• Title/Summary/Keyword: Ni particle

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Classification and recognition of electrical tracking signal by means of LabVIEW (LabVIEW에 의한 Tracking 신호 분류 및 인식)

  • Kim, Dae-Bok;Kim, Jung-Tae;Oh, Sung-Kwun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.4
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    • pp.779-787
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    • 2010
  • In this paper, We introduce electrical tracking generated from surface activity associated with flow of leakage current on insulator under wet and contaminated conditions and design electrical tracking pattern recognition system by using LabVIEW. We measure the leaking current of contaminated wire by using LabVIEW software and the NI-c-DAQ 9172 and NI-9239 hardware. As pattern recognition algorithm and optimization algorithm for electrical tracking system, neural networks, Radial Basis Function Neural Networks(RBFNNs) and particle swarm optimization are exploited. The designed electrical tracking recognition system consists of two parts such as the hardware part of electrical tracking generator, the NI-c-DAQ 9172 and NI-9239 hardware and the software part of LabVIEW block diagram, LabVIEW front panel and pattern recognition-related application software. The electrical tracking system decides whether electrical tracking generate or not on electrical wire.

Design for Thermite Reaction Efficiency Improvement of Nb-Ni Mother Alloy (Nb-Ni 모 합금의 테르밋 반응 효율 향상 방안 설계)

  • Jin Uk Gwon;Hye Sung Kim
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.1
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    • pp.33-39
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    • 2023
  • In this study, the effect of mixing condition of raw material powders possessing various particle size and particle size distribution on thermite reaction efficiency was investigated. When fine raw powders are used, rather the reaction yield tends to decrease due to agglomeration. In contrast, coarse raw powders make deteriorate the contact area between raw material powders containing Al reducing agent. To ensure the optimal thermite reaction efficiency, it is required to optimize a mixture condition of raw material powders prior to thermite reaction. From the current experiment, the maximum thermite reaction efficiency is 77%, which came from Nb2O5 + NiO +Al mixtures with size distribution from 9.25 to 22.63 ㎛.

Synthesis and characterization of LiMn1.5Ni0.5O4 powders using polymerization complex method (착체중합법을 이용한 LiMn1.5Ni0.5O4 분말합성 및 특성평가)

  • Sin, Jae-Ho;Kim, Jin-Ho;Hwang, Hae-Jin;Kim, Ung-Soo;Cho, Woo-Seok
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.4
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    • pp.194-199
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    • 2012
  • The $LiMn_{1.5}Ni_{0.5}O_4$, substituting a part of Mn with Ni in the $LiMn_2O_4$, the spinel structure has good charge-discharge cycle stability and high discharge capacity at 4.7 V. In this study $LiMn_{1.5}Ni_{0.5}O_4$ powders were synthesized by polymerization complex method. The effect on the characteristics of synthesized $LiMn_{1.5}Ni_{0.5}O_4$ powders was studied with citric acid (CA) : metal ion (ME) molar ratio (5 : 1, 10 : 1, 15 : 1, 30 : 1) and calcination temperature ($500{\sim}900^{\circ}C$). Single phase of $LiMn_{1.5}Ni_{0.5}O_4$ was observed from XRD analysis on the powders calcined at low ($500^{\circ}C$) and high temperatures ($900^{\circ}C$). The crystalline size and crystallinity increased with calcination temperature. At low calcination temperature the particle size decreased and specific surface area increased as the CA molar ratio increased. On the other hand, high particle growth rate at high calcination temperature interfered the particle size reduction and specific surface area increase induced by the increase of CA molar ratio.

Preparation and Characterization of Stable Suspensions of Ni Nanoparticles (Ni 나노 분말을 이용한 안정한 현탁액 제조 및 특성)

  • Lee Eun-Hee;Lee Min-Ku;Rhee Chang-Kyu
    • Journal of Powder Materials
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    • v.13 no.2 s.55
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    • pp.138-143
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    • 2006
  • In this study, the effects of the dispersants, i.e., Hypermer KD-2 and poly(l-vinyl-2-pyrrolidone) (PVP), and their concentration on the dispersion stability of Ni nanoparticles ($10nm{\sim}40nm$) in ethanol were investigated by using a visual inspection, a transmission profile (Turbiscan), and a zeta potential measurement. The transmission profiles measured by Turbiscan showed that the particle size increased over the entire height of the sample for suspensions with both the dispersants without showing any particle coalescence and sedimentation. The visual inspection also confirmed that the Ni suspensions with Hypermer KD-2 and PVP were very stable for more than a year. The zeta potential values varied from positive to negative with increasing the dispersant's concentration. The dispersion stability of the suspensions was not affected by both the dispersant's concentration and the zeta potential values. The observed suspension stability of Ni nanoparticles was attributed to the steric effect for the Hypermer KD-2 and to the bridging effect for the PVP.

Fabrication of Core-Shell Structured Ni-Based Alloy Nanopowder by Electrical Wire Explosion Method

  • Lee, A-Young;Lee, Gwang-Yeob;Oh, Hye-Ryeong;Kim, Hyeon-Ah;Kim, Song-Yi;Lee, Min-Ha
    • Journal of Powder Materials
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    • v.23 no.6
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    • pp.409-413
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    • 2016
  • Electrical wire explosion in liquid media is a promising method for producing metallic nanopowders. It is possible to obtain high-purity metallic nanoparticles and uniform-sized nanopowder with excellent dispersion stability using this electrical wire explosion method. In this study, Ni-Fe alloy nanopowders with core-shell structures are fabricated via the electrical explosion of Ni-Fe alloy wires 0.1 mm in diameter and 20 mm in length in de-ionized water. The size and shape of the powders are investigated by field-emission scanning electron microscopy, transmission electron microscopy, and laser particle size analysis. Phase analysis and grain size determination are conducted by X-ray diffraction. The result indicate that a core-shell structured Ni-Fe nanopowder is synthesized with an average particle size of approximately 28 nm, and nanosized Ni core particles are encapsulated by an Fe nanolayer.

Fabrication and Oxidation Behaviors of Nickel-coated Aluminum Powders for Energetic Applications (에너제틱 응용을 위한 Ni코팅된 Al분말소재 제조 및 산화거동)

  • Kim, Kyung Tae;Woo, Jae Yeol;Yu, Ji Hun;Lee, Hye Moon;Lim, Tae Soo;Choi, Yoon Jeong;Kim, Chang Kee
    • Particle and aerosol research
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    • v.10 no.4
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    • pp.177-182
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    • 2014
  • In this study, nickel-coated aluminum (Ni/Al) powders were synthesized for the utilization of energetic applications. Oxide materials present at the surface of Al powders of $45{\mu}m$ in averaged size were removed by using sodium hydroxide(NaOH) solution which is used for controlling pH. Nickel material is coated into the surface of oxide-removed Al powders by electroless-plating process. The microstructure of fabricated Ni/Al powders shows that nickel layers with a few hundreds nm were very homogeneously formed onto the surface of Al powders. The oxidation behavior of Ni/Al exihibit somewhat faster oxidation rate than that of pure Al with surface oxidation. Also, the higher exothermic reaction was observed from the Ni/Al powders. From the result of this, nickel coating is very promising method to obtain highly reactive and safe Al powders for energetic applications.

Composite Coating of Nickel-Boron Nitride-Phosphours and Nickel-Boron Nitride-Boron Ternary System on Aluminum (알루미늄에 니켈-질화붕소-인과 니켈-질화붕소-붕소의 3원계 복합도금)

  • Kuak Woo-Sup;Yoon, Byung-Ha;Kim, Dai-Ryong
    • Journal of the Korean institute of surface engineering
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    • v.19 no.3
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    • pp.83-91
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    • 1986
  • Codeposited of boron nitride(BN) particle dispersed into electroless nickel-phosphours (Ni-P) and nickel-boron(Ni-B) platings were studied for the purpose of developing the wear resistance and lubricity. BN can be codeposited from electroless nickel plating bath with $NaH_2PO_2$ and $NaBH_4$ as the reducing agents. Most dispersolids were distributed uniformly in the Ni-P and Ni-B matrix. Abrasion loss decreased with increasing amount of codeposits and reached a constant value 2.4 percent by volume percent of BN particle. The wear resistance and the friction coefficient of the heat treated BN composite coatings were improved about three times than that of as-coatings. The BN composite coatings were more wear resistance than hard chromium. Ni-B-BN composite coatings showed lower wear resistance and friction coefficient than Ni-P-BN. The BN content of the deposite was found to be 2.4 v/o for these optium conditions.

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Synthesized and Characterization of high density cathode materials for Lithium Secondary Batteries (리튬이온이차전지용 고밀도 양극활물질의 합성 및 평가)

  • Kwon, Yong-Jin;Choi, Byung-Hyun;Ji, Mi-Jung;Sun, Yang-Kuk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.429-429
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    • 2008
  • Li$[Ni_{1/2}Co_{1/2}]O_2$ powder were synthesized from co-precipitation spherical metal oxide, $[Ni_{1/2}Co_{1/2}](OH)_2$. The preparation of metal hydroxide was significantly dependent on synthetic conditions, such as pH, amount of chelating agent, stirring speed, etc. The optimized condition resulted in $[Ni_{1/2}Co_{1/2}](OH)_2$, of which the particle size distribution was uniform and the particle shape was spherical, as observed by scanning electron microscopy. Calcination of the uniform metal hydroxide with LiOH at higher temperature led to a well-ordered layer-structured Li$[Ni_{1/2}Co_{1/2}]O_2$, as confirmed by X-ray diffraction pattern. Also these materials have ${\alpha}-NaFeO_2$ ($R\bar{3}m$) structure. Due to the homogeneity of the metal hydroxide, $[Ni_{1/2}Co_{1/2}](OH)_2$, the final product, Li$[Ni_{1/2}Co_{1/2}]O_2$, was also significantly uniform, i.e., the average particle size was of about 10 to 15 ${\mu}m$ in diameter and the distribution was relatively narrow. As a result, the corresponding tap-density was also high approximately 2.41 $gcm^{-3}$, of which the value is comparable to that of commercialized $LiCoO_2$.

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Preparation and cation mixing phenomena of LiCo$O_2$and $LiCo_{1-x}$$Ni_x$$O_2$ solid solutions (LiCo$O_2$$LiCo_{1-x}$$Ni_x$$O_2$고용체의 제조 및 양이온 혼합 현상)

  • 임창성;안홍주;강승민;하정수;고영신
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.6
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    • pp.601-605
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    • 1999
  • $LiCoO_2$and $LiCo_{1-x}$$Ni_x$$O_2$ solid solutions were fabricated by the solid state reaction process. The structural cation mixing phenomena were investigated using XRD, SEM, particle size analysis and $^7$Li NMR,The synthesized LiCoO$_2$ and $LiCo_{1-x}Ni_XO_2$ microcrystallines showed the hexagonal layered structures. Mean particle sizes were increased with the increase of the amount of nickel in the solid solutions. The cation mixing effects were increased as increasing the fraction of nickel(x), x = 0.3, 0.5, 0.7. the peak frequency of $^7$Li NMR was shifted to the higher frequency and the line width increased as increasing the amount of nickel in the solid solutions.

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Nano Structure and Mechanical Properties of Rapidly Solidified Al81-(x+y)Si19NixCey Alloy (급속응고된 Al81-(x+y)Si19NixCey 합금의 나노조직과 기계적 특성)

  • 이태행;홍순직
    • Journal of Powder Materials
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    • v.10 no.6
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    • pp.406-414
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    • 2003
  • In order to produce good wear resistance powder metallurgy Al-Si alloys with high strength, addition of glass forming elements of Ni and Ce in $Al_{81}$Si$_{19}$ alloy was examined using SEM, TEM, tensile strength and wear testing. The solubility of Si in aluminum increased with increasing Ni and Ce contents for rapidly solidified powders. These bulk alloys consist of a mixed structure in which fine Si particles with a particle size below 500 nm and very fine A1$_3$Ni, A1$_3$Ce compounds with a particle size below 200 nm are homogeneously dispersed in aluminum matrix with a grain size below 600 nm. The tensile strength at room temperature for $Al_{81}$Si$_{19}$, $Al_{78}$Si$_{19}$Ni$_2$Ce$_{0.5}$, and $Al_{76}$Si$_{19}$Ni$_4$Ce$_1$ bulk alloys extruded at 674 K and ratio of 10 : 1 is 281,521, and 668 ㎫ respectively. Especially, $Al_{73}$Si$_{19}$Ni$_{7}$Ce$_1$ bulk alloy had a high tensile strength of 730 ㎫. These bulk alloys are good wear-resistance bel ter than commercial I/M 390-T6. Specially, attactability for counterpart is very little, about 15 times less than that of the I/M 390-T6. The structural refinement by adding glass forming elements such as Ni and Ce to hyper eutectic $Al_{81}$Si$_{19}$ alloy is concluded to be effective as a structural modification method.d.tion method.