 200 W at the fixed etch condition of 16 sccm $O_2/4\;sccm\;N_2$ gas flow and 100 mTorr chamber pressure. Surface morphology was also investigated using both a surface profilometry and scanning electron microscopy (SEM). The RMS roughness of etched acrylic surface was strongly affected by % $O_2$ composition in the $O_2/N_2$ plasmas. However, RIE chuck power changes hardly affected the roughness results in the range of 75-200 W. During etching experiment, Optical Emission Spectroscopy (OES) data was taken and we found both $N_2$ peak (354.27 nm) and $O_2$ peak (777.54 nm). The preliminarily overall results showed that the multi-layers electrode concept could be successfully utilized for high volume reactive ion etching of acrylic in the future.

Setting up Relationship between Pull-out Resistance of Helical Anchor and Rotational Penetration Torque for Methodology Development (헬리컬 앵커개발 및 적용을 위한 앵커의 회전 관입 토크와 인발저항력과의 상관관계 정립)

  • Kim, Nak-Kyeong;Kim, Young-Uk;Moon, Jun-Ho;Xin, Zhen-Hua;Gu, Kyo-Young
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.3
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    • pp.661-667
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    • 2016
  • This study evaluated the potential of methodology development of the helical type anchor for soft ground applications. The rotational penetration of the helix structure might make construction-steps easy without the soil spitting and reusable rods could reduce the material cost. Removal of the anchors would be simple as a construction, which can be named the removal anchor. The anchoring resistance after construction is strongly related to the number of helixes resulting in a concise design process. The investigation involved a chamber test with soft soils. In the test, a specially designed and fabricated helical anchor and torque-driver were used to obtain the maximum pull-out resistance of the anchor after rotational penetration. As a result of the tests, The rotational torque and pull-out resistance have a proportional relationship with the strength of the prepared soils. Within the range of the study, the torque of the anchor penetrating increased with increasing pull-out resistance.

Effect of pre-post injection timing of diesel fuel for naval vessel on the combustion and emission characteristics in an optically-accessible single cylinder diesel engine (단기통 디젤엔진에서 함정용 디젤유의 전·후 분사시기가 연소 및 배출가스 특성에 미치는 영향)

  • Lee, Hyungmin
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.7
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    • pp.868-876
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    • 2014
  • The objective of this study is focused on the analyzing combustion, carbon monoxide and hydrocarbon emission characteristics of marine diesel oil, utilized for naval propulsion engine, with varying pre-post injection timing of an optically accessible single cylinder engine. And also the combustion process is analyzed by means of a high speed camera visualization. On the result of retarding pre-injection timing toward main injection timing, the mean effective pressure and maximum pressure of combustion chamber are increased; however, the heat release rate is decreased. Furthermore, the emission rates of carbon monoxide and hydrocarbon are reduced in this case. In hence, when a post-injection timing is advanced, the mean effective pressure and maximum pressure are increased, because the combustion has been performed under the high temperature and high pressurized environment during main injection time, and the emission rates of carbon monoxide and hydrocarbon are increased. From the experimental results, it considered that retarding of pre-injection timing affects to shorten the ignition delay of main injection clearly, and to raise the flame intensity comparing to the advanced state. The ignition delay during post-injection is not appeared at any post-injection time, but the flame intensity has been weakened gradually according to the retarding of post-injection timing.

Experimental Analysis of a Supersonic Plasma Wind Tunnel Using a Segmented Arc Heater with the Power Level of 0.4 MW (0.4 MW 급 분절형 아크 히터를 이용한 초음속 플라즈마 풍동 특성 실험)

  • Kim, Min-Ho;Lee, Mi-Yeon;Kim, Jeong-Soo;Choi, Chea-Hong;Seo, Jun-Ho;Moon, Se-Yeon;Hong, Bong-Guen
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.9
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    • pp.700-707
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    • 2013
  • Experimental analyses on a supersonic plasma wind tunnel of CBNU (Chonbuk National University) were carried out. In these experiments, a segmented arc heater was employed as a plasma source and operated at the gas flow rates of 16.3 g/s and the total currents of 300 A. The input power reached ~350 kW with the torch efficiency of 51.4 %, which is defined as the ratio of total exit enthalpy to the input power. The pressure of plasma gas in the arc heater was measured up to 4 bar while it was down to ~45 mbar in a vacuum chamber through a Laval nozzle. During this conversion process, the generated supersonic plasma was expected to have a total enthalpy of ~11 MJ/kg from the measured input power and torch efficiency. In addition to the measurement of total enthalpy, a cone type probe was inserted into the supersonic plasma flow in order to estimate the angle between shock layer and surface of the probe. From these measurements, the temperature and the Mach number of the supersonic plasma were predicted as ~2,950 K and ~3.7, respectively.

Research and Policy Directions against Ambient Fine Particles (초미세먼지 문제 해결을 위한 연구 및 정책 방향)

  • Kim, Yong Pyo
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.3
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    • pp.191-204
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    • 2017
  • Concerns on the air pollution problem caused by ambient fine particles have become a big social issue in Korea. Important factors that should be addressed to develop effective and efficient air quality management policy, especially, against fine particles are discussed and research and policy directions to address these factors are suggested. It is suggested that two factors are in high priority; one is scientific understanding of the major formation mechanisms of fine particles and the other is the process of policy decision and implementation. For the scientific understanding, smog chamber measurement, intensive field study, and chemical transport model development that can simulate the characteristics of Northeast Asia are considered to be important. For the policy directions, priority setting of the proposed policies and development and implement of effective communication sytem are considered to be important.

Simultaneous Removal of $SO_2$ and NOx Using Ozone Generator and Absorption- Reduction Technique (오존발생장치와 흡수환원법을 이용한 배기가스 동시 탈황 탈질 공정)

  • Mok, Young-Sun;Lee, Joo-Hyuck;Shin, Dong-Nam;Koh, Dong-Jun;Kim, Kyong-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.2
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    • pp.191-196
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    • 2006
  • The injection of ozone, produced by dielectric barrier discharge, into the exhaust gas gives rise to a rapid oxidation of NO that is the main component of nitrogen oxides($NO_x$) in most practical exhaust gases. Once NO is converted into $NO_2$, it on readily be reduced to $N_2$ in the next step by a reducing agent such as sodium sulfide and sodium sulfite. The reducing agents used ca also remove $SO_2$ effectively, which makes it possible to treat $NO_x\;and\;SO_2$ simultaneously. The present two-step process made up of an ozonizing chamber and an absorber containing a reducing agent solution was able to remove about 95% of the $NO_x$ and 100% of the $SO_2$, initially contained in the simulated exhaust gas. The formation of $H_2S$ from sodium sulfide was prevented by using a strong basic reagent(NaOH) together with the reducing agent. The removal of $NO_x$\;and\;SO_2$ was more effective for $Na_2S$ than $Na_2SO_3$.

Effectiveness of an Environment-friendly Fumigator for Microorganisms that Can Cause Biological Damage to Records in Japan, Malaysia, and Oman (일본, 말레이시아, 오만의 기록물에서 분리한 유해미생물에 대한 친환경 기록물 소독장비 효과검증)

  • Kim, Min Ji;Lee, Eon Sook;Choi, Young Nam;Choi, Young Sin
    • Journal of Korean Society of Archives and Records Management
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    • v.15 no.2
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    • pp.165-179
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    • 2015
  • Archives have historical and academic values. That is why the study of preservation conditions and the environment for the effective management of various records progress. However, materials such as paper and adhesives will inevitably cause biological damages. These damages spread into the inner side of archives, which would make it impossible to recover. For example, archival records from Malaysia and Oman are easily exposed to biological damage because of these countries' hot and humid climate. As such, once records are damaged, disinfection operations are customary in these areas. Methyl bromide (MeBr) and ethylene oxide (EtO) were used in the disinfection process as they showed good insecticidal effect. However their antibacterial effect are negligible. As such, the need for an environmental-friendly fumigator was evident. An environmental-friendly fumigator is designed to improve storage stability. Such equipment is expected to contribute to prevention of damages to cultural heritages through its use of vaporization technology, maintenance of a disinfection space (chamber), and self-generation of nitrogen.

Characteristics of Volatile Organic Compounds and Aldehydes Emission from Yellow poplar (Liriodendron tulipifera L.) (백합나무 판재의 VOCs 및 Aldehydes 방출특성)

  • Lee, Min;Park, Sang-Bum;Lee, Sang-Min;Son, Dong-Won
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.4
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    • pp.357-366
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    • 2014
  • Based on fundamental properties and machining characteristics of Yellow poplar (Liriodendron tulipifera L.), it has well performance on machinability or workability, drying, and fine surface. Additionally, yellow poplar is light weight and has bright color with high performance of bending processing, so it could be used for furniture or artworks materials and wood-based panel materials. Recently, public attention has been focused on indoor air quality, and Ministry of environment drift more tight regulation on indoor air quality for an apartment house and public facility with the times. Construction materials has been assessed emission of volatile organic compounds (VOCs) and formaldehyde according to law (No.10789), so yellow poplar is also needed to assess these emission characteristics. Emission of VOC and aldehyde compounds from dry and green wood condition of yellow poplar were investigated with KS M 1998:2009. Based on results, more than 30 compounds were detected from yellow poplar, and lower NVOC (natural VOC) were emitted than AVOC (Anthropogenic VOC) and OVOC (other VOC). Formaldehyde emission was lower than $5{\mu}g/m^3$ and acetaldehyde, ketone, and propionaldehyde were detected from yellow poplar. From dry yellow poplar, m-Tolualdehyde ($33.6{\mu}g/m^3$) was additionally detected while no detection of propionaldehyde. After drying process, amount of ketone emission increased significantly. The unique smell of yellow poplar may not only come from emission of acetaldehyde and propionaldehyde.