• Title/Summary/Keyword: Polyethylene Oxide

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Preparation and Properties of Fireproofing Polyolefin Compound Using Nano Clay (Nano Clay를 이용한 난연성 Polyolefin Compound의 제조 및 특성에 관한 연구)

  • Kang, Doo-Whan;Huh, June
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.2
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    • pp.165-172
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    • 2003
  • Fireproofing polyolefin nanocomposite for the application of power distributing panel was prepared by compounding linear low density polyethylene(LLDPE), decabromodiphenyl oxide (DBDPO), $Sb_2O_3$ as flame retardant agents, and modified nano clay as filler. The optimized formulation ratio of compounds to prepare the fireproofing polyolefin nanocomposite was obtained. The flame retardant properties for nanocomposite prepared by compounding 22.5 phr of nano clay and 18 phr of DBDPO based on 100 phr of LLDPE were shown that the combustion time. 10${\sim}$18 s, combustion distance, 12${\sim}$15 mm and non-melt dropping characteristics. In particular. the content of DBDPO in nanocomposite could be decreased to 18 phr from 40 phr DBDPO for fireproofing composite containing 30 phr of clay. The electrical properties measured from tracking test, had an excellent antitracking properties by not showing the phenomenon of leakage current and sparking.

DNA Separation Using Cellulose Derivatives and PEO by PDMS Microchip

  • Kang, Chung-mu;Back, Seung-Kwon;Song, In-gul;Choi, Byung-ok;Chang, Jun-keun;Cho, Keun-chang;Kim, Yong-seong
    • Bulletin of the Korean Chemical Society
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    • v.27 no.4
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    • pp.519-523
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    • 2006
  • Poly(dimethyl siloxane) (PDMS) has been employed as a microchip material for DNA separation in microfluidic condition. Different sieving molecules such as cellulose derivatives having glucose building block (methyl cellulose (MC), hydroxyethyl cellulose (HEC), and hydroxypropyl methyl cellulose (HPMC)) and polyethylene oxide (PEO) having linear (ring-opened ethylene oxide) unit were used and their performance was compared in terms of separation efficiency and resolution. In general, PEO showed better separation performance than cellulose derivatives probably due to the nature of linear shape polymer conformation. It was possible to perform at least 15 consecutive running with 1.2% PEO at the electric field strength around 200 V/cm. Fast analysis of the standard $\Phi$X 174 RF DNA/Hae III (less than 130s) was obtained with the number of the theoretical plate around 250,000/m. Our PMDS microchip was applied to the measurement of CAG repeat number, which is related to male infertile disease.

Properties of IZTO Thin Films Deposited on PEN Substrates with Different Working Pressures

  • Park, Jong-Chan;Kang, Seong-Jun;Yoon, Yung-Sup
    • Journal of the Korean Ceramic Society
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    • v.52 no.3
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    • pp.224-227
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    • 2015
  • In this work, the properties of Indium-Zinc-Tin-Oxide (IZTO) thin films, deposited on polyethylene naphthalate (PEN) with a $SiO_2$ buffer layer, were analyzed with different working pressures. After depositing the $SiO_2$ buffer layer on PEN substrates by plasma-enhanced chemical vapor deposition (PECVD), the IZTO thin films were deposited by RF magnetron sputtering with 1 to 7-mTorr working pressure. All the IZTO thin films show an amorphous structure, regardless of the working pressure. The best morphological, electrical, and optical properties are obtained at 3-mTorr working pressure, with a surface roughness of 2.112-nm, a sheet resistance of $8.87-{\Omega}/sq$, and a transmittance at 550-nm of 88.44%. These results indicate that IZTO thin films deposited on PEN have outstanding electrical and optical properties, and the PEN plastic substrate is a suitable material for display devices.

Continuous Roll-to-Roll(R2R) sputtering system for growing flexible and transparent conducting oxide electrode at room temperature

  • Park, Yong-Seok;Jeong, Jin-A;Park, Ho-Kyun;Kim, Han-Ki
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1575-1577
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    • 2009
  • We have investigated the characteristics of transparent indium zinc oxide(IZO)/Ag/IZO multilayer electrode grown on polyethylene terephthalate (PET) substrates using a specially designed roll-to-roll sputtering system for use in flexible device are described. By the continuous R2R sputtering of the bottom IZO, Ag, and top IZO layers at room temperature, we were able to fabricate an IZO-Ag-IZO multilayer electrode with a sheet resistance of 6.15 ${\Omega}$/square, optical transmittance of 87.4 %, and figure of merit value of 42.03 10-3 ${\Omega}$-1. In addition, the IZO-Ag-IZO multilayer electrode exhibited superior flexibility to the RTR sputter grown single ITO electrode, due to the existence a ductile Ag layer between the IZO layers. This indicates that the RTR sputtered IZO-Ag-IZO multilayer is a promising flexible electrode that can substitute for the conventional single ITO electrode grown by bath type sputtering for use in low cost flexible device, due to its low resistance, high transparency, superior flexibility and fast preparation by the R2R process.

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Effect of PDMS Index Matching Layer on Characteristics of Mn-Doped SnO2 (MTO)/Ag/MTO/PDMS/MTO Transparent Electrode (PDMS 굴절 조정층이 Mn-Doped SnO2 (MTO)/Ag/MTO/PDMS/MTO 투명전극의 특성에 미치는 영향)

  • Jo, Young-Su;Jang, Gun-Eik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.6
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    • pp.408-411
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    • 2018
  • We fabricated highly flexible Mn-doped $SnO_2$ (MTO)/Ag/MTO/polydimethylsiloxane (PDMS)/MTO multilayer transparent conducting films. To reduce refractive-index mismatching of the MTO/Ag/MTO/polyethylene terephthalate (PET), index-matching layers were inserted between the oxide-metal-oxide-structured films and the PET substrate. The PDMS layer was deposited by spin-coating after adjusting the mixing ratio of PDMS and hexane. We investigated the effects of the index-matching layer on the color and reflectance differences with different PDMS dilution ratios. As the dilution ratio increased from 1:100 to 1:130, the color difference increased slightly, while the reflectance difference decreased from 0.62 to 0.32. The MTO/Ag/MTO/PDMS/MTO film showed a transmittance of 87.18~87.68% at 550 nm. The highest value of the Haacke figure of merit was $47.54{\times}10^{-3}{\Omega}^{-1}$ for the dilution ratio of 1:130.

Fabrication of an Automatic Color-Tuned System with Flexibility Using a Dry Deposited Photoanode

  • Choi, Dahyun;Park, Yoonchan;Lee, Minji;Kim, Kwangmin;Choi, Jung-Oh;Lee, Caroline Sunyong
    • International Journal of Precision Engineering and Manufacturing-Green Technology
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    • v.5 no.5
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    • pp.643-650
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    • 2018
  • A self-powered electrochromic device was fabricated on an indium tin oxide-polyethylene naphthalate flexible substrate using a dye-sensitized solar cell (DSSC) as a self-harvesting source; the electrochromic device was naturally bleached and operated under outdoor light conditions. The color of the organic electrochromic polymer, poly(3,4-ethylenedioxythiophene) polystyrene sulfonate, was shifted from pale blue to deep blue with an antimony tin oxide film as a charge-balanced material. Electrochromic performance was enhanced by secondary doping using dimethyl sulfoxide. As a result, the device showed stable switching behavior with a high transmittance change difference of 40% at its specific wavelength of 630 nm for 6 hrs. To improve the efficiency of the solar cell, 1.0 wt.% of Ag NWs in the photoanode was applied to the $TiO_2$ photoanode. It resulted in an efficiency of 3.3%, leading to an operating voltage of 0.7 V under xenon lamp conditions. As a result, we built a standalone self-harvesting electrochromic system with the performance of transmittance switching of 29% at 630 nm, by connecting with two solar cells in a device. Thus, a self-harvesting and flexible device was fabricated to operate automatically under the irradiated/dark conditions.

Physical Properties of Medical Radiation Shielding Sheet According to Shielding Materials Fusion and Resin Modifier Properties (차폐 재료의 융합과 개질제 특성에 따른 의료방사선 차폐 시트 물리적 특성 고찰)

  • Kim, Seon-Chil
    • Journal of the Korea Convergence Society
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    • v.9 no.12
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    • pp.99-106
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    • 2018
  • The modifier proposed in this research is for enhancing the affinity of the glass component with the high polymer resin and the molecular weight. The particle packing, tensile strength and shielding performance of the shielding sheet made of the tungsten oxide were evaluated. The best effect can be obtained when 20% of the modifier PMMA used to improve the shielding performance and maintain the affinity and strength with the sealant is mixed. The fusion of the materials presented in this study and the mass production of the shielding sheet through the modifier are possible and will contribute to the production of lightweight shielding sheets in the future.

The Effects of Polymer Degradation on the Drag Reduction in CWM Transport (CWM 관수송의 저항 감소현상에 있어서 고분자첨가제의 퇴화 영향에 관한 연구)

  • 송창환;김종보;김인석;최형진
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.10
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    • pp.1908-1914
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    • 1992
  • A significant drag reduction in the turbulent flow of CWM(coal Water Mixture) adding minute amounts of high molecular weight polymer additives has been obtained and it was compared with pure CWM.However, the rate of drag reduction could come down with flow time, which is caused by polymer degradation, The rate of drag reduction and polymer degradation is affected by polymer type, concentration, molecular weight, and flow velocity. In the present investigation, these important parameters were evaluated for their influences on polymer degradation in order to find out stable conditions for CWM transportation with time. It was necessary to determine the more effective type of polymer additives to guarantee the optimum conditions for CWM transport. Experiments were undertaken with a test section of pipe diameter 9.8mm and pipe length 3500mm(L/D=357) in a closed loop, and polyacrylamide and polyetylene oxide were utilized as polymer additives. The tests were carried out under the conditions of 200, 400, 700ppm of polymer concentrations. CWM concentrations utilized were 5% and 10% with flow velocities of 4.9m/s and 6.1m/s. Experimental data show that polyehylene oxide degraded faster than polyacrylamide in CWM transport, and polyacryamide is considered to be a more effective candidate as additive for long time-CWM transport. Polymer degradation is also found to be more likely at lower polymer concentrations, at higher flow velocities, and higher CWM concentrations.

Preparation and Characterization of Low Density Polyethylene (LDPE) and Flower-like Zinc Oxide (FZnO) Composite Films (저밀도폴리에틸렌(LDPE)/꽃 모양 산화아연(FZnO) 복합필름의 제조 및 물성 분석)

  • Kim, Insoo;Lee, Hojun;Kim, Dowan;Seo, Jongchul
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.22 no.3
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    • pp.85-93
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    • 2016
  • Flower-like zinc oxide (FZnO) was successfully synthesized via a sonochemical process. The chemical structure, morphology, and antimicrobial properties of as- prepared FZnO were investigated. Additionally, pure LDPE and five different LDPE/FZnO composite films were prepared with different FZnO content by using a twin screw extruder. According to the FTIR and SEM analyses, there exists weak interfacial interaction between LDPE and FZnO. Compared with pure LDPE, the LDPE/FZnO composite films showed UV barrier and enhanced antimicrobial activity against Escherichia coli (E. coli) as a Gram-negative micro-organism and Staphylococcus aureus (S. aureus) as a Gram-positive micro-organism. To enhance the interfacial interaction and good dispersion of FZnO into the LDPE matrix, and resultantly to such as UV barrier and antimicrobial properties of LDPE/FZnO composite films as the packaging materials, further efforts are required.

The Effect of Polyethylene Oxide on the Aggregation State and Toxicity of Amphotericin B (폴리에틸렌 옥사이드가 암포테리신-B의 응집 특성 및 독성에 미치는 영향)

  • Yu, Bong-G.
    • Journal of Pharmaceutical Investigation
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    • v.31 no.1
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    • pp.7-12
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    • 2001
  • Amphotericin B (AmB) is a drug of choice for the treatment of systemic fungal diseases, but its use is considerably limited due to a high incidence of toxicity, particularly nephrotoxicity. It has been demonstrated that the toxicity of AmB is caused by self-aggregated species of the drug and that unaggregated (monomeric) drug is nontoxic but still expresses antifungal activity. Poly (ethylene oxide) (PEO) is a water-soluble polymer, which may impact the aggregation state of AmB. We have studied the aggregation state of AmB as a function of PEO molecular weight and concentration. At 3,000 and 8,000 g/mole, there was minimal or no change of critical aggregation concentration (CAC) of AmB regardless of the concentration of polymer. By contrast at 20,000 g/mole, the CAC of AmB strikingly increased to 24.3 and $37.5\;{\mu}M$ at 5.0% and 10 % w/v of polymer, respectively. The critical overlap concentration (COC) of PEO 20,000 g/mole was 5.5%. It appears that an interaction between monomeric AmB and polymer coil increases above the COC, competing with self-aggregation of the drug. Accordingly, the degree of aggregation of AmB stayed low and the toxicity became less. There was no such effect at 3,000 and 8,000 g/mole of PEO, owing perhaps to small dimensions in comparison to AmB. Based upon these findings, less toxic AmB formulation may be developed by a pharmaceutical technique such as solid dispersion system containing both AmB and PEO 20,000 g/mole.

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