• Polymer(Korea)
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• v.36 no.5
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• pp.593-598
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• 2012

Solution polymerization behaviors of L-lactide using single and mixed aluminium catalyst systems were studied. Triisobutylaluminium (TIBA) was a reference catalyst for mixing. For the $Al(O-i-Pr)_3$/TIBA catalytic systems, the molecular weight of the resulting polylactide (PLA) decreased as the composition of $Al(O-i-Pr)_3$ increased. The higher molecular weight shoulder was revealed in their GPC curve. At TIBA of 80 mol% a bimodal GPC curve was shown. The conversion in the trimethylaluminium (TMA)/TIBA catalysts system decreased as the composition of TMA in the mixed catalyst increased. The conversion in the trioctylaluminium (TOA)/TIBA catalysts system decreased as the composition of TOA in the mixed catalyst increased. The unimodal molecular weight distribution was observed with the TOA/TIBA catalyst systems. The Al compounds-mixed catalyst could produce a higher molecular weight shoulder in the GPC curve.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.31 no.1
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• pp.49-55
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• 2013

In this paper, we proposed a good classifier to match different spatial data sets by applying evaluation of classifiers performance in data mining and biometrics. For this, we calculated distances between a pair of candidate features for matching criteria, and normalized the distances by Min-Max method and Tanh (TH) method. We defined classifiers that shape similarity is derived from fusion of these similarities by CRiteria Importance Through Intercriteria correlation (CRITIC) method, Matcher Weighting method and Simple Sum (SS) method. As results of evaluation of classifiers performance by Precision-Recall (PR) curve and area under the PR curve (AUC-PR), we confirmed that value of AUC-PR in a classifier of TH normalization and SS method is 0.893 and the value is the highest. Therefore, to match different spatial data sets, we thought that it is appropriate to a classifier that distances of matching criteria are normalized by TH method and shape similarity is calculated by SS method.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.14 no.4
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• pp.537-549
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• 2001

The effect of partially restrained(PR) connections and the uncertainties in them on the reliability of steel frames subjected to seismic loading is addressed. A stochastic finite element method(SFEM) is proposed combining the concepts of the response surface method(RSM), the finite element method(FEM), the first-order reliability method (FORM), and the iterative linear interpolation scheme. The behavior of PR connections is captured using moment-relative rotation curves, and is represented by the four-parameter Richard model. For seismic excitation, the loading, unloading, and reloading behavior at PR connections is modeled using moment-relative rotation curves and the Masing rule. The seismic loading is applied in the time domain for realistic representation. The reliability of steel frames in the presence of PR connections is calculated considering all major sources of nonlinearity. The algorithm is clarified with the help of an example.

• Applied Chemistry for Engineering
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• v.20 no.6
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• pp.628-631
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• 2009

Recent social interests on mad cow disease and Creutzfelt-Jacob disease lead researcher' focus onto pathogenic prion proteins causing those diseases. The purpose of this study is to introduce a novel method for micromolecular level quantification of PrP 106-126 peptide, which is a part of prion protein. Fluorescamine has been chosen due to its fluorescence emission characteristics upon reaction with primary amines and Alpha-imager is used to detect the intensity of fluorescence. We succeeded in setting optimal conditions for quantification of PrP 106-206, amyloidogenic prion peptide, at micromolecular level. This study will contribute to identify prion protein aggregation inhibitor and develop new prion protein drug.

• Water for future
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• v.29 no.1
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• pp.203-212
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• 1996

The subject research attempts to develop a new temporal interpolation scheme for the method of characteristics. The proposed three-point time-line Lagrange interpolation Reachback (3PR) method is a temporal quadratic interpolation scheme using the three grid points near the intersection between a characteristic line and a previous time-line. The accuracy of the 3PR method is compared with those of temporal and spatial interpolation schemes such as Reachback, Upwind, and quandratic spatial interpolation methods for two pure advection problems. The results show that on the aspects of the numerical damping and/or oscillation the temporal interpolation schemes are better than the spatial ones under the same interpolation order conditions. In addition, the spatial ones under the same interpolation order conditions. In addition, the proposed 3PR method improves the accuracy of Reachback method as well as it contains the merits of time-line interpolation schemes.

• Journal of the Korean Magnetics Society
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• v.2 no.1
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• pp.37-43
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• 1992

Minor phases in cast and hot-pressed R(R=Pr, Nd)-Fe-B magnet were investigated through thermomagnetic analysis. The relationship between minor phases and coercivities of R-Fe-B magnets was studied. ${\alpha}-Fe$ and $Nd_{2}Fe_{17}$ were precipitated in as-cast Pr-Fe-B and Nd-Fe-B alloys respectively. These phases were considered to deteriorate the magnetic properties of R-Fe-B magnets. During the heat treatment, ${\alpha}-Fe$ and $Nd_{2}Fe_{17}$ were annihilated and the magnetic properties of cast R-Fe-B magnet were improved. Hot-pressed Nd-Fe-B magnet showed better thermal stability than sintered magnet.

• Journal of Bio-Environment Control
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• v.14 no.3
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• pp.182-189
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• 2005

This research was conducted to determine physical properties of four root media, peatmoss + vermiculite (1:1, v/v; PV), peatmoss + composted rice hall (1:1, PR), peatmoss + composted saw-dust (1:1 : PS) and peatmoss + composted pine bark (1:1 PB), as influenced by incorporation rate of Stock-sorb C (STSB). Each root medium containing STSB was packed in 22 cm diameter plastic pot and the physical properties were determined at 5 weeks after packing. As incorporation rate of STSB were elevated, total porosity increased in PV, PS and PB media with statistical differences at $5{\%}$ level. Those also resulted in increase of container capacity in PS and PB media, but statistical differences were not observed in PV and PR media. Elevated incorporation rate of STSB in PV, PS and PB media resulted in increase of air space with statistical differences. Trends in air space of the three root media showed a linear as well as quadratic responses to STSB contents of media. As incorporation rate of STSB increased, more water was retained in four root media at the soil moisture tension of 4.90 kPa, 9.81 kPa, 29.4 kPa and 1.5 MPa. The amount of water retained in PS medium was the highest at the moisture tension at 29.4 kPa and 1.5 MPa followed by PB, PR and PV medium. These results indicated that elevation of incorporation rate of STSB to various root media increased moisture retention capacity, but did not increase the available water holding capacity.

• Polymer(Korea)
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• v.36 no.6
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• pp.693-698
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• 2012

In this study aluminum isopropyl oxide ($Al(O-i-Pr)_3$) was supported on the amine-functionalized surface of silica to synthesize high molecular weight (MW) polylactide (PLA), and it was tested for PLA polymerization behaviors. A silica was funtionalized with silane compound having amine groups, then in-situ treated with $Al(O-i-Pr)_3$. $Al(O-i-Pr)_3$ attached to amine group on silica showed activity only in the presence of MAO (methyl aluminoxane). At the polymerization temperature of $115^{\circ}C$, the conversion and the MW of PLA were increased as the amount of silane was increased. At the polymerization temperature of $130^{\circ}C$, the conversion was decreased while the MW was increased drastically and reached to MW 44000 g/mol when the amine concentration was 3.0 mmol/g. A bimodal type GPC curve was shown at the polymerization temperature of $115^{\circ}C$. As the amount of amine group increased, the peaks of GPC curve were merged. At the polymerization of $130^{\circ}C$, a unimodal GPC curve was shown. $Al(O-i-Pr)_3$ supported on amine-functionalized silica was able to produce higher MW PLA with enhanced activity compared to homogeneous $Al(O-i-Pr)_3$.

• Proceedings of the KSR Conference
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• 2005.11a
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• pp.376-381
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• 2005

This paper presents the rail structure interaction analysis of the elevated viaducts which contains the curved alignments with smallest radius of 300 metre. The aim of this study is to check the compatibility between the track and the curved structure in order to verify the safety of the continuous welded rail track under service conditions. To perform the rail structure interaction analysis, nonlinear static rail structure interaction calculation is implemented. The bridge structures, the rails and the track behaviour are modelled according to the UIC774-3 and the Eurocode prEN1991-2 recommendations. Criteria in Eurocode prEN1991-2 are investigated to check the compatibility between the track and the structure for the rail structure interaction effects.

• Analytical Science and Technology
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• v.18 no.5
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• pp.369-375
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• 2005

The differential pulse anode stripping voltammograms of some rare earth elements and their complexes with catechol have been investigated in various pH and electrolytes. In a 0.1 M LiCl and pH 5.3 solution, $Euv^{3+}$ and $Pr^{3+}$ showed a single oxidation peak at -0.2 V and the oxidation currents were linearly increased with the concentration of those ions. $Tm^{3+}$, $Tb^{3+}$, $Yb^{3+}$ and $Sm^{3+}$ showed two oxidation peaks at -0.5 V and -0.2 V and the oxidation currents at -0.5 V were increased with the concentration increase of those ions. The linear range of those calibration curves was in 1 ppm-10 ppm. In the case of voltammograms of catechol complexes of rare earth elements, $Tb^{3+}$-catechol and $Eu^{3+}$-catechol complex showed a single oxidation peak at -0.95 V and -0.65V, respectively and $Sm^{3+}$-catechol, $Pr^{3+}$-catechol, $Tm^{3+}$-catechol and $Yb^{3+}$-catechol complexes showed two oxidation peaks. The linear range of the calibration curves of those complex was 0.1 ppm~1.0 ppm.