Gwangchiryeong, located adjacent to the Korean DMZ, is a mountain pass connecting Yang-Gu, Gangwon-do with In-je. It reaches a height of 800m (2,624ft) and stands on the flank of Mt. Daeam-san, which has an elevation of 1,304m (4,278ft). It is important to survey the flora of Gwangchiryeong in that not only the area encompassing the waterfall and the valley along with dense old-growth forest has various plant species but also it is a way to make out what kind of plant species exist in the DMZ due to the geographical characteristics of Gwangchiryeong adjacent to the Korean DMZ. Therefore, this study was conducted to elucidate the distribution of vascular plants and their value in Gwangchiryeong. The vascular plants that were collected 9 times from April 2014 to September 2015, and consisted of a total of 513 taxa: 88 families, 297 genera, 441 species, 4 subspecies, 62 varieties and 6 forms. Among those observed species, the rare plant species designated by Korea Forest Service were 22 taxa including Hanabusaya asiatica, Paeonia japonica, Saxifraga octopetala, etc. Endemic species were 22 taxa containing Cirsium setidens, Heloniopsis koreana, Salvia chanryoenica, etc. 18 taxa were recorded as naturalized plants and their naturalized rate and urban index were noted as 3.5% and 5.6%. Among the surveyed 513 taxa, edible, medicinal, pasturing, ornamental, timber, dye, fiber and industrial plants were 197 taxa, 154 taxa, 180 taxa, 49 taxa, 24 taxa, 8 taxa, 4 taxa and 3 taxa, respectively.