• Journal of Korean Society of Environmental Engineers
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• v.35 no.7
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• pp.464-471
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• 2013

In this study, the resource efficiency and future metal resource requirement in photovoltaic (PV) production system were evaluated by using material balance data and life cycle assesment (LCA) method. As a result, in the resource efficiency of ferrous and non-ferrous metal, lead and tin had higher resource efficiency than other materials in all PV systems (SC-Si, MC-Si, CI(G)S, CdTe). In the resource efficiency of rare metals, gallium and rhenium in silicon system and rhenium and rhodium in thin-film system ranked as the first and second high resource efficiency. In case of rare earth metal, gadolinium and samarium took higher resource efficiency. The results of the future metal resource requirement in PV systems showed that 2,545,670 ton of aluminium, 92,069 ton of zinc, 22,044 ton of copper, 1,695 ton of tin and 31 ton of nickel will be needed by 2030 in South Korea, except resource recycling supplement.

• Journal of the Society of Naval Architects of Korea
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• v.51 no.6
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• pp.548-555
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• 2014

As a considerable, experimental approach, an Auto-carriage type of $CO_2$ welding machine and a MIG(Metal Inert Gas) welding robot under inert gas atmosphere were utilized in order to realize Al 5083 welding applied to hull and relevant components of green Al leisure ships. This study aims at investigating the effect of welding conditions(current, voltage, welding speed, etc) on thermal deformation that occurs as welding operation and tensile characteristics after welding, by using Al 5083, non-ferrous material, applied to manufacturing of co-environmental Al leisure ships. With respect to welding condition to minimize the thermal deformation, 150A and 16V at the wire-feed rate of 6mm/sec were acquired in the process of welding Al 5083 through an auto carriage type of $CO_2$ welding feeder. As to tensile characteristics of Al 5083 welding through a MIG welding robot, most of tensile specimens showed the fracture behavior on HAZ(Heat Affected Zone) located at the area joined with weld metal, except for some cases. Especially, for the case of the Al specimen with 5mm thickness, 284.62MPa of tensile strength and 11.41% of elongation were obtained as an actual allowable tensile stress-strain value. Mostly, after acquiring the optimum welding condition, the relevant welding data and technical requirements might be provided for actual welding operation site and welding procedure specification(WPS).

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.10
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• pp.1190-1199
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• 2014

As a considerable, experimental approach, an autocarriage type of $CO_2$ welding machine and a MIG(metal inert gas) welding robot in the inert gas atmosphere were utilized in order to realize Al 5083 welding to hull and relevant components of green leisure ships. This study aims at investigating the effect of welding conditions(current, voltage, welding speed, etc.) on thermal deformation that occurs as welding operation and tensile characteristics after welding, by using Al 5083, nonferrous material, applied to manufacturing of eco-environmental leisure ships. With respect to welding condition to minimize the thermal deformation, 150 A and 16 V at the wire-feed rate of 6 mm/sec were acquired in the process of welding Al 5083 through an auto carriage type of $CO_2$ welding feeder. As to tensile characteristics of Al 5083 welding through a MIG welding robot, most of tensile specimens showed the fracture behavior on HAZ(heat affected zone) located at the area joined with weld metal, except for some cases. Especially, for the case of the Al specimen with 5 mm thickness, 284.62 MPa of tensile strength and 11.41 % of elongation were obtained as an actual allowable tensile stress-strain value. Mostly, after acquiring the optimum welding condition, the relevant welding data and technical requirements might be provided for actual welding operation site and welding procedure specification (WPS).

• Asian Journal of Atmospheric Environment
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• v.12 no.1
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• pp.37-46
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• 2018

The Minamata Convention on Mercury entered into force on August 16, 2017. It requires Parties to the Convention to control and, where feasible, reduce mercury emissions from the listed sources. To implement the Convention, Japan amended the Air Pollution Control Law and added clauses that force operators to control their mercury emissions below emission limit values (ELVs). The ELVs have been established separately for new and existing sources, targeting the source categories listed in the Convention: coal-fired boilers, smelting and roasting processes used in the production of non-ferrous metals (lead, zinc, copper and industrial gold), waste incineration facilities and cement clinker production facilities. The factors used to establish the ELVs include the present state of mercury emissions from the targeted categories as well as the mercury content in fuels and materials, best available techniques (BATs) and best environmental practices (BEPs) to control and reduce mercury emissions and ELVs or equivalent standards to control mercury emissions in other countries. In this regard, extensive data on mercury emissions from flue gas and the mercury content of fuels and materials were collected and analyzed. The established ELVs range from $8{\mu}g/Nm^3$ for new coal-fired boilers to $400{\mu}g/Nm^3$ for existing secondary smelting processes used in the production of copper, lead and zinc. This paper illustrates the ELVs for the targeted source categories, explaining the rationales and approaches used to set the values. The amended Law is to be enforced on April 1, 2018. From future perspectives, checks of the material flow of mercury, following up on the state of compliance, review of the ELVs and of the measurement and monitoring methods have been noted as important issues.

• Resources Recycling
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• v.11 no.4
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• pp.11-16
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• 2002

Analysis and separation of constituent materials of old car have been performed by using the industrial shredding line. For this aim, three old cars made by domestic automobile manufacturers, Sonata II, Sephia and Prince were chosen and delivered in pressed form without engine, tires and doors, etc. Shredding line was substantially composed of pre- and main-shredder. cyclone, magnetic separation, eddy current separation and man-power separation. From the separation of shredder products, iron scrap was observed to be the major material of old car accounting for 60.1 ％ of total weight and non-ferrous metals involving Al, Cu and Zn, etc. were about 2％. Light fluff, about 90％ of total fluff product, was comprised with plastic, fiber and sponge, etc. and the fraction of 5 cm undersize in light fluff was 70.5%. In case of heavy fluff, however. rubber and plastic were found to be the major constituent materials of it. Among the constituent materials of fluff, plastic showed the highest calorific value, more than 10,000 cal/gr and leather and rubber showed relatively high chlorine content, 10.3 and 2.55 wt%, respectively.

• Journal of Magnetics
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• v.19 no.2
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• pp.126-129
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• 2014

We report the crystallographic and magnetic properties of $Ni_{0.3}Fe_{0.7}Ga_2S_4$ by means of X-ray diffractometer (XRD), a superconducting quantum interference device (SQUID) magnetometer, and a M$\ddot{o}$ssbauer spectroscopy. In particular, $Ni_{0.3}Fe_{0.7}Ga_2S_4$ was studied by M$\ddot{o}$ssbauer analysis for evidence of spin reorientation. The chalcogenide material $Ni_{0.3}Fe_{0.7}Ga_2S_4$ was fabricated by a direct reaction method. XRD analysis confirmed that $Ni_{0.3}Fe_{0.7}Ga_2S_4$ has a 2-dimension (2-D) triangular lattice structure, with space group P-3m1. The M$\ddot{o}$ssbauer spectra of $Ni_{0.3}Fe_{0.7}Ga_2S_4$ at spectra at various temperatures from 4.2 to 300 K showed that the spectrum at 4.2 K has a severely distorted 8-line shape, as spin liquid. Electric quadrupole splitting, $E_Q$ has anomalous two-points of temperature dependence of $E_Q$ curve as freezing temperature, $T_f=11K$, and N$\acute{e}$el temperature, $T_N=26K$. This suggests that there appears to be a slowly-fluctuating "spin gel" state between $T_f$ and $T_N$, caused by non-paramagnetic spin state below $T_N$. This comes from charge re-distribution due to spin-orientation above $T_f$, and $T_N$, due to the changing $E_Q$ at various temperatures. Isomer shift value ($0.7mm/s{\leq}{\delta}{\leq}0.9mm/s$) shows that the charge states are ferrous ($Fe^{2+}$), for all temperature range. The Debye temperature for the octahedral site was found to be ${\Theta}_D=260K$.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2005.05a
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• pp.57-61
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• 2005

In this study, the machine vision system for inspection using color recognition method have been designed and developed to automatically sort out a specified material such as Cu scraps or other non-ferrous metal scraps mixed in Fe scraps. The system consists of a CCD camera, light sources, a frame grabber, conveying devices and an air nozzled ejector, and is program-controlled by a image processing algorithm. The ejector is designed to be operated by an I/O interface communication with a hardware controller. The sorting examination results show that the efficiency of separating Cu scraps from the Fe scraps mixed with Cu scraps is around 90 % at the conveying speed of 15 m/min. and the system is proven to be excellent in terms of its efficiency. Therefore, it is expected that the system can be commercialized in shredder firms, if the high-speed automated sorting system will be realized.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.18 no.10
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• pp.68-74
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• 2019

In the case of a partition panel for a vehicle, it is used as a vehicle chassis component that serves to distinguish the indoor and outdoor spaces of a vehicle and is mounted on a backrest portion of the vehicle's back seat to ensure the convenience of passengers by connecting the floor and the side of the vehicle. Because it is a relatively large-sized plate material among automobile chassis parts except the moving parts and non-ferrous materials can be applied, it is considered as a part having a large light-weight effect. However, the partition panel is one of the vehicle parts that must satisfy the light-weight effect as well as various structural reliability, such as torsional rigidity, vibration, and impact characteristics, for securing the running stability of the vehicle when driving at the same time. So, In this study, the possibility of replacing the aluminum partition panel as CFRP(Carbon Fiber Reinforced Plastic) partition panel is evaluated through comparing the two partition panels by using the structural reliability(stiffness/strength analysis), vibration analysis, impact analysis.

• Electronic Materials Letters
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• v.14 no.6
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• pp.689-699
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• 2018

Nanostructured Ni doped $Bi_2S_3$ ($Bi_{2-x}Ni_xS_3$, $0{\leq}x{\leq}0.07$) is explored as a candidate for telluride free thermoelectric material, through a combination process of mechanical alloying with subsequent consolidation by cold pressing followed with a sintering process. The cold pressing method was found to impact the thermoelectric properties in two ways: (1) introduction of the dopant atom in the interstitial sites of the crystal lattice which results in an increase in carrier concentration, and (2) introduction of a porous structure which reduces the thermal conductivity. The electrical resistivity of $Bi_2S_3$ was decreased by adding Ni atoms, which shows a minimum value of $2.35{\times}10^{-3}{\Omega}m$ at $300^{\circ}C$ for $Bi_{1.99}Ni_{0.01}S_3$ sample. The presence of porous structures gives a significant effect on reduction of thermal conductivity, by a reduction of ~ 59.6% compared to a high density $Bi_2S_3$. The thermal conductivity of $Bi_{2-x}Ni_xS_3$ ranges from 0.31 to 0.52 W/m K in the temperature range of $27^{\circ}C$ (RT) to $300^{\circ}C$ with the lowest ${\kappa}$ values of $Bi_2S_3$ compared to the previous works. A maximum ZT value of 0.13 at $300^{\circ}C$ was achieved for $Bi_{1.99}Ni_{0.01}S_3$ sample, which is about 2.6 times higher than (0.05) of $Bi_2S_3$ sample. This work show an optimization pathway to improve thermoelectric performance of $Bi_2S_3$ through Ni doping and introduction of porosity.

• Korean Journal of Soil Science and Fertilizer
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• v.7 no.2
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• pp.71-97
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• 1974

Many studies on the changes of the materials in the water-logged paddy soil have been reported, but there will be several problems to apply them on the field soil. The main differences between the method of soil packed in beaker or column tube to that of natural field furrow slice are with or without of the rice root and the effect of water percolation. On the other hand, the mechanism of the water percolation on the changes of material in the natural field furrow slice are gradually understood. The purpose of this experiment is to know the effect of the rice cultivation on the chemical and physical changes of material in the water-logged paddy soil. Obtained results are as follows. 1. The physical and chemical changes on the water-logged paddy soil in the non-planted control-plot were nearly the same as the beaker or column tube experiment, while in the planted plot, slightly altered patterns were observed. 2. The relation between the number of tillers and total cation, $Ca^{{+}{+}}$, $Mg^{{+}{+}}$, Fe and Mn in the leachate showed very high significance. T hisresult showed that the leaching of those cation was promoted by growing of the rice r- of the rice root. 3. On the other hand, the concentration of the potassium, silica and phosphorus in leachates was gradually decreased and that of $NH_4$-N could not detect after the stage of active tillering. These facts revealed that such components were absorbed by rice plant. 4. The highly significant correlation between the number of tillers and the concentration of the total cation, $Ca^{{+}{+}}$, $Mg^{{+}{+}}$, $Fe^{{+}{+}}$, Fe and Mn in the percolated water was observed except that of $Mg^{{+}{+}}$. It was also showed that the rice root promoted the leaching of those cation. 5. The very high significance in the correlation between $HCO_3{^-}$ and the number of tillers indicated that the higher activity of the rice root was, the more $HCO_3{^-}$ concentration in the leachate was increased. 6. The relationship between the $HCO_3{^-}$ and the total cation, $Ca^{{+}{+}}$, $Mg^{{+}{+}}$, $Fe^{{+}{+}}$, Fe and Mn was appeared very highly significant. $HCO_3{^-}$, the metabolite of the rice root, promoted the leaching of $Ca^{{+}{+}}$, $Mg^{{+}{+}}$, $Fe^{{+}{+}}$ and Mn. This fact might be a result that these cations were leached as the form of bicarbonate. 7. The iron in the leachate was the form of $Fe^{{+}{+}}$ and the correlation between $Fe^{{+}{+}}$ and $HCO_3{^-}$ was very highly significant. This result indicated that it seemed to be ferrous bicarbonate when it is leached out. 8. In the rhizosphere, ferrous iron was decreased gradually and the concentration of glucose was as high as 2 to 3 times in comparison with the other parts of the soil. These facts were the same as the previous reports in which rhizosphere was oxidized by the oxigen excreted from the root, and was enriched by the organic matter which was also excreted from the root and accumulated residues of the root. 9. ${\beta}$-Glucosidase and phosphatase activity in the rhizosphere was higher than that of the other parts of the soil. This facts might be attributed to the vigorous activity of microorganism in the rhizosphere where glucose concentration was high. 10. The pH in the leachate of the planted plot was lower than that of control, and the Eh on the planted soil was elevated in the last stage.