• Title/Summary/Keyword: Phase Equation

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Phase Equilibria in Multicomponent Mixtures using Continuous Thermodynamics (연속열역학을 이용한 다성분 혼합물의 상평형)

  • Yong, Pyeong-Soon;Kim, Ki-Chang;Kwon, Yong Jung
    • Journal of Industrial Technology
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    • v.18
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    • pp.267-275
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    • 1998
  • Continuous thermodynamics has been applied for modeling of phase equilibria in multicomponent mixtures, to avoid disadvantages of the pseudo-component and key-component method. In this paper continuous thermodynamic relations formulated by using the Pate-Teja equation of state were adopted for calculations of phase equilibria in natural gas mixtures, crude oil mixtures and mixtures extracted by supercritical $CO_2$ fluids. Calculations of phase equilibria were performed by two procedures ; a moment method coupled with the beta distribution function and a quadrature method combined with Gaussian-Legendre polynomials. Calculated results were compared with experimental data. It was showed that continuous thermodynamic frameworks considered in this paper were well-matched to experimental data.

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Evaluation of Phase Transition Behavior of Ge2Sb2Te5 Thin Film for Phase Change Random Access Memory (상변환 메모리의 응용을 위한 Ge2Sb2Te5 박막의 상변환 거동 평가)

  • Do, Woo-Hyuk;Kim, Sung-Soon;Bae, Jun-Hyun;Cha, Jun-Ho;Kim, Kyung-Ho;Lee, Young-Kook;Lee, Hong-Lim
    • Journal of the Korean Ceramic Society
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    • v.44 no.1 s.296
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    • pp.18-22
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    • 2007
  • The phase transition behavior of $Ge_2Sb_2Te_5$ (GST) thin film, which is a candidate material of recording layer for phase change random access memory (PRAM), has been evaluated using an in-situ reflectance measurement method. The experimental data have been analyzed by using johnson-mehl-avrami-kolomogorov (JMAK) model. JMAK model can be used only in isothermal state. However, temperature changes with time during the operation of PRAM. To apply JMAK equation to PRAM simulation, it has been assumed that the temperature increases stepwise and isothermally. By using JMAK equation and assumption for the transient state, the phase transition behavior of GST thin film has been predicted under $3^{\circ}C/min$ heating rate in this study. The simulation result agrees well with the experimental results. Therefore, It can be concluded that JMAK equation can be used far the PRAM simulation model.

Estimation of Density of Methane and Ethane and Vapor-Liquid Equilibrium Predictions for Methane-Ethane Binary System Using PR and PC-SAFT Equations of State (PR 및 PC-SAFT 상태방정식을 이용한 메탄과 에탄의 기상과 액상의 밀도 추산 및 이성분계의 기-액 상평형 계산)

  • Park, Jong-Kee;Choi, Kun-Hyung;Lee, Sang-Gyu;Yang, Young-Myung;Cho, Jung-Ho
    • Journal of the Korean Institute of Gas
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    • v.14 no.2
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    • pp.22-26
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    • 2010
  • In this study, experimental vapor pressures and densities of vapor and liquid phases versus temperature were estimated using PC-SAFT equation. The estimated results were compared with those using PR equation of state. For the vapor phase densities, both equations well predicted the literature data. However, PC-SAFT equation showed better prediction capability for liquid phase densities. In the comparison of vapor-liquid equilibrium prediction capability for the binary systems of methane and ethane, PC-SAFT equation was better than the PR equation.

A Study on Application of Mathematics History of Chosun Dynasty to a Quadratic Equation of Middle School (중학교 이차방정식 단원에서 조선시대(朝鮮時代) 수학사(數學史)의 활용에 대한 연구)

  • Shim, Sang-Kil
    • Journal for History of Mathematics
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    • v.22 no.2
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    • pp.117-130
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    • 2009
  • This study shows how to use effectively construction and solution of the quadratic equation developed by mathematicians such as Gyung Sun-jing, Hong Jung-ha, Hong Dae-yong, Lee Sang-hyuk, and Nam Byung-gil through mathematics history of Chosun Dynasty. Mathematics history of Chosun Dynasty can be used in order to enhance comprehension and increase interest in an introduction to the quadratic equation. It also can be used to help motivate middle school students to solve the quadratic equation with much interest during the development phase, and develope conceptual thinking and reflective thinking in the practical phase.

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Partition method of wall friction and interfacial drag force model for horizontal two-phase flows

  • Hibiki, Takashi;Jeong, Jae Jun
    • Nuclear Engineering and Technology
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    • v.54 no.4
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    • pp.1495-1507
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    • 2022
  • The improvement of thermal-hydraulic analysis techniques is essential to ensure the safety and reliability of nuclear power plants. The one-dimensional two-fluid model has been adopted in state-of-the-art thermal-hydraulic system codes. Current constitutive equations used in the system codes reach a mature level. Some exceptions are the partition method of wall friction in the momentum equation of the two-fluid model and the interfacial drag force model for a horizontal two-phase flow. This study is focused on deriving the partition method of wall friction in the momentum equation of the two-fluid model and modeling the interfacial drag force model for a horizontal bubbly flow. The one-dimensional momentum equation in the two-fluid model is derived from the local momentum equation. The derived one-dimensional momentum equation demonstrates that total wall friction should be apportioned to gas and liquid phases based on the phasic volume fraction, which is the same as that used in the SPACE code. The constitutive equations for the interfacial drag force are also identified. Based on the assessments, the Rassame-Hibiki correlation, Hibiki-Ishii correlation, Ishii-Zuber correlation, and Rassame-Hibiki correlation are recommended for computing the distribution parameter, interfacial area concentration, drag coefficient, and relative velocity covariance of a horizontal bubbly flow, respectively.

Estimation of Ammonia Emission During Composting Iivestock Manure Based on the Degree of Compost Maturity (축분 퇴비화 과정 중 퇴비 부숙도를 고려한 암모니아 발생량 산정)

  • 김기연;최홍림;고한종;김치년
    • Journal of Animal Science and Technology
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    • v.48 no.1
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    • pp.123-130
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    • 2006
  • Principal aim of this study is to suggest the statistical equation model which can predict an amount of ammonia emission according to the degree of compost maturity during composting livestock manure. Composting process was classified with intial, midterm and final phase based on germination index of compost samples. Total Kjeldahl nitrogen(TKN) and organic matter(OM) were selected as the independent variables available to contribute to ammonia emission from composting pile. Ammonia concentration measured in the samples taken at the intial phase was about 10ppm, sharply increased to 50ppm at the midterm phase, and gradually decreased to about 10ppm. The contents of Total Kjeldahl nitrogen and organic matter through whole composting period were ranged from 0.6 to 1.2% and from 30 to 40%, respectively, were reduced slightly at the midterm phase, but generally showed no constant fluctuation pattern. In estimating ammonia emission with application of the statistical equation model, the coefficients of independent variables at the midterm phase when an average concentration of ammonia was highest showed a relatively high values whereas those at the initial phase when an that of ammonia was lowest indicated a relatively low values. However, no statistical significance was found in the coefficients of independent variables and the equation model. Additionally, the further research, which can include the considerable analysis data with more samples taken than this study, is needed in order to suggest the statistically significant equation model available to predict ammonia emission during composting process.

A Linear Wave Equation Over Mild-Sloped Bed from Double Integration (이중적분을 이용한 완경사면에서의 선형파 방정식)

  • Kim, Hyo-Seob;Jung, Byung-Soon;Lee, Ye-Won
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.12 no.3
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    • pp.165-172
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    • 2009
  • A set of equations for description of transformation of harmonic waves is proposed here. Velocity potential function and separation of variables are introduced for the derivation. The continuity equation is in a vertical plane is integrated through the water so that a horizontal one-dimensional wave equation is produced. The new equation composed of the complex velocity potential function, further be modified into. A set up of equations composed of the wave amplitude and wave phase gradient. The horizontally one-dimensional equations on the wave amplitude and wave phase gradient are the first and second-order ordinary differential equations. They are solved in a one-way marching manner starting from a side where boundary values are supplied, i.e. the wave amplitude, the wave amplitude gradient, and the wave phase gradient. Simple spatially-centered finite difference schemes are adopted for the present set of equations. The equations set is applied to three test cases, Booij's inclined plane slope profile, Massel's smooth bed profile, and Bragg's wavy bed profile. The present equations set is satisfactorily verified against existing theories including Massel's modified mild-slope equation, Berkhoff's mild-slope equation, and the full linear equation.

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Dynamic Analysis of a 3-Phase BLDC Motor Considering Variation of an Air-Gap (공극의 시간변화를 고려한 3 상 BLDC 모터의 동특성 해석)

  • Park, Ki-Sun;Im, Hyung-Bin;Chung, Jin-Tai
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.33 no.10
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    • pp.1038-1044
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    • 2009
  • In this study, vibrations of an electric motor are analyzed when the motor has the interaction between mechanical and electromagnetic behaviors. For this vibration analysis a 3-phase 8-pole brushless DC motor is selected. Vibrations of the motor are influenced by coupled electromechanical characteristics. The variation of air-gap induced by vibration has an influence on the inductance of the motor coil. To analyze dynamic characteristics of the rotor, we studied inductance by the variation of an air-gap. After obtaining the kinetic, potential and magnetic energies for the motor, the equations of motion are derived by using Lagrange's equation. By applying the Newmark time integration method to the equations, the dynamic responses for the displacements and currents are computed.

Numerical Modeling of Soot Formation in $C_2H_4$/Air Turbulent Non-premixed Flames ($C_2H_4$/Air 비예혼합 난류화염의 매연생성 모델링)

  • Kim, Tae-Hoon;Woo, Min-O;Kim, Yong-Mo
    • Journal of the Korean Society of Combustion
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    • v.15 no.4
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    • pp.22-28
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    • 2010
  • The Direct Quadrature Method of Moments (DQMOM) has been presented for the solution of population balance equation in the wide range of the multi-phase flows. This method has the inherently interesting features which can be easily applied to the multi-inner variable equation. In addition, DQMOM is capable of easily coupling the gas phase with the discrete phases while it requires the relatively low computational cost. Soot inception, subsequent aggregation, surface growth and oxidation are described through a population balance model solved with the DQMOM for soot formation. This approach is also able to represent the evolution of the soot particle size distribution. The turbulence-chemistry interaction is represented by the laminar flamelet model together with the presumed PDF approach and the spherical harmonic P-1 approximation is adopted to account for the radiative heat transfer.

Interrelationship Between the Drift-flux Model and the Two-fluid Model (드리프트 플럭스 모델과 2-유체 모델 사이의 상관 관계)

  • No, Hee-Cheon
    • Nuclear Engineering and Technology
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    • v.25 no.2
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    • pp.233-236
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    • 1993
  • For one-dimensional two-phase flow without phase change and without axially-temporally rapid change of pressure, the interrelationship between the drift-flux model and the two-fluid model is studied. It is derived on the basis of the fact that the vapor conservation equation is related to the momentum equation by the drift flux. Starting from the two-fluid model, we obtain the interfacial friction expressed in terms of drift-flux parameter. Also, by deriving the void propagation equation, the drift-flux is shown to have jnterrelationship with forces in the two-fluid model.

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