• 제목/요약/키워드: Nano Control

검색결과 1,020건 처리시간 0.027초

Band gap control by tri-block nanoribbon structure of graphene and h-BN

  • 이지우;정가운
    • EDISON SW 활용 경진대회 논문집
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    • 제4회(2015년)
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    • pp.324-329
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    • 2015
  • First-principles investigations on the hybrid one dementional hexagonal hybrboron-nitride nano ribbons (BNNRs) with a armchair graphene nano-ribbons(AGRNRs), are presented. Electronics properties of the mixed armchair BNC nano-ribbon (BNCNRs) structure show control of a band gap on all cases at the special K-point. And we have studied, the band gap is direct in all cases. The band gap of mixed ABNCNRs could be divided into three groups (${\Delta}3p$, ${\Delta}3p+1$ and ${\Delta}3p+2$) and decrease with the increase of the width. Also these results show similar to the AGNRs case. Different from the band gap value ordering of AGNRs (${\Delta}3p+1$ > ${\Delta}3p$ > ${\Delta}3p+2$), the ordering of ABNCNRs is ${\Delta}3p$ > ${\Delta}3p+1$ > ${\Delta}3p+2$. The discrepancy may come from the differences between the edges of AGRNRs and the boundaries of hybrid BNCNRs. In addition, the bandgap of ABNCNRs are much smaller than those of the corresponding AGNRs. Our results show that the origin of band gap for BNCNRs with armchair shaped edges arises from both quantum confinement effect of the edges. These results similar to thecase of AGNRs. These properties of hybrid BN/C nano-ribbon structure may offer suitable bandgap to develop nnanoscale electronics and solar cell beyond individual GNRs and BNNRs.

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능동적 박막 펌핑에 의한 파운틴 펜 나노 리소그래피 유동 특성에 관한 연구 (A Study on Flow Characteristics of Fountain-pen Nano-Lithography with Active Membrane Pumping)

  • 이진형;이영관;이성근;이석한;김윤제;김훈모
    • 대한기계학회논문집B
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    • 제30권8호
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    • pp.722-730
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    • 2006
  • In this study, the flow characteristics of a FPN (Fountain Pen Nano-Lithography) using active membrane pumping are investigated. The FPN has integrated chamber, micro channel, and high capacity reservoir for continuous ink feed. The most important aspect in this probe provided control of fluid injection using active membrane pumping in chamber. The flow rates in channel by capillary force are theoretically analyzed, including the control of the mass flow rates by the deflection of the membrane. The above results are compared with the numerical simulations that calculated by commercial code, FLUENT. The velocity of the fluid in micro channel shows linear behaviors. And the mass flows are proportional to the second order function of the pumping pressure that is imposed to the membrane.

Surface Hydrolysis of Fibrous Poly(${\epsilon}$-caprolactone) Scaffolds for Enhanced Osteoblast Adhesion and Proliferation

  • Park, Jeong-Soo;Kim, Jung-Man;Lee, Sung-Jun;Lee, Se-Geun;Jeong, Young-Keun;Kim, Sung-Eun;Lee, Sang-Cheon
    • Macromolecular Research
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    • 제15권5호
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    • pp.424-429
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    • 2007
  • A procedure for the surface hydrolysis of an electrospun poly(${\epsilon}$-caprolactone) (PCL) fibrous scaffold was developed to enhance the adhesion and proliferation of osteoblasts. The surface hydrolysis of fibrous scaffolds was performed using NaOH treatment for the formation of carboxyl groups on the fiber surfaces. The hydrolysis process did not induce deformation of the fibers, and the fibers retained their diameter. The cell seeding density on the NaOH-treated PCL fibrous scaffolds was more pronounced than on the non-treated PCL fibers used as a control. The alkaline phosphatase activity, osteocalcin and a mineralization assay strongly supported that the surface-hydrolyzed PCL fibrous scaffolds provided more favorable environments for the proliferation and functions of osteoblasts compared to the non-treated PCL fibrous scaffolds use as a control.

폴리올 공정 제어에 의한 탄소기반 나노 Pt 촉매 담지 특성 평가 (Electrochemical Catalysts Test for Nano Pt Particles on Carbon Support Synthesized by a Polyol Process Parameter Control )

  • 문채린;배진우;최순목
    • 한국전기전자재료학회논문지
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    • 제36권2호
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    • pp.164-169
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    • 2023
  • Nano Pt particles were dispersed on carbon-based supports by a polyol process for a catalyst application in a polymer electrolyte fuel cell. We tried to optimize the effect of pH on the electrostatic forces between the support and the Pt colloids. We investigated the relationship among the surface charges on the carbon support, the solution pH, and the concentration of a glycolate, and the Pt particle size. The produced catalyst with nano Pt particles on the support was evaluated by the long-term cyclic voltammetry (CV) performance test and compared with the results from a commercial catalyst. Our experimental results reveal that the pH-control can modify the particle size distribution and the dispersion of the nano Pt particles. This resulted in a cost-effective method for the synthesis of highly Pt loaded Pt/C catalysts for fuel cells better than a commercial catalyst system.

Efficacy of Cr (III) Supplementation on Growth, Carcass Composition, Blood Metabolites, and Endocrine Parameters in Finishing Pigs

  • Wang, M.Q.;He, Y.D.;Lindemann, M.D.;Jiang, Z.G.
    • Asian-Australasian Journal of Animal Sciences
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    • 제22권10호
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    • pp.1414-1419
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    • 2009
  • The study was conducted to evaluate the effects of trivalent chromium from different sources on growth, carcass composition, and serum parameters in finishing pigs. Ninety-six crossbred pigs with an initial average body weight of 65.57${\pm}$1.05 kg were blocked by body weight and randomly assigned to four treatments with three replicates. Pigs were offered one of four diets including a control diet or the control diet supplemented with 200 ${\mu}g/kg$ chromium from either chromium chloride ($CrCl_{3}$), chromium picolinate (CrPic) or chromium nanocomposite (CrNano) for 40 days. After completion of the feeding trial, eight pigs from each treatment were selected to collect blood samples, and slaughtered to measure carcass composition. The results showed that supplemental chromium had no significant effect on growth performance, while CrNano increased carcass lean proportion and loin Longissimus muscle area (p<0.05), and decreased carcass fat proportion and 10th rib backfat depth (p<0.05). CrPic supplementation also resulted in lower fat proportion and larger Longissimus muscle area (p<0.05). The addition of Cr from CrNano or CrPic decreased serum glucose (p<0.05) and increased concentrations of total protein and free fat acid in serum (p<0.05). Serum urea nitrogen, triglyceride and cholesterol were decreased (p<0.05), and serum high density lipoprotein and lipase activity were increased (p<0.05) with the supplementation of CrNano. Serum insulin was decreased (p<0.05) by supplemental Cr from CrNano or CrPic, and serum insulin-like growth factor I was increased significantly in the CrNano treated group. These results suggest that chromium nanocomposite has higher efficacy on carcass composition in pigs compared to the traditional chromium sources.

Nano-engineered concrete using recycled aggregates and nano-silica: Taguchi approach

  • Prusty, Rajeswari;Mukharjee, Bibhuti B.;Barai, Sudhirkumar V.
    • Advances in concrete construction
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    • 제3권4호
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    • pp.253-268
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    • 2015
  • This paper investigates the influence of various mix design parameters on the characteristics of concrete containing recycled coarse aggregates and Nano-Silica using Taguchi method. The present study adopts Water-cement ratio, Recycled Coarse Aggregate (%), Maximum cement content and Nano-Silica (%) as factors with each one having three different levels. Using the above mentioned control parameters with levels an Orthogonal Array (OA) matrix experiments of L9 (34) has selected and nine number of concrete mixes has been prepared. Compressive Strength, Split Tensile Strength, Flexural Tensile Strength, Modulus of Elasticity and Non-Destructive parameters are selected as responses. Experimental results are analyzed and the optimum level for each response is predicted. Analysis of 28 days CS depicts that NS (%) is the most significant factor among all factors. Analysis of the tensile strength results indicates that the effect of control factor W/C ratio is ranked one and then NS (%) is ranked two which suggests that W/C ratio and NS (%) have more influence as compared to other two factors. However, the factor that affects the modulus of elasticity most is found to be RCA (%). Finally, validation experiments have been carried out with the optimal mixture of concrete with Nano-Silica for the desired engineering properties of recycled aggregate concrete. Moreover, the comparative study of the predicted and experimental results concludes that errors between both experimental and predicted values are within the permissible limits. This present study highlights the application of Taguchi method as an efficient tool in determining the effects of constituent materials in mix proportioning of concrete.

Influence of nano alumina coating on the flexural bond strength between zirconia and resin cement

  • Akay, Canan;Tanis, Merve Cakirbay;Mumcu, Emre;Kilicarslan, Mehmet Ali;Sen, Murat
    • The Journal of Advanced Prosthodontics
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    • 제10권1호
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    • pp.43-49
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    • 2018
  • PURPOSE. The purpose of this in vitro study is to examine the effects of a nano-structured alumina coating on the adhesion between resin cements and zirconia ceramics using a four-point bending test. MATERIALS AND METHODS. 100 pairs of zirconium bar specimens were prepared with dimensions of $25mm{\times}2mm{\times}5mm$ and cementation surfaces of $5mm{\times}2mm$. The samples were divided into 5 groups of 20 pairs each. The groups are as follows: Group I (C) - Control with no surface modification, Group II (APA) - airborne-particle-abrasion with $110{\mu}m$ high-purity aluminum oxide ($Al_2O_3$) particles, Group III (ROC) - airborne-particle-abrasion with $110{\mu}m$ silica modified aluminum oxide ($Al_2O_3+SiO_2$) particles, Group IV (TCS) - tribochemical silica coated with $Al_2O_3$ particles, and Group V (AlC) - nano alumina coating. The surface modifications were assessed on two samples selected from each group by atomic force microscopy and scanning electron microscopy. The samples were cemented with two different self-adhesive resin cements. The bending bond strength was evaluated by mechanical testing. RESULTS. According to the ANOVA results, surface treatments, different cement types, and their interactions were statistically significant (P<.05). The highest flexural bond strengths were obtained in nano-structured alumina coated zirconia surfaces (50.4 MPa) and the lowest values were obtained in the control group (12.00 MPa), both of which were cemented using a self-adhesive resin cement. CONCLUSION. The surface modifications tested in the current study affected the surface roughness and flexural bond strength of zirconia. The nano alumina coating method significantly increased the flexural bond strength of zirconia ceramics.

천연 수용성 설포라판의 나노입자화를 통한 면역 활성 증진 (Enhancement of Immune Activities of Natural Water-Soluble Sulforaphane by Nano Encapsulation Process)

  • 하지혜;한재건;정향숙;오성호;권민철;최영범;고정림;이현용
    • 한국약용작물학회지
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    • 제16권6호
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    • pp.402-408
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    • 2008
  • This study was performed to investigate improving immune activities of natural water-soluble sulforaphane extracted from Brassica oleracea var. italica by nano encapsulation process. The nanoparticles of the sulforaphane extracted with ultrasonification process at $60^{\circ}C$ promoted human B and T cell growth, about $7{\sim}35%$ compared to the control. The secretion of IL-6 and TNF-${\alpha}$ from T cells were also enhanced as $2.6{\times}10^{-4}pg/cell$ and $2.1{\times}10^{-4} pg/cell$, respectively, by the adding nano samples. NK cell activation was improved about 8%, compare to the control in adding cultured medium of T cell added nano samples. It was also found that sulforaphane extracted from B. oleracea var. italica had highly inhibitory activity on hyaluronidase as $IC_{50}$ about $200\;{\mu}g/m{\ell}$. It can be concluded that natural water-soluble sulforaphane samples by nano-encapsulation, each size is 200 nm, extracted from B. oleracea var. italica has high immune activities through higher efficiency of bio-activation than conventional extracts.

용매열 공정을 이용한 세리아(CeO2) 나노분말의 합성 및 분산거동 (Synthesis and Dispersion of Ceria(CeO2) Nanoparticles by Solvothermal Process)

  • 임태섭;옥지영;최연빈;김봉구;손정훈;정연길
    • 한국재료학회지
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    • 제30권7호
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    • pp.376-382
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    • 2020
  • CeO2 nanoparticles, employed in a lot of fields due to their excellent oxidation and reduction properties, are synthesized through a solvothermal process, and a high specific surface area is shown by controlling, among various process parameters in the solvothermal process, the type of solvent. The synthesized CeO2 nanoparticles are about 11~13 nm in the crystallite size and their specific surface area is about 65.38~84.65 ㎡/g, depending on the amount of ethanol contained in the solvent for the solvothermal process; all synthesized CeO2 nanoparticles shows a fluorite structure. The dispersibility and microstructure of the synthesized CeO2 nanoparticles are investigated according to the species of dispersant and the pH value of the solution; an improvement in dispersibility is shown with the addition of dispersants and control of the pH. Various dispersing properties appear according to the dispersant species and pH in the solution with the synthesized CeO2 nanoparticles, indicating that improved dispersing properties in the synthesized CeO2 nanoparticles can be secured by applying dispersant and pH control simultaneously.

Adaptive and Robust Aeroelastic Control of Nonlinear Lifting Surfaces with Single/Multiple Control Surfaces: A Review

  • Wang, Z.;Behal, A.;Marzocca, P.
    • International Journal of Aeronautical and Space Sciences
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    • 제11권4호
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    • pp.285-302
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    • 2010
  • Active aeroelastic control is an emerging technology aimed at providing solutions to structural systems that under the action of aerodynamic loads are prone to instability and catastrophic failures, and to oscillations that can yield structural failure by fatigue. The purpose of the aeroelastic control among others is to alleviate and even suppress the vibrations appearing in the flight vehicle subcritical flight regimes, to expand its flight envelope by increasing the flutter speed, and to enhance the post-flutter behavior usually characterized by the presence of limit cycle oscillations. Recently adaptive and robust control strategies have demonstrated their superiority to classical feedback strategies. This review paper discusses the latest development on the topic by the authors. First, the available control techniques with focus on adaptive control schemes are reviewed, then the attention is focused on the advanced single-input and multi-input multi-output adaptive feedback control strategies developed for lifting surfaces operating at subsonic and supersonic flight speeds. A number of concepts involving various adaptive control methodologies, as well as results obtained with such controls are presented. Emphasis is placed on theoretical and numerical results obtained with the various control strategies.