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Fabrication and Oxidation Behaviors of Nickel-coated Aluminum Powders for Energetic Applications

에너제틱 응용을 위한 Ni코팅된 Al분말소재 제조 및 산화거동

  • 김경태 (한국기계연구원 부설 재료연구소) ;
  • 우재열 (한국기계연구원 부설 재료연구소) ;
  • 유지훈 (한국기계연구원 부설 재료연구소) ;
  • 이혜문 (한국기계연구원 부설 재료연구소) ;
  • 임태수 (한국기계연구원 부설 재료연구소) ;
  • 최윤정 (국방과학연구소) ;
  • 김창기 (국방과학연구소)
  • Received : 2014.12.15
  • Accepted : 2014.12.23
  • Published : 2014.12.30

Abstract

In this study, nickel-coated aluminum (Ni/Al) powders were synthesized for the utilization of energetic applications. Oxide materials present at the surface of Al powders of $45{\mu}m$ in averaged size were removed by using sodium hydroxide(NaOH) solution which is used for controlling pH. Nickel material is coated into the surface of oxide-removed Al powders by electroless-plating process. The microstructure of fabricated Ni/Al powders shows that nickel layers with a few hundreds nm were very homogeneously formed onto the surface of Al powders. The oxidation behavior of Ni/Al exihibit somewhat faster oxidation rate than that of pure Al with surface oxidation. Also, the higher exothermic reaction was observed from the Ni/Al powders. From the result of this, nickel coating is very promising method to obtain highly reactive and safe Al powders for energetic applications.

Keywords

Acknowledgement

Supported by : 국방과학연구소

References

  1. Ghanta S.R., Muralidharan K. (2013). Chemical synthesis of aluminum nanoparticles. Journal of Nanoparticles Research, 15, 1715-1725. https://doi.org/10.1007/s11051-013-1715-1
  2. Helmich R.J. and Suslick K. S. (2010). Chemical aerosol flow synthesis of hollow metallic aluminum particles. Chemistry of Materials. 22, 4835-4837. https://doi.org/10.1021/cm101342r
  3. Jouet R. J., Warren A.D., Rosenberg D.M., Bellito V. J., Park K., Zachariah M.R. (2005). Surface passivation of bare aluminum nanoparticles using perfluoroalkyl carboxyl acids, Chemistry of Materials, 17, 2987-2996. https://doi.org/10.1021/cm048264y
  4. Chung S.W., Guliants E.A., Bunker C. E., Hammerstroem D.W., Deng Y., Burgers M.A., Jellis P.A., Buckner S.W. (2009). Capping and passivation of aluminum nanopaticles using alkyl-substituted epoxides. Langmuir, 25, 8883-8887. https://doi.org/10.1021/la901822h
  5. Osborne D.T., Pantoya M.L. (2007). Effect of Al particle size on the thermal degradation of Al/Teflon mixtures. Combustion Science and Technology, 179, 1467-1480. https://doi.org/10.1080/00102200601182333
  6. Sippel T.R., Son S. F., Groven L.J. (2014). Aluminum agglomeration reduction in a composite propellent using tailored Al/PTFE particles, Combustion and Flame 161, 311-321 https://doi.org/10.1016/j.combustflame.2013.08.009
  7. Foley T.J., Johnson C.E., Higa K.T. (2005) Inhibition of oxide formation on aluminum nanoparticles by transition metal coating, Chemistry of Materials, 17, 4086-4091. https://doi.org/10.1021/cm047931k
  8. Andrzejak T.A., Shafirovich E., Varma A. (2007). Ignition mechanism of nickel-coated aluminum particles, Combustion and Flame, 150, 60-70. https://doi.org/10.1016/j.combustflame.2007.03.004
  9. Shafirovich E. and Varma A. (2004) Nickel-coated aluminum particles: a promising fuel for mars mission. NASA T/M-2004-213114.