• 제목/요약/키워드: Picosecond

검색결과 116건 처리시간 0.025초

TCSPC에 의한 DODCI의 형광 소멸시간 및 비등방성 측정 연구 (Lifetime and Anisotropy Measurements of DODCI in the excited state by TCSPC)

  • 이민영;김동호
    • 한국광학회지
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    • 제1권1호
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    • pp.52-57
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    • 1990
  • 피코초 레이저와 고속 전자장치를 사용하여 subnanosecond에서 microsecond 넓은 범위에 걸쳐서 발광 소멸 시간을 측정할 수 있는 time-correlated single photon counting(TCSPC) 장치를 개발하였다. 이 TCPSC를 사용하여 색소레이저에 있어서 saturable absorber로 많이 쓰이는 DODCI의 소멸시간 및 회전 완화시간을 측정함으로써 여기상태에서의 동력학과 회전운동에 관해 연구하였다.

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Picosecond Dynamics of CN--Ligated Ferric Cytochrome c after Photoexcitation Using Time-resolved Vibrational Spectroscopy

  • Kim, Joo-Young;Park, Jae-Heung;Chowdhury, Salina A.;Lim, Man-Ho
    • Bulletin of the Korean Chemical Society
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    • 제31권12호
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    • pp.3771-3776
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    • 2010
  • The dynamics of the $CN^-$-ligated ferric cytochrome c (CytcCN) in $D_2O$ at 283 K following Q-band photoexcitation at 575 nm was observed using femtosecond time-resolved vibrational spectroscopy. The equilibrium vibrational spectrum of the CN stretching mode of CytcCN shows two overlapping bands: one main band (82%) at $2122\;cm^{-1}$ with $23\;cm^{-1}$ full width at half maximum (fwhm) and the other band (18%) at $2116\;cm^{-1}$ with $7\;cm^{-1}$ fwhm. The time-resolved spectra show bleaching of the CN fundamental mode of CytcCN and two absorption features at lower energies. The bleach signal and both absorption features are all formed within the time resolution of the experiment (< 200 fs) and decay with a life time of 1.9 ps. One transient absorption feature, appearing immediately red to the bleach signal, results from the thermal excitation of low-frequency modes of the heme that anharmonically couple to the CN fundamental mode, thereby shifting the CN mode to lower energies. The shift of the CN mode decays with a lifetime of 2 ps, equivalent to the time scale for vibrational cooling of the low-frequency heme modes. The other transient absorption feature, which is 3.3 times weaker than the bleach signal and shifted $27\;cm^{-1}$ toward lower energies, is attributed to the CN mode in an electronically excited state where the CN bond is weakened with a lowered extinction coefficient. These observations suggest that photoexcited CytcCN mainly undergoes ultrafast radiationless relaxation, causing photo-deligation of $CN^-$ from CytcCN highly inefficient. As also observed in $CN^-$-ligated myoglobin, inefficient ligand photodissociation might be a general property of $CN^-$-ligated ferric hemes.

Effectiveness of the Pico-toning Technique for the Treatment of Melasma with a Low Fluence 1,064-nm Nd:YAG Laser in Asian Patients

  • Kim, Dong Gyu;Nam, Seung Min;Shin, Jin Soo;Park, Eun Soo
    • Medical Lasers
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    • 제9권2호
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    • pp.166-171
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    • 2020
  • Background and Objectives Melasma is an acquired pigmentary disorder characterized by brown or dark brown colored macules and patches which mostly involve the face. Compared to nanosecond lasers, picosecond lasers have fewer adverse effects on surrounding tissues and give better results for melanin fragmentation. The purpose of this study was to evaluate the efficacy of the pico-toning technique using a low fluence 1,064-nm Nd:YAG laser on melasma patients. Materials and Methods This study is a retrospective analysis of melasma cases treated using the pico-toning technique from June 2017 to November 2020. Based on photographic images, the modified Melasma Area and Severity Index (mMASI) score was blind evaluated by two independent plastic surgeons. Patient satisfaction was assessed through a 5-point Likert scale questionnaire after treatment sessions. All adverse effects and complications were reviewed based on medical records. Results A total of 23 patients were included in the study. The mMASI scores for baseline and 2 months after the last procedure were 5.1 ± 1.4 and 2.6 ± 0.4, respectively. The mean mMASI score reduced significantly after the treatment session (p < 0.05). The patient satisfaction score with the procedure was 3.8 ± 1.0. The subject satisfaction score and difference in the mMASI score before the procedure and 2 months after the last procedure showed a significant correlation. Adverse effects observed in this study were erythema (n = 1) and edema (n = 1). Conclusion The results of the study show that the pico-toning technique is effective in Asian patients with melasma. We believe that safety was enhanced by using low fluence, and thus better results were achieved with fewer adverse effects.

DC/SFQ 회로의 시뮬레이션 및 작동 (Simulation and Operation of DC/SFQ Circuit)

  • 박종혁;정구락;임해용;한택상;강준희
    • 한국초전도저온공학회:학술대회논문집
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    • 한국초전도저온공학회 2002년도 학술대회 논문집
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    • pp.109-110
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    • 2002
  • The purpose of a superconductive DC/SFQ circuit is to produce a controlled number of picosecond single flux quantum pulses at the output when a slowly changing DC current is applied to the input. In this work, we have designed and simulated a DC/SFQ circuit based on Nb/Al$O_{x}$/Nb Josephson junction technology. From the simulation, we could obtain the margins for various circuit parameters. And also we have successfully operated a DC/SFQ circuit which was fabricated with the same design. The margin for the input bias current of the circuit was observed to be of $\pm$60%, which was very close to the simulated value.

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F-Center Excitation Energy Transfer to CN$^-$ vibrational Levels in CsCl

  • Jang, Du-Jeon
    • 한국광학회:학술대회논문집
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    • 한국광학회 1990년도 광학 및 양자전자학 워크샵
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    • pp.94-100
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    • 1990
  • The rapid quenching dynamics of the F-center excitation by CN- defects in CsCl crystals were investigated by monitoring the ground state bleach recovery kinetics of F-centers, using a picosecond streak camera absorption spectrometer. The F-centers in CN- doped quenched samples show two bleach recovery components. Optical aggregation converts the slow component to the fast component. The slow one is due to the normal relaxation of the F*-centers as found in CN_ free crystals. The fast one is due to the energy transfer of the F-center electronic excitation to the vibrational energy levels of CN_ molecualr defects. The energy transfer occurs only in the F-center-CN_ defect pairs, FH(CN_)-centers.

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3차 교차상관신호의 역상관을 통한 펨토초 및 처프된 피코초 펄스의 정확한 선행펄스 대비율 측정 (Accurate Contrast-ratio Measurement of Femtosecond and Chirped Picosecond Pulses from the Decorrelation of Third-order Correlation Trace)

  • Hong, Kyung-Han;Sung, Jae-Hee;Yu, Tae-Jun;Choi, Il-Woo;Kim, Hyung-Taek;Noh, Young-Chul;Ko, Do-Kyeong;Lee, Jong-Min
    • 한국광학회:학술대회논문집
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    • 한국광학회 2007년도 동계학술발표회 논문집
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    • pp.349-350
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    • 2007
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매우 짧은 전자기 펄스 수신을 위한 저항성 모노폴 센서의 특성 분석 (Analysis of Characteristics of Resistive Monopole Sensors for Receiving Very Short Electromagnetic Pulses)

  • 최용호;전상재;전광진;박의준
    • 한국전자파학회:학술대회논문집
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    • 한국전자파학회 2003년도 종합학술발표회 논문집 Vol.13 No.1
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    • pp.550-554
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    • 2003
  • In order to detect very short electromagnetic pulses (EMP) with picosecond width, a receiving antenna with a wide bandwidth and good sensitivity over several GHz is needed. In this paper, the receiving characteristics of various thin wire monopole (or dipole) antennas with nonreflecting resistive loading are analyzed for determining the optimum configurations. This study also indicates that it is possible to choose an ideal load impedance for achieving the required fidelity and sensitivity. The analysis is facilitated by introducing the frequency transfer function.

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Intramolecular Hydrogen Bonds in Proteinase Inhibitor Protein, A Molecular Dynamics Simulation Study

  • Chung, Hye-Shin
    • BMB Reports
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    • 제29권4호
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    • pp.380-385
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    • 1996
  • Ovomucoid third domain is a serine proteinase inhibitor protein which consists of 56 amino acid residues. A fifty picosecond molecular dynamics (MD) simulation was carried out for ovomucoid third domain protein with 5 $\AA$ layer of water molecules. A comparison of main chain atoms in the MD averaged structure with the crystal structure showed that most of the backbone structures are maintained during the simulation. Investigation of the intramolecular hydrogen bondings indicated that most of the interactions between main chain atoms were conserved, whereas those between side chains were reorganized for the period of the simulation. Especially, the side chain interactions around the scissile bond of reactive site P1 (Met18) were found to be more extensive for the MD structures. During the simulation, hydrogen bonds were maintained between the side chains of Glu19 and Arg21 as well as those of Thr17 and Glu19. Extensive side chain interactions observed in the MD structures may shed light on the question of why protein proteinase inhibitors are strong inhibitors for proteinases rather than good substrates.

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초고속 전자 현미경의 개발과 극복 과제 (Challenges in the development of the ultrafast electron microscope)

  • 박두재
    • 진공이야기
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    • 제2권1호
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    • pp.17-20
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    • 2015
  • In this article, a historical and scientific review on the development of an ultrafast electron microscope is supplied, and the challenges in further improvement of time resolution under sub-picosecond or even sub-femtosecond scale is reviewed. By combining conventional scanning electron microscope and femtosecond laser technique, an ultrafast electron microscope was invented. To overcome its temporal resolution limit which originates from chromatic aberration and Coulomb repulsion between individual electrons, a generation of electron pulse via strong-field photoemission has been investigated thoroughly. Recent studies reveal that the field enhancement and field accumulation associated with the near-field formation at sharply etched metal nanoprobe enabled such field emission by ordinary femtosecond laser irradiation. Moreover, a considerable acceleration reaching 20 eV with near-infrared laser and up to 300 eV acceleration with mid-infrared laser was observed, and the possibility to control the amount of acceleration by varying the incident laser pulse intensity and wavelength. Such findings are noteworthy because of the possibility of realizing a sub-femtosecond, few nanometer imaging of nanostructured sample.in silicon as thermoelectric materials.

Optical Failure Analysis Technique in Deep Submicron CMOS Integrated Circuits

  • Kim, Sunk-Won;Lee, Hyong-Min;Lee, Hyun-Joong;Woo, Jong-Kwan;Cheon, Jun-Ho;Kim, Hwan-Yong;Park, Young-June;Kim, Su-Hwan
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제11권4호
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    • pp.302-308
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    • 2011
  • In this paper, we have proposed a new approach for optical failure analysis which employs a CMOS photon-emitting circuitry, consisting of a flip-flop based on a sense amplifier and a photon-emitting device. This method can be used even with deep-submicron processes where conventional optical failure analyses are difficult to use due to the low sensitivity in the near infrared (NIR) region of the spectrum. The effectiveness of our approach has been proved by the failure analysis of a prototype designed and fabricated in 0.18 ${\mu}m$ CMOS process.