• Title/Summary/Keyword: Phase stability

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Phase Stability and Plasma Erosion Resistance of La-Gd-Y Rare-earth Oxide - Al2O3 Ceramics (La-Gd-Y 희토류계 산화물-알루미나 세라믹스의 상안정화 영역과 내플라즈마 특성)

  • Kim, Kyeong-Beom;Lee, Sung-Min
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.540-545
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    • 2010
  • In this study, we have investigated new plasma resistant materials with less usage of rare-earth oxides than $Y_2O_3$ which is currently used in the semiconductor industry. We observed the stability ranges of $(Gd{\cdot}Y)_3Al_5O_{12}$ and $(La{\cdot}Y)Al_{11}O_{18}$ ternary systems, and measured their etch rates under typical fluorine plasma. $(Gd{\cdot}Y)_3Al_5O_{12}$ system showed an extensive solid solution up to 80 mol% gadolinium, but $(La{\cdot}Y)Al_{11}O_{18}$ showed a negligible substitution between rare-earth ions, which can be explained by the differences between the ionic radii. The etch rates depended on the total amount of rare-earth oxides but not on the substitution of the rare-earth ions. When the specimen was examined using XPS after the exposure to fluorine plasma, the strong surface fluorination was observed with a shift of the binding energy to higher energy.

Preparation and Characterization of EGCG Entrapped Ethosome (EGCG가 포집된 Ethosome의 제조와 특성조사)

  • Gwak, Hyo Jung;Jin, Byung Suk
    • Applied Chemistry for Engineering
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    • v.18 no.2
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    • pp.130-135
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    • 2007
  • Entrapment of (-)-epigallocatechin gallate (EGCG) into ethosome was carried out for improving its stability against decomposition. Solubility of EGCG was increased by the addition of ethanol into water, which enable ethosome to entrap appropriate amount of EGCG. It was observed that the EGCG solution concentration and constituent lipid composition had a considerable effect on the particle size and entrapment efficiency of ethosomes. The formation of liquid crystalline phase in ethosome was investigated by polarized optical microscopy. By comparing the stability of EGCG in solution and in ethosome exposed to UV or high temperature, we evaluated the EGCG stabilization effect through its entrapment in ethosome. Incorporation of tocopherol into ethosome retarded the decomposition of EGCG under UV.

First-order Generalized Integrator Based Frequency Locked Loop and Synchronization for Three-Phase Grid-connected Converters under Adverse Grid Conditions

  • Luo, Zhaoxu;Su, Mei;Sun, Yao;Liu, Zhangjie;Dong, Mi
    • Journal of Power Electronics
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    • v.16 no.5
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    • pp.1939-1949
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    • 2016
  • This paper presents an alternative frequency adaptive grid synchronization technique named HDN-FLL, which can accurately extract the fundamental positive- and negative-sequence components and interested harmonics in adverse three-phase grid voltage. The HDN-FLL is based on the harmonic decoupling network (HDN) consisting of multiple first order complex vector filters (FOCVF) with a frequency-locked loop (FLL), which makes the system frequency adaptive. The stability of the proposed FLL is strictly verified to be global asymptotically stable. In addition, the linearization and parameters tuning of the FLL is also discussed. The structure of the HDN has been widely used as a prefilter in grid synchronization techniques. However, the stability of the general HDN is seldom discussed. In this paper, the transfer function expression of the general HDN is deduced and its stability is verified by the root locus method. To show the advantages of the HDN-FLL, a simulation comparison with other gird synchronization methods is carried out. Experimental results verify the excellent performance of the proposed synchronization method.

Dual-Loop Power Control for Single-Phase Grid-Connected Converters with LCL Filter

  • Peng, Shuangjian;Luo, An;Chen, Yandong;Lv, Zhipeng
    • Journal of Power Electronics
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    • v.11 no.4
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    • pp.456-463
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    • 2011
  • Grid-connected converters have widely adopted LCL filters to acquire high harmonic suppression. However, the LCL filter increases the system order so that the design of the system stability would be complicated. Recently, sole-loop control strategies have been used for grid-connected converters with L or LC filters. But if the sole-loop control is directly transplanted to grid-connected converters with LCL filters, the systems may be unstable. This paper presents a novel dual-loop power control strategy composed of a power outer loop and a current inner loop. The outer loop regulates the grid-connected power. The inner loop improves the system stability margin and suppresses the resonant peak caused by the LCL filter. To obtain the control variables, a single-phase current detection is proposed based on PQ theory. The system transfer function is derived in detail and the influence of control gains on the system stability is analyzed with the root locus. Simulation and experimental results demonstrate the feasibility of the proposed control.

Linearized Dynamic Analysis of a Four-Wheel Steering Vehicle (Bicycle 모델을 이용한 4륜 조향 차량의 동력학 해석)

  • Lee, Y.H.;Kim, S.I.;Suh, M.W.;Son, H.S.;Kim, S.H.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.2 no.5
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    • pp.101-109
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    • 1994
  • Recently, four-wheel steering systems have been developed and studied as one of the latest automotive technologies for improving the handling characteristics of a vehicle. In much of the proposed four-wheel steering systems, the side slip angle at the vehicle's center of gravity is maintained at zero. This approach allows the greater maneuverability at low speed by means of counter-phase rear steering and the improved stability at high speed through same-phase rear steering. In this paper, the effects of several four-wheel steering systems are studied and discussed on the responsiveness and stability of the vehicle by using the linear analysis. Especially, the effects of the cornering stiffnesses of both front and rear wheels are investigated on the yaw velocity gain and critical speed of the vehicle.

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EVALUATION OF DATA QUALITY OF PERMANENT GPS STATIONS IN SOUTH KOREA

  • Park, Kwan-Dong;Kim, Ki-Nam;Lim, Hyung-Chul;Park, Pil-Ho
    • Journal of Astronomy and Space Sciences
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    • v.19 no.4
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    • pp.367-376
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    • 2002
  • As of September 2002, there are more than 60 operational permanent Global Positioning System (GPS) stations in South Korea. Their data are being used for a variety of purposes: geodynamics, geodesy, real-time navigation, atmospheric science, and geography. Especially, many of the sites are reference stations for DGPS (Differential GPS). However, there has been no comprehensive and qualitative analysis published to evaluate the data quality. In this study, we present preliminary results of our assessment of the permanent GPS sites in South Korea. We have analyzed the multi-path characteristics of each station using a quality-checking software package called TEQC. Another multipath analysis tool based on post-fit phase residuals was used to check the repeating patterns and the amount of the multipath at each site. The long-term stability of each station was analyzed using the root-mean-square (RMS) error of the estimated site positions for one year, which enabled us to evaluate the mount stability. In addition, the number of cycle slips at each site was derived by TEQC. Based on these series of tests, we compared the stability and data quality of permanent GPS stations in South Korea.

Evaluation on the Safety of ${\gamma}$-Irradiated Angelica gigas Nakai: Stability of Active Components and Safety in Genotoxicity Test (감마선 조사 당귀(Angelica gigas Nakai)의 유효성분 안정성 및 유전독성학적 안전성 연구)

  • 조성기;유영법
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.29 no.2
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    • pp.300-306
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    • 2000
  • In the present studies, we assessed the stability of active components and toxicological safety of irradiated Angelica gigas Nakai(Danggui). In order to confirm the stability of active components in the ${\gamma}$-irradiated roots of Danggui, the quantitative analysis of decursin and decursinol angelate of ${\gamma}$-irradiated sample was carried out by high performance liquid chromatographic (HPLC) methods using reverse phase columns and normal phase columns. From the root of Danggui, decursin and decursinol angelate were isolated by a silica gel column chromatography(toluene : ether (1 : 1), Hexane : EtOAc(15 : 1)). And then the structures were confirmed in the 1H and 13C-NMR analysis. The HPLC chromatograms of decursin and decursinol angelate in ${\gamma}$-irradiated Danggui were similar with those of non-irradiated sample. In the examination of in vitro genotoxicity of the water extract from ${\gamma}$-irradiated Danggui using Salmonella reversion assay(Ames test) and micronucleus test in Chinese hamster ovary (CHO) cells, mutagenicity was not exhibited in the two assays with or without metabolic activation. These resutls suggest that active components in the ${\gamma}$-irradiated Danggui should be stable and that the safety of ${\gamma}$-irradiated Danggui could be revealed in further test in vivo.

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Long-term Stability Optimization of Dynamic Spectroscopic Ellipsometery based on Dual-wavelength Calibration (이중 파장 보정방법 기반 다이나믹 분광타원편광계의 안정도 최적화)

  • Choi, Inho;Kheiryzadehkhanghah, Saeid;Choi, Sukhyun;Hwang, Gukhyeon;Shim, Junbo;Kim, Daesuk
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.3
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    • pp.178-183
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    • 2021
  • This paper describes a dynamic spectroscopic ellipsometry based on dual-wavelength calibration. DSE provides ellipsometric parameters at rates above 20 Hz, but the interferometer's sensitivity to temperature makes it difficult for that proposed system to maintain stable 𝜟k over long periods of time. To solve this problem, we set up an additional path in the DSE to perform simulations of the polarization phase calibration method using dual wavelengths. Through simulation, we were able to eliminate most of the polarization phase error and maintain a stable 𝜟k in the long-term stability experiment for 10 hours. This is the result that the 𝜟k stability of the proposed system is improved tens of times compared to the existing system.

Analyzing the bearing capacity of shallow foundations on two-layered soil using two novel cosmology-based optimization techniques

  • Gor, Mesut
    • Smart Structures and Systems
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    • v.29 no.3
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    • pp.513-522
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    • 2022
  • Due to the importance of accurate analysis of bearing capacity in civil engineering projects, this paper studies the efficiency of two novel metaheuristic-based models for this objective. To this end, black hole algorithm (BHA) and multi-verse optimizer (MVO) are synthesized with an artificial neural network (ANN) to build the proposed hybrid models. Based on the settlement of a two-layered soil (and a shallow footing) system, the stability values (SV) of 0 and 1 (indicating the stability and failure, respectively) are set as the targets. Each model predicted the SV for 901 stages. The results indicated that the BHA and MVO can increase the accuracy (i.e., the area under the receiving operating characteristic curve) of the ANN from 94.0% to 96.3 and 97.2% in analyzing the SV pattern. Moreover, the prediction accuracy rose from 93.1% to 94.4 and 95.0%. Also, a comparison between the ANN's error decreased by the BHA and MVO (7.92% vs. 18.08% in the training phase and 6.28% vs. 13.62% in the testing phase) showed that the MVO is a more efficient optimizer. Hence, the suggested MVO-ANN can be used as a reliable approach for the practical estimation of bearing capacity.

Effect of Sintering Holding Time and Cooling Rate on the Austenite Stability and Mechanical Properties of Nanocrystalline FeCrC Alloy

  • Gwanghun Kim;Junhyub Jeon;Namhyuk Seo;Seunggyu Choi;Min-Suk Oh;Seung Bae Son;Seok-Jae Lee
    • Archives of Metallurgy and Materials
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    • v.66 no.3
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    • pp.759-763
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    • 2021
  • The effects of the sintering holding time and cooling rate on the microstructure and mechanical properties of nanocrystalline Fe-Cr-C alloy were investigated. Nanocrystalline Fe-1.5Cr-1C (wt.%) alloy was fabricated by mechanical alloying and spark plasma sintering. Different process conditions were applied to fabricate the sintered samples. The phase fraction and grain size were measured using X-ray powder diffraction and confirmed by electron backscatter diffraction. The stability and volume fraction of the austenite phase, which could affect the mechanical properties of the Fe-based alloy, were calculated using an empirical equation. The sample names consist of a number and a letter, which correspond to the holding time and cooling method, respectively. For the 0A, 0W, 10A, and 10W samples, the volume fraction was measured at 5.56, 44.95, 6.15, and 61.44 vol.%. To evaluate the mechanical properties, the hardness of 0A, 0W, 10A, and 10W samples were measured as 44.6, 63.1, 42.5, and 53.8 HRC. These results show that there is a difference in carbon diffusion and solubility depending on the sintering holding time and cooling rate.