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Non-monotonic Size Dependence of Electron Mobility in Indium Oxide Nanocrystals Thin Film Transistor

  • Pham, Hien Thu;Jeong, Hyun-Dam
    • Bulletin of the Korean Chemical Society
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    • v.35 no.8
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    • pp.2505-2511
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    • 2014
  • Indium oxide nanocrystals ($In_2O_3$ NCs) with sizes of 5.5 nm-10 nm were synthesized by hot injection of the mixture precursors, indium acetate and oleic acid, into alcohol solution (1-octadecanol and 1-octadecence mixture). Field emission transmission electron microscopy (FE-TEM), High resolution X-Ray diffraction (X-ray), Nuclear magnetic resonance (NMR), and Fourier transform infrared spectroscopy (FT-IR) were employed to investigate the size, surface molecular structure, and crystallinity of the synthesized $In_2O_3$ NCs. When covered by oleic acid as a capping group, the $In_2O_3$ NCs had a high crystallinity with a cubic structure, demonstrating a narrow size distribution. A high mobility of $2.51cm^2/V{\cdot}s$ and an on/off current ratio of about $1.0{\times}10^3$ were observed with an $In_2O_3$ NCs thin film transistor (TFT) device, where the channel layer of $In_2O_3$ NCs thin films were formed by a solution process of spin coating, cured at a relatively low temperature, $350^{\circ}C$. A size-dependent, non-monotonic trend on electron mobility was distinctly observed: the electron mobility increased from $0.43cm^2/V{\cdot}s$ for NCs with a 5.5 nm diameter to $2.51cm^2/V{\cdot}s$ for NCs with a diameter of 7.1 nm, and then decreased for NCs larger than 7.1 nm. This phenomenon is clearly explained by the combination of a smaller number of hops, a decrease in charging energy, and a decrease in electronic coupling with the increasing NC size, where the crossover diameter is estimated to be 7.1 nm. The decrease in electronic coupling proved to be the decisive factor giving rise to the decrease in the mobility associated with increasing size in the larger NCs above the crossover diameter.

Imaging of self-assembled monolayers by surface plasmon microscope (표면 플라즈몬 현미경을 이용한 자기조립 단분자막의 이미징)

  • 표현봉;신용범;윤현철;양해식;김윤태
    • Korean Journal of Optics and Photonics
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    • v.14 no.1
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    • pp.97-102
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    • 2003
  • Multi-channel images of 11-MUA(11-Mercaptoundecanoic acid) and 11-MUOH(11-Mercaptoundecanol) self-assembled monolayers were obtained by using two-dimensional surface plasmon resonance (SPR) absorption. The patterning process was simplified by exploiting direct photo-oxidation of thiol bonding (photolysis) instead of conventional photolithography. Sharper images were resolved by using a white light source in combination with a narrow bandpass filter in the visible region, minimizing the diffraction patterns on the images. The line profile calibration of the image contrast caused by different resonance conditions at each point on the sensor surface (at a fixed incident angle) enables us to discriminate the monolayer thickness in nanometer scale. Furthermore, there is no signal degradation such as photo bleaching or quenching, which are common in the detection methods based on fluorescence.

Endoscopic Surgery for Pituitary Tumor

  • Kim, Dong-Hyun;Kim, Kyu-Hong;Cho, Young-Woon;Kim, Joon-Soo;Lee, In-Chang;Bae, Sang-Do
    • Journal of Korean Neurosurgical Society
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    • v.37 no.1
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    • pp.20-24
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    • 2005
  • Objective: The purpose of this study is to assess the efficacy and advantages of an endoscopic endonasal approach for the treatment of pituitary tumors. Methods: We retrospectively analyzed the records of 31 patients with pituitary tumors having endoscopic endonasal surgery between March 1999 and August 2003. Results: Among 31 patients with pituitary adenomas, 25 (81%) patients exhibited gross total removal of tumor on postoperative MRI within 3 days after surgery. Among 6 patients removed subtotally, 2 had only radiosurgery, 3 have had periodic follow-up MRIs and one patient with large extended tumor (grade IV, Stage E) had secondary transcranial removal of tumor before radiosurgery. Postoperative complications included cerebrospinal fluid leak in 2 patients, sinusitis in 1 patient, and one patient died due to unexpected intracerebral hemorrhage on 5 days after surgery. Besides considerable experiences with this approach are needed because of narrow working channel to the sella turcica, the results of our study showed following advantages of this procedure: visualization of areas not seen with the operating microscope, elimination of oronasal complications, more functional and cosmetic outcome, and shortened operative time and hospital stay. Conclusion: The authors consider that endoscopic endonasal transsphenoidal approach provides good results with minimal invasion for patients with pituitary tumors.

Multibeam-based Subspace Approach for Code Acquisition in Antenna Array DS-CDMA Systems (안테나 어레이 DS-CDMA 통신 시스템에서 코드 동기 획득을 위한 다중 빔 기반의 부분공간 접근 방법)

  • Kim, Sang-Choon
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.9 no.6
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    • pp.1167-1173
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    • 2005
  • In this paper, the use of an antenna array is considered for code timing acquisition of DS-CDMA signals. The probabilities of acquisition are evaluated by applying multiple narrow fixed-beams to the conventional MUSIC acquisition approach in the multiuser environment on the time-varying Rayleigh fading channel. Each fixed-beam for spatial filtering is dedicated to an individual angular sector that is formed by dividing the entire angular domain by the number of antenna elements. The fixed-beams with a capability of interference suppression provide the additional degrees of freedom,. Hence, the multibeam-based MUSIC estimator can be used to synchronize to more users than the conventional MUSIC algorithm for one antenna. The multibeam-based subspace method is evaluated to significantly improve the performance of a single antenna based MUSIC technique in multiuser scenarios.

A Study on A Proper Application for The Navigational Rules in The Public Order in Open Port Act (개항질서법상 항법적용)

  • JI, Sang-Won
    • Journal of Navigation and Port Research
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    • v.28 no.5
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    • pp.359-364
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    • 2004
  • When sea going vessel approaches her destination port, marine traffic density is increased, especially, the marine traffic is concentrated in the entrance channel and the fairway in the inner harbour is more narrow. Therefore, special navigational rules for preventing collision at sea is needed in the inner harbour. Hence there are the rules in The Public Order in Open Port Act in Korea But, in the case of conflict of navigational rule concerned, it is possible to be raised a question that which rule shall be applied preferentially. Also, it is necessary to understand the exact meaning of the navigational rules in The Public Order in Open Port Act. Because the misunderstanding of the rule is caused the collision Therefore, this paper aims to discuss the exact meaning of the navigational rule concerned in the view of legal basis and suggest the principles for a proper application of it.

Assessment on Navigational Stress and Fairway' Width according to Traffic Flow (교통용량에 따른 운항위험도와 항로폭과의 관계에 관한 연구)

  • Seong, Yu-Chang
    • Journal of Navigation and Port Research
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    • v.38 no.3
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    • pp.253-259
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    • 2014
  • Traffic risks in fairway and harbour area increase lately according to be a sharpe change of ship's size and speed. It becomes hot issue to design a fairway, which's width is important to lower traffic risk and ensure navigational safety. The current design making a fairway and width do not focus on maneuvering motion of a large ship, but traffic risks are clear on reflecting the design of fairway, specially on width. To contact with these problems, this research proposes how to determine fairway' width in consideration of traffic volume. it suggests several situations of marine traffic congestion as like narrow channel and harbour area. here uses 162 simulations in MTS Ver.1 developed. Acquired simulation's results, environmental stress dates, figure in a model that relates with required fairway' width and allowable traffic volume. In added, suggested model compares current design with an width.

Topography of the Yeongsan River Basin and its Locals' Life (영산강유역의 지형과 주민생활)

  • Beom, Seon-Gyu
    • Journal of the Korean association of regional geographers
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    • v.8 no.4
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    • pp.451-467
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    • 2002
  • The Yeongsan River is one of major rivers in South Korea, and its basin is one of core areas that produce foods for the nation. The Yeongsan River Basin has flood plain and hill areas well developed, and areas surrounding the Yeongsan Lake has a tidal mud-plat widely dispersed. The flood plains are called 'Deul'. In particular, at the upstream of 'Mulmok' with a narrow valley are widely spread flood plain. The flood plains were developed into rice paddies until the end of Joseon Dynasty. Local core cities were created against these agricultural lands. Hills are called 'Deung', 'Kkageum' and 'Yasan' and in particular, are widely distributed in Naju City and Yeongam County. Forest land on hill began to be seriously developed into agricultural land from the 1960s, and this development is being pursued even today. Much fanning are conducted in the form of leased fanning by outside people. Tidal mud-plats were widely distributed along the downstream of the Yeongsan River, Namhae Bay. Tidal mud-plat is called 'BBeolbat' and tidal channel is called 'Gaeong.' After the estuary dyke of the Yeongsan River was built in 1981, the tidal mud-plat was developed into agricultural land in large-scale reclamation projects, and changed into 'Yeongsan Plains,' With the appearance of new plains, locals' life fundamentally changed, turning all villages into pure farm villages.

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Oceanography in the Waters Adjacent to Kamchatka and Kurile Islands in the Northwestern Pacific - I (북서태평양 명태 어장의 해황 - 1 . 해저지형과 해수유동 -)

  • Yang, Jae-Mock;chang, Sun-Duck
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.13 no.1
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    • pp.11-15
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    • 1977
  • The circulation of the sea water in relation to the submarine topography is discussed using the oceanographic, current measurement and echo-sounding data obtained by R/V Odaesan in the waters adjacent to Kamchatka and Kurile Islands. The continental shelf which is approximately seventy-five kilometers wide at the east of Kamchata Peninsula becomes narrower at the Kurile Islands, and is cut, at the sea floor approximately twenty miles east of Onekotan Island, by a narrow, shallow sea channel extending from the depression in the Onekotan Strait, forming an elevation similar to a guyot. The measured current speed of approximately one knot in the Oyashio Current region east of Kurile Island is faster than that (0.5-0.7 knot) deduced by the dynamic computation of ocean current.

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A Polysilicon Field Effect Transistor Pressure Sensor of Thin Nitride Membrane Choking Effect of Right After Turn-on for Stress Sensitivity Improvement (스트레스 감도 향상을 위한 턴 온 직후의 조름 효과를 이용한 얇은 질화막 폴리실리콘 전계 효과 트랜지스터 압력센서)

  • Jung, Hanyung;Lee, Junghoon
    • Journal of Sensor Science and Technology
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    • v.23 no.2
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    • pp.114-121
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    • 2014
  • We report a polysilicon active area membrane field effect transistor (PSAFET) pressure sensor for low stress deflection of membrane. The PSAFET was produced in conventional FET semiconductor fabrication and backside wet etching. The PSAFET located at the front side measured pressure change using 300 nm thin-nitride membrane when a membrane was slightly strained by the small deflection of membrane shape from backside with any physical force. The PSAFET showed high sensitivity around threshold voltage, because threshold voltage variation was composed of fractional function form in sensitivity equation of current variation. When gate voltage was biased close to threshold voltage, a fractional function form had infinite value at $V_{tn}$, which increased the current variation of sensitivity. Threshold voltage effect was dominant right after the PSAFET was turned on. Narrow transistor channel established by small current flow was choked because electron could barely cross drain-source electrodes. When gate voltage was far from threshold voltage, threshold voltage effect converged to zero in fractional form of threshold voltage variations and drain current change was mostly determined by mobility changes. As the PSAFET fabrication was compatible with a polysilicon FET in CMOS fabrication, it could be adapted in low pressure sensor and bio molecular sensor.

A Study on Shifting of Pivoting Point in accordance with Configuration of Ships (선형에 따른 전심의 이동에 관한 연구)

  • 최명식
    • Journal of the Korean Institute of Navigation
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    • v.10 no.2
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    • pp.83-96
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    • 1986
  • In the restricted sea way such as fair way in harbor, narrow channel etc, the safe ship-handling is a very important problem, which is greatly related with turning ability of ships. It is of great importance that ship-handlers can grasp the position of pivoting point varying with time increase at any moment for relevant steering activities. Mean while, in advanced ship-building countries they study and investigated pivoting point related with turning characteristics, hut their main interest lies in ship design, not in safe ship controlling and maneuvering. In this regards it is the purpose of this paper to provide ship-handlers better under standing of pivoting point location together with turning characteristics and then to help them in safe ship-handling by presenting fact that pivoting points vary according to configuration of ships. The author calculated the variation of pivoting point as per time increase for various type of vessels, based on the hydrodynamic derivatives obtained at test of Davidson Laboratory of Stevens Institutes of Technology , New Jersey, U.S.A. The results were classified and investigated according to the magnitude of block coefficient , length-beam ratio, length-draft ratio, rudder area ratio ete, and undermentioned results were obtained. (1) The trajectory of pivoting point due to variation of rudder angle are all the same at any time, though the magenitude of turning circle are changed variously. (2) The moving of pivoting point is affected by the magnitude of block coefficient, length-beam ratio, length-draft ratio, however the effect by rudder area ratio might be disregarded. (3) In controlling and maneuvering of vessels in harbor, ship-handlers might regard that the pivoting point would be placed on 0.2~0.3L forward from center of gravity at initial stage. (4) The pivoting point of VLCC or container feeder vessels which have block coefficient more than 0.8 and length-beam ratio less than 6.5 are located on or over bow in the steady turning. (5) When a vessel intends to avoid some floating obstruction such as buoy forward around her eourse, the ship-handler might consider that the pivoting point would be close by bow in ballast condition and cloase by center of gravity in full-loaded condition.

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