• Title/Summary/Keyword: Opaque material

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A COMPARATIVE STUDY OF THE PHYSICOCHEMICAL PROPER TIES AND BOND STRENGTH TO METAL BETWEEN THE REGULAR OPAQUE POWDER AND CORE POWDER (도재소부전장금관용 Opaque 분말과 도재전장관용 core 분말의 물리화학적 성질 및 금속과의 결합력에 대한 비교연구)

  • Lim, Jang-Seop;Chung, Chang-Mo;Jeon, Young-Chan
    • The Journal of Korean Academy of Prosthodontics
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    • v.35 no.1
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    • pp.144-164
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    • 1997
  • The purpose of this study were to investigate the chemical composition, mean particle size, linear thermal expansion coefficient and metal-bonding strength of the regular opaque powder and core powder. In this study, 4 types of ceramic powders, namely Duceram Jacket Opaque powder, Duceram Opaque powder, Vita Hi-Ceram powder, Vita VMK Paint On-88 powder were used. Chemical composition was evaluated by EDS(Energy Dispersive X-ray Spectrophotometer, Oxford QX-2000, England), particle size was measured by MALVERN Instruments(MALVERN Instruments SB. OC., U.S.A.. ad linear thermal expansion coefficient was measured by dilatometer(Motoyama, Japan). Bond strength was measured by the Universal tsting machine(Istron Co., Ltd., U.S.A.). The Results were as follows : 1. Through recognition of the relative difference in chemical composition between the core powder and the regular opaque powder, the difference in the proportion of $Al_2O_3$ in each type of material is demonstrated ; Duceram Jaket Opaque powder : 30.16%, Duceram Opaque powder : 16.60%, Vita Hi-Ceram : 63.64%, Vita VMK Paint-On 88 : 16.16%. 2. There was no significant difference in the proportion of metal-bonding materials between the core powder and the regular opaque powder. 3. In the regular opaque powder, alkaline materials were incoporated in order to increase the coefficient of thermal expansion. 4. In the particle size analysis, there was no significant difference in mean particle size or in the particle size distribution between the core powder and the regular opaque powder. 5. In the thermal expansion test for temperature range of $25-600^{\circ}C$, the regular opaque powder had higher coefficient of thermal expansion than that of core powder. 6. In the 4 point flexural bending test, there was no statistically significant difference in the mean bond strength between the core powder and the opaque powder among the Duceram products.

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Thickness and translucency of opaque shade composite resin for masking effect (배경 색조 차단 목적의 불투명 복합 레진의 두께와 반투명도)

  • Baek, Kyung-Won;Kim, Sung-Joon
    • The Journal of the Korean dental association
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    • v.49 no.4
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    • pp.203-210
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    • 2011
  • The aims of this study were to evaluate the adequate thickness of opaque resins for situations such as an oral black cavity and discolored tooth structure, as well as the translucency of each opaque material at various thicknesses. Six opaque-shade composite resins (Z-350 OA3, Amelogen Universal A2O, Esthet-X A2O, Esthet-X A4O, Charmfil UO and Aelite Universal OA3) were prepared in metal molds with a hole of 8 mm in diameter and various thicknesses (0.5mm, 1.0mm, 1.5mm, 2.0mm, 2.5mm, 3.0 mm and 4.0mm). Four backgrounds (white tile, black tile, C4 shade porcelain and opaque resin itself) were used to determine the translucency parameter (between black and white backgrounds). and to mimic a black oral cavity (between black and opaque resin backgrounds) and a discolored tooth structure (between C4 and opaque resin backgrounds). Color measurements were made by a colorimeter to determine the CIELAB values of each specimen with each background and to calculate the translucency parameter and ${\Delta}E^*$ value difference among the specimens on the backgrounds. The translucency parameter and ${\Delta}E^*$ obtained between black and opaque resin backgrounds decreased in similar pattern as thickness increased. A C4 background was masked by resin thicknesses of 0.5-1.0mm, while a black background required thicknesses of 1.0-2.0mm. Adequate knowledge about differences in the optical character like translucency of the materials used is essential, together with the accumulated experience of the individual clinician.

SPECTROPHOTOMETRIC ANALYSIS OF THE INFLUENCE OF METAL SUBSTRATE ON THE COLOR OF CERAMIC (금속하부구조물이 도재의 색조에 미치는 영향에 대한 분광측색분석)

  • Lee Su-Ok;Woo Yi-Hyung;Choi Dae-Gyun;Kwon Keung-Rok
    • The Journal of Korean Academy of Prosthodontics
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    • v.41 no.2
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    • pp.148-159
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    • 2003
  • Statement of problem Metal-ceramic restorations have been used extensively by dental clinicians for nearly 40 years. Strength an functional ability of metal-ceramic restorations are proved to be satisfying, However esthetics and biocompatibility of metal alloy which is used in metal-ceramic restoration is not ideal. Using pure gold as an alternative, have advantage of esthetics, biocompatibility over conventional metal alloy. But there had been little article which studied on the color effect of pure gold on fual porcelain color. Purpose The purpose of this study was to spectrophotometrically evaluate the difference between color of metal alloy(Au-Pt, Ni-Cr) and pure gold, during color masking procedure with opaque porcelain and to analyze the differences, Material and Methods Three types of metal - base metal(Ni-Cr), high gold alloy(Au-Pt), pure gold(GES) - specimen were fabricated 1cm in diameter. Four steps were established - after finishing, after pre-coditioning, after application of first opaque porcelain(0.08mm in thickness), after application of second opaque porcelain(0.15mm in thickness)- and tested color with spectrophotometer every each steps and analyzed with $CIEL^*a^*b^*$ color order system. One-Way ANOVA test was used to and out if there were significant differences between groups tested and Shaffe multiple comparison was used to identify where the differences were. Results 1. After finishing and pre-conditioning, pure gold(GES) group showed most high values in $L^*,a^*,b^*$. 2. After application of first opaque porcelain(0.08mm in thickness), after application of second opaque porcelain(0.15mm in thickness), pure gold(GES) group showed the least difference in $L^*,a^*,b^*$ values and the lowest ${\Delta}E$ value(${\Delta}E$=0.63). 3. After application of first opaque porcelain and after application of second opaque porcelain differences that were significant (P<0.05) between groups were found only in $a^*$ values. 4. Base metal alloy group showed the lowest $a^*$ value in test after application of first opaque porcelain and the highest value in test after application of first opaque porcelain Conclusion Pure gold group and high gold group showed higher $a^*$ values than base metal group when tested after 0.08mm thickness of opaque porcelain was applied and pure gold group showed much similar $L^*,a^*,b^*$ values between 0.08mm thickness and 0.15mm thickness of opaque porcelain. This meant that pure gold was more easily masked by opaque porcelain than the other two groups.

OPACITY AND MASHING EFFECT OF THE OPAQUE SHADE COMPOSITE RESINS (Opaque shade 복합레진의 opacity와 배경 색상 차단 능력의 평가)

  • Park, Su-Jung;Hwang, Yun-Chan;Oh, Won-Mann;Hwang, In-Nam
    • Restorative Dentistry and Endodontics
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    • v.32 no.4
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    • pp.356-364
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    • 2007
  • The purpose of this study was to assess the background color-interceptive ability ana opacity of opaque shade composites (Universal composite, Filtek Z350, Charisma, Clearfil ST, Palpaque Estelite, Esthet-X, and Metafil Flo). Twenty four background specimens (diameter 5.5 mm, thickness 3.0 mm) with Root dentin Mustard (Bisco, Schaumburg, IL, USA) were made. The CIE $L^*a^*b^*$ value of background specimens was measured by a spectrophotometer (Spectrolino, GretagMacbeth, Regensdorf, Switzerland). Three specimens in every group were filled on the background specimens. The surface color of samples was measured by a spectrophotometer in 3.0 mm and every thickness to 0.5 mm while grinding. The color difference in the background color along with 3.0 mm specimen gauged the masking effect in each thickness while grinding and polishing. The opacity was calculated in 1 mm thick specimens. The opacity was in the decreasing order of Clearfil ST, Metafil Flo, Filtek Z350, Palpaque Estelite, Universal composite, Charisma, and Esthet-X (p < 0.05). As the thickness get reduced, $L^*$ value showed decreasing, $a^*$ increasing tendency. The surface color difference between pair of the 3.0 mm thick specimen and after grinding in same opaque resin was above 3.3 except Clearfil ST and Metafil Flo. The color difference (${\Delta}E^*$) between pair of background specimen and opaque resin built-up specimen showed more than 10.0 regardless kinds and thickness. The variance in opacity characteristics and color of the opaque composites is dependent upon manufacturer. When using the opaque resin, the optical properties of each material must be considered as well as cavity.

Effects of Package Materials on Quality Change of Pine Bud Beverage Under Ultraviolet Light

  • An, Duek-Jun
    • Preventive Nutrition and Food Science
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    • v.14 no.4
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    • pp.349-353
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    • 2009
  • The effects of packaging materials on preserving the functional component of pine bud beverage stored under UV (ultraviolet) light exposure conditions were studied. The order of UV light blocking properties of the selected packages was: opaque can> opaque PET (polyethylene terepthalate) with green lamination=transparent PET with 10% PEN (polyethylene naphthalate) blending> transparent PET, and did not depend on film thickness in specified range. At 20${^{\circ}C}$, the order of preserving degree of original color and endobornyl acetate, which is quality index of pine bud beverage, was the same as above. Exposure to UV light can cause of deterioration of functional food components, but green color lamination and blending of PEN materials with transparent PET help to preserve the UV sensitive pine bud beverage components. However, the treated PET bottles have poorer preservation capabilities than the opaque cans. Transparent PET with PEN blending, in particular, will be very useful packaging material for colorful functional beverage preservation by helping to protect the ingredients while attracting consumer attention.

The Influence of Surface Treatment and Opaque Application Methods on the Bond Strength of PFM Restorations (모래분사법과 불투명 도재의 도포방법이 도재용착주조관의 전단결합강도에 미치는 영향)

  • Kim, Sung-Min;Choi, Sung-Min;Chung, In-Sung
    • Journal of Technologic Dentistry
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    • v.33 no.4
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    • pp.339-347
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    • 2011
  • Purpose: This study was investigated the bonding strength of two kinds of Ni-Cr alloy with respect to the condition of surface treatment. Methods: The surface treatment was performed on the two kinds of Ni-Cr alloy (B alloy and R alloy) specimens, which were sandblasted with $50{\mu}m$, $110{\mu}m$, and $250{\mu}m$ aluminium oxide and were treated with opaque application (paste and wash opaque). The roughness on the surfaces of the specimens was observed. The metal-ceramic interfaces were analyzed with EPMA in order to ionic diffusion, and the shear test was performed. Results: The BA250 specimen, which has higher surface roughness, showed the highest bonding strength in B specimens. In R specimens, the bonding strength of RA110 specimen was the highest. Conclusion: B specimen formed a mechanical bond between metal-ceramic interfaces; however, in the case of R specimen, a chemical bond was formed between that interfaces. There was no significant statistical difference between the bonding strengths of two types of specimens (p>0.05).

γ-Ray Shielding Behaviors of Some Nuclear Engineering Materials

  • Mann, Kulwinder Singh
    • Nuclear Engineering and Technology
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    • v.49 no.4
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    • pp.792-800
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    • 2017
  • The essential requirement of a material to be used for engineering purposes at nuclear establishments is its ability to attenuate the most penetrating ionizing radiations, gamma $({\gamma})-rays$. Mostly, high-Z materials such as heavy concrete, lead, mercury, and their mixtures or alloys have been used in the construction of nuclear establishments and thus termed as nuclear engineering materials (NEM). The NEM are classified into two categories, namely opaque and transparent, depending on their behavior towards the visible spectrum of EM waves. The majority of NEM are opaque. By contrast, various types of glass, which are transparent to visible light, are necessary at certain places in the nuclear establishments. In the present study, ${\gamma}-ray$ shielding behaviors (GSB) of six glass samples (transparent NEM) were evaluated and compared with some opaque NEM in a wide range of energy (15 keV-15 MeV) and optical thickness (OT). The study was performed by computing various ${\gamma}-ray$ shielding parameters (GSP) such as the mass attenuation coefficient, equivalent atomic number, and buildup factor. A self-designed and validated computer-program, the buildup factor-tool, was used for various computations. It has been established that some glass samples show good GSB, thus can safely be used in the construction of nuclear establishments in conjunction with the opaque NEM as well.

Wax Appearance Temperature Measurement of Opaque Oil for Flow Assurance in Subsea Petroleum Production System (해저 석유 생산시스템 내 유동안정성 확보를 위한 불투명 오일의 왁스생성온도 측정법)

  • Lim, Jong-Se;Back, Seung-Young;Kang, Pan-Sang;Yul, Seung-Ryul;Kim, Hyo-Sang;Park, Ji-Hong
    • Journal of Advanced Marine Engineering and Technology
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    • v.36 no.1
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    • pp.185-194
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    • 2012
  • Deepwater oil is becoming more attractive because most onshore and shallow water oil is developing or developed. With the on-going trend to deepwater oil developments, flow assurance problems which prevent oil flow from reservoir to processing facilities are becoming an issue because deposited material can be occurred in case oil is exposed to very different environment from reservoir. Wax deposition which is one of flow assurance problems can be a major technical and economic issue because it is very sensitive to temperature. In order to predict and mitigate wax problems, the precise measurement of wax appearance temperature (WAT) which is the starting temperature of wax precipitation is very important. Various methods have been suggested for WAT measurement of opaque oil because there is no standard method for opaque oil. In this study, the WAT of opaque oil samples was measured using viscosity measurement method, differential scanning calorimetry, filter plugging method, and pressurized filter plugging method. Wax deposition test and high temperature gas chromatography analysis were applied to verify measured WAT. As a result of study, the WAT of opaque oils was successfully measured and verified. If WAT measurement methods of opaque oil related to oil characteristics is systematized using the results of this study, it can be a valuable tool for WAT measurement of opaque oil and flow assurance related to wax deposition.

A Study on the Psychological effects of glass in Modern Interior Architecture -focused on Mies van der Rohes House Projects- (현대 실내 건축에 있어서 유리가 미친 심리적 영향에 관한 연구 -Mies van der Rohe의 주택을 중심으로-)

  • 문정묵
    • Korean Institute of Interior Design Journal
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    • no.25
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    • pp.103-110
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    • 2000
  • The material world around human is normally composed of opaque one, with which human has made the spaces. The opaque material to make space has played a role to control the relationship among people and has produced socio-cultural things since the history started. The opening of opaque material(wall) connects one space with the other. Therefore, the meaning of opening is a connection among people who are in different spaces in terms of sociology. In conjunction with this, socio-cultural situation has been deployed differently. In the traditional european domestic space, the glass has been applied to this opening since they found the glass. It disconnects two spaces physically but connects them visually. Therefore, without blocking the opening visually, the glass became to protect people with their interior space from outside environment. The important thing is that the application of the glass in a building had been restricted because of opening size. However, after Industrial Revolution with the advanced technology of architecture, the glass came to be applied to the building and it became widen. So, the concept of glass window became to be the one of glass wall. This change made a transformation of visual character between two spaces which are separated with glass wall. This means that the glass wall gave two directional visibility while the glass window gave one directional visibility from inside to outside of space. This is because the amount of the natural light to the interior space increased due to widen glass in a space. This gave a change of visual authority and the space of surveillance(interior space) became to the one of communication. The space of surveillance, Michel Foucault mentioned in his book surveillance and punishment, is a very private one that is not visually permeable from the people outside, while the space of communication is a public one which needs other eyes. In the space of publicity, there needs a rationality, morality and ethics because of public surveillance and in the space of privacy, there restores a desire for sex and assaults.

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Optical characteristics of resin composite before and after polymerization (광중합 전후 복합레진의 광학적 특성)

  • Eom, Ah-Hyang;Kim, Duck-Su;Lee, Soo-Hee;Byun, Chang-Won;Park, Noh-Hoon;Choi, Kyoung-Kyu
    • Restorative Dentistry and Endodontics
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    • v.36 no.3
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    • pp.219-230
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    • 2011
  • Objectives: The aim of this study was to evaluate the optical characteristics such as color and translucency changes before and after light curing, to quantify the CQ and to measure refractive indices of body and opaque shade of resin composites materials. Materials and Methods: Resin composites used in this study were A2 body and A2 opaque shade of Esthet-X, Filtek supreme, Gradia Direct, Clearfil Majesty and Beautifil II. Color and translucency changes before and after light curing were evaluated by colorimeter, the CQ was quantified by GC-MS and refractive index changes were measured by spectroscopic ellipsometer. Results: Translucency parameter (TP) was significantly increased after curing. The CQ content of body shades are higher than that of opaque shades in all resin composites. Refractive index increased after polymerization in all materials and significant difference in ${\Delta}$refractive index was found between body and opaque shade (significance level 0.05). Conclusions: For an accurate shade match, direct shade matching of resin composite should be performed by using the cured material.