• 제목/요약/키워드: Organic Additives

검색결과 381건 처리시간 0.075초

Competitive Adsorption of Dispersant and Binder on Alumina and Its Effect on the Electrokinetic Behavior in Aqueous Media

  • Paik, Un-Gyu
    • The Korean Journal of Ceramics
    • /
    • 제4권4호
    • /
    • pp.292-296
    • /
    • 1998
  • In wet powder processing of alumina, a number of organic molecules such as dispersant and binder are used to produce the flow behavior and properties requisite for shape forming. In this study, interparticle forces of alumina particles suspended in aqueous media were controlled by suspension pH, poly (methacrylic acid) (PMAA, used as dispersant) and poly (vinyl alcohol) (PVA, used as binder). The combined adsorption isotherms of the dispersant and binder additives on alumina were determined by total organic carbon analyzer, while the adsorption of dispersant was differentiated from binder in the mixed additive system by ultraviolet spectroscopy. The electrokinetic behavior of alumina suspensions were then correlated with the adsorption characteristics of dispersant and binder onto alumina particles. It was found that the isoelectric ($pH_{iep}$) of alumina shifted from pH 8.9${\pm}$0.1 to acidic pH as PMAA concentration increased, while PVA adsorption did not affect the $pH_{iep}$ but caused a decrease in the near surface potential.

  • PDF

Effects of Constituents in CNT Pastes on the Field Emission Characteristics of Carbon Nanotubes

  • 김석환;이동구
    • 한국전기전자재료학회논문지
    • /
    • 제24권3호
    • /
    • pp.245-249
    • /
    • 2011
  • Carbon nanotubes (CNTs) have been significantly used for the field emitters for display applications. However, the lifetime of CNT emitters which are formed by screen printing technique is not guaranteed yet, because the constituents in CNT paste affect the lifetime of CNTs. The CNT pastes for screen printing are normally composed of organic vehicles (nitro cellulose, ethyl cellulose, etc) and additives (glass frits, indium tin oxide (ITO), etc) with CNTs. In this study, the effects of constituents in CNT pastes on the lifetime and emission characteristics of CNTs were investigated by thermal and electrical analysis. Use of glass frits worsened the lifetime and electron emission of CNTs. However, an addition of ITO to CNT paste rather improved the lifetime of CNTs. Degradation of CNTs was small when nitro cellulose was used in CNT paste as an organic vehicle.

탄화장치 개발에 의한 쑥(Artemisia asiatica) 탄화 유기용액(쑥초액) 제조에 관한 연구 (Study on the Manufacturing Process of Artemisia asiatica Carbonized Organic Solution(Wormwood Acetic Acid) by Development of Carbonize Equipment)

  • Ryu, Soung-Ryual
    • 통합자연과학논문집
    • /
    • 제4권1호
    • /
    • pp.15-22
    • /
    • 2011
  • In this study, liquid with carbonized artemisia was developed for the first time that can be used as food additives and outside medicinal agents by burning artemisia species such as Artemisia dubia wall, Artemisia capillaris Thunb, Artemisia montana (Nakai) Pamp), Artemisia keiskeana Miq, Leonurus Japonicus Houtt. etc. In addition, edibility of recovered liquid with carbonized artemisia was verified by comparing the contents according to each ingredient with common refined pyroligneous liquid through the analysis of 9 kinds of organic acid by the species of artemisia, methanol and ethanol. Besides, the result of antimicrobial activities on six kinds of food spoilage and food poisoning bacteria observed by paper disc method for liquid with carbonized artemisia indicated that those two liquids showed strong antimicrobial. At the concentration of 1.5 mg/disc, clear zone for S. sonnei and S. aureus, L. monocytogenes was 13~16 mm, and they showed stronger antimicrobial activities than other strain.

유기성 폐기물과 알칼리 안정화제가 첨가된 연안 양식장 퇴적물 조비료의 영양성분 조성 (Nutritive Quality of the Crude Organic Fertilizer Produced with Coastal Aquaculture-Ground Bottom Sediments, Organic Wastes and Alkaline Stabilizers)

  • 김정배;강창근;이근섭;박정임;이필용
    • 한국환경과학회지
    • /
    • 제11권12호
    • /
    • pp.1291-1298
    • /
    • 2002
  • To utilize coastal aquaculture ground bottom sediment in which concentrations of harmful pollutants are low and organic content is high as an organic fertilizer alkaline stabilizers such as CaO, Oyster shell, Mg(OH)$_2$ were added to the bottom sediment organic additives of livestock or food wastes. Nutritive qualities of crude fertilizers were measured to examine effects of alkaline stabilizers and organic waste additions. The Mg(OH)$_2$-added crude fertilizer had significantly lower total carbon(T-C) and nitrogen(T-N) content, reflecting the dilution effect due to great amount of Mg(OH)$_2$ addition. However, the addition of oyster shell had no significant effect on the T-C and T-N content of the fertilizer. $P_2O_5$ and $K_2$O content was considerably higher in the mixed sample of aquaculture ground bottom sediments and livestock wastes than in the mixture of the sediments and food wastes, resulting from higher $P_2O_5$ and $K_2$O content in livestock wastes. Addition of Mg(OH)$_2$ increased the content of MgO In the crude fertilizer but significantly reduced the content of other nutritive elements such as $P_2O_5$, $K_2$O and CaO. Addition of oyster shell as an alkaline stabilizer seemed to have the advantage of saving time and expenses far dryness due to its role as a modulator of water content. Moreover, additions of effect Mg(OH)$_2$ decreased the concentrations of heavy metals in the fertilizer by the dilution while additions of oyster shell had no influence on heavy metal concentrations in the fertilizer.

좀민들레(Taraxacum hallaisanense Nakai) 추출물의 항산화 및 항염증 활성 효과 (Antioxidant and Anti-inflammatory Effects of Taraxacum hallaisanense Nakai Extracts)

  • 난리;추병길
    • 한국유기농업학회지
    • /
    • 제26권3호
    • /
    • pp.501-514
    • /
    • 2018
  • 본 논문은 가축의 면역 증진을 위한 천연 첨가제로서 좀민들레의 활용 가능성을 검토하고자 항산화 및 항염증 활성 평가를 실시하였다. 총 폴리페놀 및 플라보노이드 함량은 94.95, 86.33 mg/g으로 나타났고 DPPH, ABTS radical 소거능은 각각 100, $200{\mu}g/mL$의 농도에서 50%의 억제율을 보였으며, $1000{\mu}g/mL$에서 50%의 환원력을 나타냈다. LPS와 함께 처리한 Raw 264.7 cell에서는 좀민들레에 의한 세포 독성이 나타나지 않았으며 염증 매개 인자 NO와 염증성 사이도카인 $IL-1{\beta}$의 생성량을 유의하게 감소시켰다. 또한 염증성 단백질 발현량을 측정하기 위해 western blotting을 통해 확인한 결과, $400{\mu}g/mL$으로 처리하였을 때 LPS 처리구에 비해 염증성 단백질 발현 수준을 유의하게 감소시킨 것으로 확인되었다. 본 연구 결과, 좀민들레 추출물은 세포에 대한 독성이 없이 유의한 항산화 활성과 항염증 활성을 나타냄으로써 가축의 질병예방을 위한 면역 증진 및 생산성 향상에 기여할 수 있는 안전한 대체 천연 첨가제로 이용될 수 있다고 생각된다.

이가 양이온 금속 친환 및 유기 첨가제를 이용하여 분무열분해법으로 제조된 Y2O3:Eu3+ 적색 형광체의 휘도 개선 (Photoluminescence Enhancement of Y2O3:Eu3+ Red Phosphor Prepared by Spray Pyrolysis using Aliovalent Cation Substitution and Organic Additives)

  • 민병호;정경열
    • 한국분말재료학회지
    • /
    • 제27권2호
    • /
    • pp.146-153
    • /
    • 2020
  • The co-doping effect of aliovalent metal ions such as Mg2+, Ca2+, Sr2+, Ba2+, and Zn2+ on the photoluminescence of the Y2O3:Eu3+ red phosphor, prepared by spray pyrolysis, is analyzed. Mg2+ metal doping is found to be helpful for enhancing the luminescence of Y2O3:Eu3+. When comparing the luminescence intensity at the optimum doping level of each Mg2+ ion, the emission enhancement shows the order of Zn2+ ≈ Ba2+ > Ca2+ > Sr3+ > Mg2+. The highest emission occurs when doping approximately 1.3% Zn2+, which is approximately 127% of the luminescence intensity of pure Y2O3:Eu3+. The highest emission was about 127% of the luminescence intensity of pure Y2O3:Eu3+ when doping about 1.3% Zn2+. It is determined that the reason (Y, M)2O3:Eu3+ has improved luminescence compared to that of Y2O3:Eu3+ is because the crystallinity of the matrix is improved and the non-luminous defects are reduced, even though local lattice strain is formed by the doping of aliovalent metal. Further improvement of the luminescence is achieved while reducing the particle size by using Li2CO3 as a flux with organic additives.

PDP 투명유전체 형성용 Green Sheet 제조 (Fabrication of Transparent Dielectric Green Sheet for Plasma Display Panel)

  • Heo, Sung-Cheol;Park, Duck-Kyun;Oh, Young-Jei
    • 한국세라믹학회지
    • /
    • 제41권4호
    • /
    • pp.277-283
    • /
    • 2004
  • Plasma Display Panel(PDP) 상판용 투명유전체의 green sheet를 제조코자 투명유전체 슬러리의 분산특성 및 유기물의 함량과 조성비에 따른 밀도와 기계적 특성을 연구하였다. 비수계 시스템에서 슬러리의 완전분산을 위한 분산제의 종류와 분산제의 양을 결정하기 위해 침강실험, 점도측정을 행하여 최적의 분산조건을 구하였다. 조성물 변수로서 투명유전체조성 분말/(투명유전체조성 분말+유기물)의 비와 결합제/(결합제+가소제)의 비를 각각 변화시켜 green sheet를 제조하였다. 제조된 tape casting 슬러리의 대부분은 의가소성(pseudoplastic) 거동을 보이는데, 의가소성 거동은 shear thinning의 효과를 가지는 것으로 기술 할 수 있다. 각각의 조성을 가지는 슬러리는 모두 전단속도가 증가함에 겉보기 점도가 감소하는 shear thinning 효과를 보여 주었다. Green sheet의 특성을 조사한 결과 유기물의 함량 및 조성이 green sheet의 밀도와 기계적 특성을 결정하는 중요한 인자가 되었다.

음식물 쓰레기의 호기성분해를 위한 고온균의 분리 및 생육 특성 (Isolation and Characterization of Thermophilic Bacteria for Aerobic Decomposition of Food Waste)

  • 최민호;조성은;유정목;정윤진;박연희
    • 유기물자원화
    • /
    • 제3권1호
    • /
    • pp.21-34
    • /
    • 1995
  • 음식물 쓰레기 퇴비화 장치에 사용하기 위한 미생물제제 개발을 목적으로 토양, 퇴비 등으로부터 고온균을 분리하여 그 생육 특성을 조사하였다. 분리한 81주 중에서 음식물 쓰레기를 분해시키는 전분 분해효소, 단백 분해효소, 지방 분해효소 및 섬유소 분해효소의 활성이 높은 20주를 분리하여 형태 및 생리적 특성을 조사한 결과 모두 그람 양성의 간균으로 카탈라제를 가지고 있었으며 17주는 포자 형성균으로 밝혀졌다. 이 균주들은 대부분 pH 5에서 pH 10까지 생육할 수 있었으며 8% NaCl이 함유된 배지에서도 성장하였다. 또한 각 효소의 생산 균주 그룹별로 생육에 미치는 영향을 조사한 결과 통기에 의해 생육이 크게 증가하였으며, $50^{\circ}C$ 이상 온도가 올라갈수록 생육이 저하되었다.

  • PDF

재활용 석고 부산물을 이용한 준불연 유무기 융합 단열재 개발 연구 (Development of Organic-Inorganic Hybrid Insulating Materials with Semi-Non-Combustible Using by Recycling Gypsum)

  • 하주연;신현규;송태협
    • 한국건설순환자원학회논문집
    • /
    • 제7권4호
    • /
    • pp.431-437
    • /
    • 2019
  • 본 연구는 유기계 기재에 무기계 바인더 소재를 함침시킴으로써 유기계 수준의 경제성을 가지며 우수한 단열성능 및 화재 안전성을 보유한 유무기 융합형 단열재 개발을 목적으로 한다. 유기계 기재는 폴리우레탄 소재의 상용 스펀지를 사용하였고, 함침용 무기 바인더 용액은 재활용 석고 부산물에 물과 첨가제를 혼합하여 제조하였다. 개발 소재의 성능평가 결과 열전도율 0.051W/mK 이하의 우수한 단열성능 뿐만 아니라 국토교통부 고시 제 2015-744호 기준에 명시된 준불연 재료임을 확인할 수 있었다. 또한 본 개발 소재는 제조 공정 과정에서 밀도 제어에 따른 열전도율 및 난연성 조절이 가능하여 다양한 용도의 단열재에 적용 가능할 것으로 판단된다.

Efficiency Improvement of Organic Solar Cells Using Two-step Annealing Technique

  • Masood, Bilal;Haider, Arsalan;Nawaz, Tehsin
    • Transactions on Electrical and Electronic Materials
    • /
    • 제17권3호
    • /
    • pp.134-138
    • /
    • 2016
  • The fullerene solar cells are becoming a feasible choice due to the advanced developments in donor materials and improved fabrication techniques of devices. Recently, sufficient optimization and improvements in the processing techniques like incorporation of solvent vapor annealing (SVA) with additives in solvents has become a major cause of prominent improvements in the performance of organic solar cell-based devices . On the other hand, the challenge of reduced open circuit voltage (Voc) remains. This study presents an approach for significant performance improvement of overall device based on organic small molecular solar cells (SMSCs) by following a two step technique that comprises thermal annealing (TA) and SVA (abbreviated as SVA+TA). In case of exclusive use of SVA, reduction in Voc can be eliminated in an effective way. The characteristics of charge carriers can be determined by the measurement of transient photo-voltage (TPV) and transient photo-current (TPC) that determines the scope for improvement in the performance of device by two step annealing. The recovery of reduced Voc is linked with the necessary change in the dynamics of charge that lead to increased overall performance of device. Moreover, SVA and TA complement each other; therefore, two step annealing technique is an appropriate way to simultaneously improve the parameters such as Voc, fill factor (FF), short circuit current density (Jsc) and PCE of small molecular solar cells.