• 제목/요약/키워드: Novel metal

검색결과 638건 처리시간 0.025초

A Novel Metal Supported SOFC Fabrication Method Developed in KAIST: a Sinter-Joining Method

  • Bae, Joongmyeon
    • 한국세라믹학회지
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    • 제53권5호
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    • pp.478-482
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    • 2016
  • Metal-supported SOFCs have been investigated to overcome the disadvantages of ceramic-supported SOFCs, including issues related to mechanical strength and sealing. In the case of ceramic-supported cells, the mechanical support is a brittle ceramic or cermet, and it contains expensive materials. However, metal-supported cells utilize ceramic layers that are only as thick as necessary for electrochemical functioning, thereby compensating for the disadvantages of ceramic-supported cells. The mechanical support is fabricated from inexpensive and robust metals, and the electrochemically active layers are applied directly to the metal support. The metal-supported SOFCs thus can provide a reduced system cost, ease of manufacturing, and operational advantages. Owing to these features, metal-supported SOFCs are a very promising candidate for commercialization. Given the importance of studying worldwide trends in metal-supported SOFC research for performance evaluation, this paper reviews development trends with a focus on fabrication methods. Furthermore, a novel fabrication method developed in KAIST is discussed.

공기정화기용 광촉매 필터의 성능-귀금속 담지 영향 (The Performance of Photocatalyst filter for an Air Cleaner-Effect of novel metal)

  • 장현태;김정근;차왕석
    • 한국산학기술학회논문지
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    • 제7권6호
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    • pp.1284-1291
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    • 2006
  • 기상 휘발성 유기화합물인 아세톤과 포름알데히드에 대한 분해반응을 $TiO_2$ 광촉매에 귀금속을 혼합 담지하여 분해능을 연구하였다. 아세톤의 경우 $TiO_2$에 팔라디움 혼합담지에 의하여 분해 반응성이 개선되었으며, 일반적인 광촉매 반응에 있어서 수분의 첨가시 OH기의 형성에 따른 분해반응성의 증가를 실험한 결과 아세톤의 경우 수분의 흡착에 의하여 분해반응성이 감소하는 것으로 나타났다. 아세톤의 경우 $45^{\circ}C$가 최적으로 나타났으며, 포름알데히드의 경우는 $75^{\circ}C$가 최적으로 나타났다. 귀금속 담지에 의한 영향에서는 아세톤의 경우 Pd를 $TiO_2$의 중량비 1wt%를 첨가한 경우 반응성의 향상을 보았으며, 포름알데히드의 경우 Pt가 반응성의 향상을 나타내었다.

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Novel-1,3-Alternate Calix[4]thiacrown Ethers

  • Sim, Won-Bo;Lee, Jai-Young;Kwon, Jong-Chul;Kim, Moon-Jib;Kim, Jong-Seung
    • Bulletin of the Korean Chemical Society
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    • 제23권6호
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    • pp.879-884
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    • 2002
  • A series of novel 1,3-alternate calix[4]-mono-thiacrown and -bis-thiacrowns were synhesized within good yields. The three dimensional 1,3-alternate conformation was confimed by X-ray crystal structure. From the results of two phase extraction and NMR studies on the ligand-metal complex, one can conclude that the calix[4]thiacrown ethers showed the very high selectivity for silver ion over other metal ions by an electrostatic interaction between sulfur atom and silver ion and by a $\pi-metal$ complexation.

Enhanced Electrical Performance of SiZnSnO Thin Film Transistor with Thin Metal Layer

  • Lee, Sang Yeol
    • Transactions on Electrical and Electronic Materials
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    • 제18권3호
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    • pp.141-143
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    • 2017
  • Novel structured thin film transistors (TFTs) of amorphous silicon zinc tin oxide (a-SZTO) were designed and fabricated with a thin metal layer between the source and drain electrodes. A SZTO channel was annealed at $500^{\circ}C$. A Ti/Au electrode was used on the SZTO channel. Metals are deposited between the source and drain in this novel structured TFTs. The mobility of the was improved from $14.77cm^2/Vs$ to $35.59cm^2/Vs$ simply by adopting the novel structure without changing any other processing parameters, such as annealing condition, sputtering power or processing pressure. In addition, stability was improved under the positive bias thermal stress and negative bias thermal stress applied to the novel structured TFTs. Finally, this novel structured TFT was observed to be less affected by back-channel effect.

Conducting Metal Oxide Interdigitated Electrodes for Semiconducting Metal Oxide Gas Sensors

  • Shim, Young-Seok;Moon, Hi-Gyu;Kim, Do-Hong;Jang, Ho-Won;Yoon, Young-Soo;Yoon, Soek-Jin
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.65-65
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    • 2011
  • We report the application of conducting metal oxide electrodes for semiconducting metal oxide gas sensors. Pt interdigitated electrodes have been commonly used for metal oxide gas sensor because of the low resistivity, excellent thermal and chemical stability of Pt. However, the high cost of Pt is an obstacle for the wide use of metal oxide gas sensors compared with its counterpart electrochemical gas sensors. Meanwhile, relatively low-cost conducting metal oxides are widely being used for light-emitting diodes, flat panel displays, solar cell and etc. In this work, we have fabricated $WO_3$ and $SnO_2$ thin film gas sensors using interdigitated electrodes of conducting metal oxides. Thin film gas sensors based on conducting metal oxides exhibited superior gas sensing properties than those using Pt interdigitated electrodes. The result was attributed to the low contact resistance between the conducting metal oxide and the sensing material. Consequently, we demonstrated the feasibility of conducting metal oxide interdigitated electrodes for novel gas sensors.

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자동차 헤드라이트용 고압방전등 안정기 시스템의 새로운 점등방식 (Novel Ignition Method for Automotive HID lamp Ballast System)

  • 김윤호;엄태욱;이재학
    • 대한전기학회논문지:전기기기및에너지변환시스템부문B
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    • 제55권4호
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    • pp.238-243
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    • 2006
  • This paper presents novel ignition method for automotive 35W metal halide discharge lamp electronic ballast. At this study, the novel method of ignition is developed to reduce costs and size of the ballast. By use of the novel method, the voltage needed in ignition is decreased, which result in use of the lower voltage rating power devices compared with conventional method and product compactness was achieved by deleting a circuit generating negative voltage needed in ignition at an conventional circuit. In terms of luminosity, color rendering, light efficiency(lm/W) and lifespan, the metal halide lamp is superior to, but unlike halogen lamp, it have more complicated transient characteristics to reach its steady state than the conventional halogen lamp. Therefore, in this paper, the electronic ballast was designed such that the metal halide lamp could be optimized for the automotive, by applying a method of microcontroller-based digital control. The results of the proposed system is verified through various experiment results.

A SDR/DDR 4Gb DRAM with $0.11\mu\textrm{m}$ DRAM Technology

  • Kim, Ki-Nam
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제1권1호
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    • pp.20-30
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    • 2001
  • A 1.8V $650{\;}\textrm{mm}^2$ 4Gb DRAM having $0.10{\;}\mu\textrm{m}^2$ cell size has been successfully developed using 0.11 $\mu\textrm{m}$DRAM technology. Considering manufactur-ability, we have focused on developing patterning technology using KrF lithography that makes $0.11{\;}\mu\textrm{m}$ DRAM technology possible. Furthermore, we developed novel DRAM technologies, which will have strong influence on the future DRAM integration. These are novel oxide gap-filling, W-bit line with stud contact for borderless metal contact, line-type storage node self-aligned contact (SAC), mechanically stable metal-insulator-silicon (MIS) capacitor and CVD Al process for metal inter-connections. In addition, 80 nm array transistor and sub-80 nm memory cell contact are also developed for high functional yield as well as chip performance. Many issues which large sized chip often faces are solved by novel design approaches such as skew minimizing technique, gain control pre-sensing scheme and bit line calibration scheme.

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해양 IT 소자에의 응용을 위한 RFIC/MMIC용 초소형 저임피던스 윌킨슨 전력분배기 설계 (Highly Miniaturized and Low impedance Wilkinson Power Divider on RFIC/MMIC for application to IT components of Ocean Engineering)

  • 김충열;윤영
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2005년도 전기학술대회논문집
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    • pp.412-416
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    • 2005
  • In this paper we propose low-impedance and miniaturized a wilkinson power divider on MMIC passive component which was fabricated by a novel microstrip line structure employing periodically perforated ground metal (PPGM). The novel microstrip line structure showed much lower impedance and shorter guided-wavelength than conventional one. Using the novel microstrip line with periodically perforated ground metal, a miniaturized 17 ${\Omega}$ power divider was fabricated. The line width of the power divider was 20 ${\mu}m$, and the size of it was 0.110 $mm^2$, which is 21 % of conventional one. The power divider exhibited good RF performances from 10 to 20 GHz.

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Electrochemical Properties of Novel Metal Powder Electrodes for Polymer Electrolyte Membrane Electrolysis

  • Kim, Chang-Hee;Kang, Kyung-Soo;Park, Chu-Sik;Hwang, Gab-Jin;Bae, Ki-Kwang
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.1227-1228
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    • 2006
  • The electrochemical properties of novel metal powders were investigated for the electrode materias of polymer electrolyte memebrane electrolysis. Two types of Pt black and $IrO_2$ powder electrodes were hot-pressed on the polymer electrolyte membrane to form membrane electrode assembly. The galvanodynamic polarization methode was used to characterize the electrochemical properties of both electrodes. From the experimental results, we concluded that the $IrO_2$ powder electrode exhibits better electrochemical performance than Pt black as cathode material for the electrolysis.

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Novel solvothermal approach to hydrophilic nanoparticles of late transition elements and its evaluation by nanoparticle tracking analysis

  • Dutilleul, Marion Collart;Seisenbaeva, Gulaim A.;Kessler, Vadim G.
    • Advances in nano research
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    • 제2권2호
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    • pp.77-88
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    • 2014
  • Solvothermal treatment of late transition metal acetylacetonates in a novel medium composed either of pure acetophenone or acetophenone mixtures with amino alcohols offers a general approach to uniform hydrophilic metal nanoparticles with high crystallinity and low degree of aggregation. Both pure metal and mixed-metal particles can be accesses by this approach. The produced materials have been characterized by SEM-EDS, TEM, FTIR in the solid state and by Nanoparticle Tracking Analysis in solutions. The chemical mechanisms of the reactions producing nanoparticles has been followed by NMR. Carrying out the process in pure acetophenone produces palladium metal, copper metal with minor impurity of $Cu_2O$, and NiO. The synthesis starting from the mixtures of Pd and Ni acetylacetonates with up to 20 mol% of Pd, renders in minor yield the palladium-based metal alloy along with nickel oxide as the major phase. Even the synthesis starting from a mixed solution of $Cu(acac)_2$ and $Ni(acac)_2$ produces oxides as major products. The situation is improved when aminoalcohols such as 2-aminoethanol or 2-dimethylamino propanol are added to the synthesis medium. The particles in this case contain metallic elements and pairs of individual metals (not metal alloys) when produced from mixed precursor solutions in this case.