• Title/Summary/Keyword: Nano Carbon

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Experimental Study on Internal Temperature Change Induced by Heating Element Attached to Tunnel Lining Surface (터널 라이닝 표면에 부착된 발열체로 인한 내부 온도 변화의 실험적 연구)

  • Jin, Hyunwoo;Hwang, Youngcheol
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.11
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    • pp.35-40
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    • 2017
  • The rearside of concrete lining of tunnels constructed in cold region might experience on freezing due to the low temperature. This causes damage of concrete lining resulting in adverse affect on the durability as well as integrity of tunnel structure by causing damage to the concrete lining. In order to prevent the rearside of tunnel lining from freeing, the temperature change inside the concrete lining was measured by attaching a heating element to the tunnel lining surface and generating heat for a certain period of time. A special freezing chamber was developed to conduct the experiments considering in-situ environment. The carbone nanotube (CNT) was used as a heating element in this study. The temperature distribution of the concrete lining was measured by applying the heat to the heating element. The effect of the outside temperature and heating duration were analyzed.

Effects of temperature on Hardness and Stiffness of NR and SBR Vulcanizates (NR과 SBR 가황물의 경도와 강성도 대한 온도의 영향)

  • Jin, Hyun-Ho;Hong, Chong-Kook;Cho, Dong-Lyun;Kaang, Shin-Young
    • Elastomers and Composites
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    • v.42 no.3
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    • pp.143-150
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    • 2007
  • Hardness of rubbery materials, which is important for dimensional stability and product performance, was investigated upon temperature change in this study. A newly developed IRHD (International Rubber Hardness Degree) tester was used to measure the hardness changes of NR and SBR specimens at various temperatures and the hardness values were compared with the Young's modulus. The harness and Young's modulus of NR and SBR showed an abrupt change near the glass transition temperatures. The hardness and Young's modulus were increased by increasing temperature due to the increased random chain conformation of molecules. The effect of temperature on hardness and Young's modulus of NR and SBR specimens filled with carbon black and silica was decreased by increasing filler content.

Ultra-High Frequency Characteristics of Double-Wall Carbon Nanotube Resonator with Different Length (서로 다른 길이를 갖는 이중벽 탄소 나노튜브 공진기의 초고주파 주파수 특성)

  • Kim, Jin-Tae;Lee, Jun-Ha;Lee, Kang-Ho;Choi, Jong-Ho
    • Journal of the Korea Society of Computer and Information
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    • v.15 no.12
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    • pp.175-180
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    • 2010
  • In this paper, we have investigated ultrahigh frequency nano-mechanical resonators, made of DWCNTs with various wall lengths, via classical molecular dynamics simulations. We have aimed our analysis on the frequency variations of these resonators with the DWCNT wall lengths. The results show that the variations can be well fitted by either the Pearson VII function when the resonant frequency of normalized by its maximum frequency is plotted as a function of the inner/outer wall length ratio L5/L10 for different values of the outer wall length L10, and the Gauss distribution function when the resonant frequency of normalized by its maximum frequency is plotted as a function of the outer/inner wall length ratio for different values of the inner wall length.

Preparation and Properties of Hollow Fiber Membrane for Gas Separation Using CTA (CTA를 이용한 중공사형 기체분리막의 제조 및 특성)

  • Koh, Hyung-Chul;Ha, Seong-Yong;Nam, Sang-Yong
    • Membrane Journal
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    • v.21 no.1
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    • pp.98-105
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    • 2011
  • Cellulose triacetate (CTA) polymer among cellulose esters were used for preparing hollow fiber membranes by phase separation method to investigate the gas permeation properties. To endow gas separation properties, 1,4-dioxane and LiCl were used as additives in the polymer dope solution. The spinning conditions including spinning temperature were controlled to form an active skin layer on the hollow fiber surface. Scanning electron microscopy was used to examine morphology of surface and cross section of the prepared CTA hollow fibers. The gas permeation performance of CTA hollow fiber membranes showed $P_{CO2}$ = 17 GPU and ${\alpha}_{CO2/N2}$ = 48.

Characterization of LaCoO3 Perovskite Catalyst for Oxygen Reduction Reaction in Zn-air Rechargeable Batteries (아연-공기전지용 페롭스카이트 산화물 촉매의 산소환원반응 특성)

  • Sun, Ho-Jung;Cho, Myung-Yeon;An, Jung-Chul;Eom, Seungwook;Park, Gyungse;Shim, Joongpyo
    • Journal of Hydrogen and New Energy
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    • v.25 no.4
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    • pp.436-442
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    • 2014
  • $LaCoO_3$ powders synthesized by Pechini process were pulverized by planetary ball-milling to decrease particle size and characterized as a catalyst in alkaline solution for oxygen reduction and evolution reaction (ORR & OER). The changes of physical properties, such as particle size distribution, surface area and electric conductivity, were analyzed as a function of ball-milling time. Also, the variations of the crystal structure and surface morphology of ball-milled powders were examined by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The electrochemically catalytic activities of the intrinsic $LaCoO_3$ powders decreased with increasing ball-milling time, but their electrochemical performance as an electrode improved by the increase of the surface area of the powder.

Development of Recombinant Pseudomonas putida Containing Homologous Styrene Monooxygenase Genes for the Production of (S)-Styrene Oxide

  • Bae, Jong-Wan;Han, Ju-Hee;Park, Mi-So;Lee, Sun-Gu;Lee, Eun-Yeol;Jeong, Yong-Joo;Park, Sung-Hoon
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.11 no.6
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    • pp.530-537
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    • 2006
  • Recently isolated, Pseudomonas putida SN1 grows on styrene as its sole carbon and energy source through successive oxidation of styrene by styrene monooxygenase (SMO), styrene oxide isomerase (SOI), and phenylacetaldehyde dehydrogenase. For the production of (S)-styrene oxide, two knockout mutants of SN1 were constructed, one lacking SOI and another lacking both SMO and SOI. These mutants were developed into whole-cell biocatalysts by transformation with a multicopy plasmid vector containing SMO genes (styAB) of the SN1. Neither of these self-cloned recombinants could grow on styrene, but both converted styrene into an enantiopure (S)-styrene oxide (e.e. > 99%). Whole-cell SMO activity was higher in the recombinant constructed from the SOI-deleted mutant (130 U/g cdw) than in the other one (35 U/g cdw). However, the SMO activity of the former was about the same as that of the SOI-deleted SN1 possessing a single copy of the styAB gene that was used as host. This indicates that the copy number of styAB genes is not rate-limiting on SMO catalysis by whole-cell SN1.

Optimization of SWCNT-Coated Fabric Sensors for Human Joint Motion Sensing

  • Cho, Hyun-Seung;Park, Seon-Hyung;Yang, Jin-Hee;Park, Su-Youn;Han, Bo-Ram;Kim, Jin-Sun;Lee, Hae-Dong;Lee, Kang-Hwi;Lee, Jeong-Whan;Kang, Bok-Ku;Chon, Chang-Soo;Kim, Han-Sung;Lee, Joo-Hyeon
    • Journal of Electrical Engineering and Technology
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    • v.13 no.5
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    • pp.2059-2066
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    • 2018
  • This study explored the feasibility of utilizing an SWCNT-coated fabric sensor for the development of a wearable motion sensing device. The extent of variation in electric resistance of the sensor material was evaluated by varying the fiber composition of the SWCNT-coated base fabrics, attachment methods, number of layers, and sensor width and length. 32 sensors were fabricated by employing different combinations of these variables. Using a custom-built experimental jig, the amount of voltage change in a fabric sensor as a function of the length was measured as the fabric sensors underwent loading-unloading test with induced strains of 30 %, 40 %, and 50 % at a frequency of 0.5 Hz. First-step analysis revealed the following: characteristics of the strain-voltage curves of the fabric sensors confirmed that 14 out of 32 sensors were evaluated as more suitable for measuring human joint movement, as they yield stable resistance values under tension-release conditions; furthermore, significantly stable resistance values were observed at each level of strain. Secondly, we analyzed the averaged maximum, minimum, and standard deviations at various strain levels. From this analysis, it was determined that the two-layer sensor structure and welding attachment method contributed to the improvement of sensing accuracy.

Coatings Properties and Efficiency Performance of Cr-DLC Films Deposited by Hybrid Linear Ion Source for Hydraulic Gear Pump (하이브리드 선형이온원에 의한 유압 기어펌프용 Cr-DLC코팅막의 특성과 효율성능)

  • Cha, Sun-Yong;Kim, Wang-Ryeol;Park, Min-Suk;Kwon, Se-Hun;Chung, Won-Sub;Kang, Myung-Chang
    • Journal of Powder Materials
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    • v.17 no.6
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    • pp.456-463
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    • 2010
  • This paper describes the results of the application of Cr-Diamond-like carbon (DLC) films for efficiency improvement through surface modification of spur gear parts in the hydraulic gear pump. Cr-DLC films were successfully deposited on SCM 415 substrates by a hybrid coating process using linear ion source (LIS) and magnetron sputtering method. The characteristics of the films were systematically investigated using FE-SEM, nano-indentation, sliding tester and AFM instrument. The microstructure of Cr-DLC films turned into the dense and fine grains with relatively preferred orientation. The thickness formed in our Cr buffer layer and DLC coating layer were obtained the 487 nm and $1.14\;{\mu}m$. The average friction coefficient of Cr-DLC films considerably decreased to 0.15 for 0.50 of uncoated SCM415 material. The hardness and surface roughness of Cr-DLC films were measured 20 GPa and 10.76 nm, respectively. And then, efficiency tests were performed on the hydraulic gear pump to investigate the efficiency performance of the Cr-DLC coated spur gear. The experimental results show that the volumetric and mechanical efficiency of hydraulic gear pump using the Cr-DLC spur gear were improved up to 2~5% and better efficiency improvement could be attributed to its excellent microstructure, higher hardness, and lower friction coefficient. This conclusion proves the feasibility in the efficiency improvement of hydraulic gear pump for industrial applications.

Sensitivity enhancement of H2 gas sensor using PbS quantum dots (황화납 양자점 감지막을 통해 감도가 개선된 수소센서)

  • Kim, Sae-Wan;Kim, Na-Ri;Kwon, Jin-Beom;Kim, Jae Keon;Jung, Dong Geon;Kong, Seong Ho;Jung, Daewoong
    • Journal of Sensor Science and Technology
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    • v.29 no.6
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    • pp.388-393
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    • 2020
  • In this study, a PbS quantum dots (QDs)-based H2 gas sensor with a Pd electrode was proposed. QDs have a size of several nanometers, and they can exhibit a high surface area when forming a thin film. In particular, the NH2 present in the ligand of PbS QDs and H2 gas are combined to form NH3+, subsequently the electrical characteristics of the QDs change. In addition to the resistance change owing to the reaction between Pd and H2 gas, the resistance change owing to the reaction between the NH2 of PbS QDs and H2 gas increases the current signal at the sensor output, which can produce a high output signal for the same concentration of H2 gas. Using the XRD and absorbance properties, the synthesis and particle size of the synthesized PbS QDs were analyzed. Using PbS QDs, the sensitivity was significantly improved by 44%. In addition, the proposed H2 gas sensor has high selectivity because it has low reactivity with heterogeneous gases such as C2H2, CO2, and CH4.

Improved Production of Long-Chain Fatty Acid in Escherichia coli by an Engineering Elongation Cycle During Fatty Acid Synthesis (FAS) Through Genetic Manipulation

  • Jeon, Eunyoung;Lee, Sunhee;Lee, Seunghan;Han, Sung Ok;Yoon, Yeo Joon;Lee, Jinwon
    • Journal of Microbiology and Biotechnology
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    • v.22 no.7
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    • pp.990-999
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    • 2012
  • The microbial biosynthesis of fatty acid of lipid metabolism, which can be used as precursors for the production of fuels of chemicals from renewable carbon sources, has attracted significant attention in recent years. The regulation of fatty acid biosynthesis pathways has been mainly studied in a model prokaryote, Escherichia coli. During the recent period, global regulation of fatty acid metabolic pathways has been demonstrated in another model prokaryote, Bacillus subtilis, as well as in Streptococcus pneumonia. The goal of this study was to increase the production of long-chain fatty acids by developing recombinant E. coli strains that were improved by an elongation cycle of fatty acid synthesis (FAS). The fabB, fabG, fabZ, and fabI genes, all homologous of E. coli, were induced to improve the enzymatic activities for the purpose of overexpressing components of the elongation cycle in the FAS pathway through metabolic engineering. The ${\beta}$-oxoacyl-ACP synthase enzyme catalyzed the addition of acyl-ACP to malonyl-ACP to generate ${\beta}$-oxoacyl-ACP. The enzyme encoded by the fabG gene converted ${\beta}$-oxoacyl-ACP to ${\beta}$-hydroxyacyl-ACP, the fabZ catalyzed the dehydration of ${\beta}$-3-hydroxyacyl-ACP to trans-2-acyl-ACP, and the fabI gene converted trans-2-acyl-ACP to acyl-ACP for long-chain fatty acids. In vivo productivity of total lipids and fatty acids was analyzed to confirm the changes and effects of the inserted genes in E. coli. As a result, lipid was increased 2.16-fold higher and hexadecanoic acid was produced 2.77-fold higher in E. coli JES1030, one of the developed recombinants through this study, than those from the wild-type E. coli.