• Title/Summary/Keyword: NaCl Concentration

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Synthesis of LiMn2O4 Powders Using Li-Ion Secondary Battery by SHS Process (SHS합성법에 의한 리튬이온이차전지용 정극활물질 LiMn2O4 의 제조)

  • Jang, Chang-Hyun;Nersisyan, Hayk;Kim, Jung-Han;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.42 no.7 s.278
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    • pp.503-508
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    • 2005
  • A simple and effective method for the synthesis of LiMn$_{2}$O$_{4}$ powder as a cathode material for lithium secondary battery is reported. Micrometer size LiMn$_{2}$O$_{4}$ was prepared by combustion synthesis technique employing initial mixture of l.l LiNO$_{3}$ -1.3Mn-0.7MnO$_{2}$-1NaCl composition. Parametric study of the combustion process including molar ratio of Mn/MnO$_{2}$ and NaCl concentration were carried out under air atmosphere. The combustion products obtained were additionally heat treated at the temperature 900$^{\circ}C$ and the washed by distilled water. The results of charging-discharging characteristics revealed that LiMn$_{2}$O$_{4}$ cell synthesized in the presence of NaCl had a high capacity and much better reversibility than one formed without NaCl An approximate chemical mechanism for LiMn$_{2}$O$_{4}$ formation is proposed.

Effect of Salinity on Orobanche cernua Seed Germination

  • Al-Khateeb, W.M.;Hameed, K.M.;Shibli, R.A.
    • The Plant Pathology Journal
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    • v.19 no.3
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    • pp.148-151
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    • 2003
  • Seeds of broomrape (Orobanche cernua) were exposed to 0, 25, 50, 75, and 100 mM NaCl solutions during their preconditioning period (14 days of moisture) under laboratory conditions and induced to germinate by synthetic germination stimulant (GR24). There was significant reduction in seed germination with increased salt concentration as shown in 35.2, 32.5, 23.6, 14.3, and 9.2% germination, respectively. Exposure of Orobanche cernua seeds to 0.0, 1.0, 1.25, and 1.5 M levels of NaCl for 9 hours resulted in 29.4, 21.3, 20.5, and 17.4% germination, respectively. Water preconditioned seeds showed Heavier protein profile bands of 6.5-14.2 KDa than those of dry seeds. Seeds treated with 0.75 M NaCl showed profile similar with that of water preconditioned ones, plus an extra band at 29-36 KDa. The protein profiles of 1.0 and 1.5 M NaCl treated seeds showed weaker bands with the absence of 29-36 KDa band.

Acute Toxicity of Sodium Chloride, Formaline and Potassium Permanganate to Nile Tilapia Fry (나일틸라피아 치어에 미치는 염화나트륨, 포르말린 및 과망간산칼륨의 금성독성)

  • 박인석;최경철;노재구;김동수
    • Journal of Aquaculture
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    • v.15 no.2
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    • pp.119-121
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    • 2002
  • A study on the acute toxicity in the Nile tilapia, Oreochromis niloticus fry showed that the 24hr-$LC_{50}$ was 18.6% for NaCl,152 ppm for formaline and 2.1 ppm for $KMnO_4$. The fry responded to narrow range of concentration of all the tested chemicals and their toxic effects were dose-dependent.

Effect of NaCl, Gum Arabic and Microbial Transglutaminase on the Gel and Emulsion Characteristics of Porcine Myofibrillar Proteins

  • Davaatseren, Munkhtugs;Hong, Geun-Pyo
    • Food Science of Animal Resources
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    • v.34 no.6
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    • pp.808-814
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    • 2014
  • This study investigated the effect of gum arabic (GA) combined with microbial transglutaminase (TG) on the functional properties of porcine myofibrillar protein (MP). As an indicator of functional property, heat-set gel and emulsion characteristics of MP treated with GA and/or TG were explored under varying NaCl concentrations (0.1-0.6 M). The GA improved thermal gelling ability of MP during thermal processing and after cooling, and concomitantly added TG assisted the formation of viscoelastic MP gel formation. Meanwhile, the addition of GA decreased cooking yield of MP gel at 0.6 M NaCl concentration, and the yield was further decreased by TG addition, mainly attributed by enhancement of protein-protein interactions. Emulsion characteristics indicated that GA had emulsifying ability and the addition of GA increased the emulsification activity index (EAI) of MP-stabilized emulsion. However, GA showed a negative effect on emulsion stability, particularly great drop in the emulsion stability index (ESI) was found in GA treatment at 0.6 M NaCl. Consequently, the results indicated that GA had a potential advantage to form a viscoelastic MP gel. For the practical aspect, the application of GA in meat processing had to be limited to the purposes of texture enhancer such as restructured products, but not low-salt products and emulsion-type meat products.

Formation of Oxidants and Removal of Dye Rhodamine B using PbO2 Electrode (PbO2 전극을 이용한 산화제 생성과 염료 Rhodaime B 제거)

  • Park, Young-Seek
    • Journal of Korean Society on Water Environment
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    • v.27 no.2
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    • pp.194-199
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    • 2011
  • This study has been carried out to evaluate the performance of $PbO_2$ electrode for the purpose of degradation of N,N-Dimethyl-4-nitrosoaniline (RNO, indicator of OH radical), generation of ozone and decolorization of Rhodamine B (RhB) in water. The effect of the applied current (0.2~1.2 A), electrolyte type (NaCl, KCl and $Na_2SO_4$), electrolyte concentration (0.0~2.5 g/L) and solution pH (3~11) were evaluated. Experimental results showed that RhB and RNO removal were increased with the increase of current, NaCl dosage and decrease of pH. Ozone generation tendencies appeared with the almost similar to the RhB and RNO degradation, except of solution pH (Ozone generation was increased with increase of pH). Optimum current for RhB degradation and consumption of electric power was 1.0 A. The RhB degradation with Cl type electrolyte were higher than that with the sulfate type. Optimum NaCl dosage for RhB degradation was 1.0 g/L.

The Immuno-Modulatory and Antitumor Effects of Crude Polysaccharides Extracted from Daedaleopsis tricolor (삼색도장버섯(Daedaleopsis tricolor)에서 추출한 조다당류의 면역 활성 및 항암 효과)

  • Shim, Sung-Mi;Im, Kyung-Hoan;Kim, Jung-Wan;Lee, U-Youn;Kim, Ha-Won;Lee, Min-Woong;Lee, Tae-Soo
    • The Korean Journal of Mycology
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    • v.31 no.3
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    • pp.161-167
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    • 2003
  • Neutral salt soluble [0.9% NaCl (Fr. NaCl)], hot water soluble (Fr. HW) and methanol soluble (Fr. MeOH) materials were extracted from Daedaleopsis tricolor. In vitro cytotoxicity tests, Fr. HW was not cytotoxic against cancer cell lines such as Sarcoma 180, HepG2 and HT-29 at the concentration of $0{\sim}2,000\;{\mu}g/ml$, while Fr. NaCl and Fr. MeOH were cytotoxic to the cell lines. Intraperitoneal injection with Fr. NaCl showed antitumor effect with life prolongation of 77.4% in mice inoculated with Sarcoma 180. Fr. NnCl and Fr. HW improved proliferation of spleen cells and the immunopotentiation activity of B lymphocyte by increasing spleen cells and the alkaline phosphatase activity by $1.7{\sim}2.4\;and\;2.2{\sim}8.7$ folds, respectively. Fr, NaCl generated $90\;{\mu}M$ of nitric oxide (NO) when cultured with RAW 264.7 at the concentration of $50\;{\mu}g/ml$, while lipopolysaccharide, a positive control, produced $79{\mu}M$. Intraperitoneal injection with Fr. NaCl (50 mg/kg body weight) increased the numbers of peritoneal exudate cells and circulating leukocytes by 10 folds and two folds, respectively, than in the control group. The antitumor effect of D, tricolor was likely due to immunopotentiation activity.

Separation of Tungsten and Vanadium from Alkaline Solution with adding CaCl2 (알칼리 용액 중 CaCl2 첨가에 의한 텅스텐과 바나듐의 분리)

  • Moon, Gyeonghye;Choi, In-hyeok;Park, Kyungho;Kang, Hee-Nam;Kang, Jungshin;Lee, Jin-Young
    • Resources Recycling
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    • v.26 no.4
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    • pp.42-49
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    • 2017
  • As a fundamental study for the separation of vanadium and tungsten from the leaching solution obtained from the soda roasting and water leaching process of spent SCR (Selective Catalytic Reduction) catalyst was carried out. The precipitation behaviors of vanadium and tungsten using the artificial solution (V: $1g{\cdot}L^{-1}$, W: $10g{\cdot}L^{-1}$) was investigated depending on temperature, NaOH concentration and the amount of $CaCl_2$ (aq.) added. V (aq.) was selectively precipitated at lower temperature than 293 K while tungsten also was precipitated at higher temperature. Precipitation rate of V and W was decreased by the increasing concentration of NaOH. On the other hand, excess Ca addition induced the increase of precipitation rate for V and W due to the formation of $Ca(OH)_2$ following the pH decline. The response surface methodology was employed to optimize the selective precipitation. Vanadium of 99.5% and tungsten of 0.0% was precipitated at $0.5mol{\cdot}L^{-1}$ of aqueous NaOH and 1 equivalent ratio of $CaCl_2$ at 293 K.

Mathematical Model for Predicting the Growth Probability of Staphylococcus aureus in Combinations of NaCl and NaNO2 under Aerobic or Evacuated Storage Conditions

  • Lee, Jeeyeon;Gwak, Eunji;Ha, Jimyeong;Kim, Sejeong;Lee, Soomin;Lee, Heeyoung;Oh, Mi-Hwa;Park, Beom-Young;Oh, Nam Su;Choi, Kyoung-Hee;Yoon, Yohan
    • Food Science of Animal Resources
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    • v.36 no.6
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    • pp.752-759
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    • 2016
  • The objective of this study was to describe the growth patterns of Staphylococcus aureus in combinations of NaCl and $NaNO_2$, using a probabilistic model. A mixture of S. aureus strains (NCCP10826, ATCC13565, ATCC14458, ATCC23235, and ATCC27664) was inoculated into nutrient broth plus NaCl (0, 0.25, 0.5, 0.75, 1, 1.25, 1.5, and 1.75%) and $NaNO_2$ (0, 15, 30, 45, 60, 75, 90, 105, and 120 ppm). The samples were then incubated at 4, 7, 10, 12 and $15^{\circ}C$ for up to 60 d under aerobic or vacuum conditions. Growth responses [growth (1) or no growth (0)] were then determined every 24 h by turbidity, and analyzed to select significant parameters (p<0.05) by a stepwise selection method, resulting in a probabilistic model. The developed models were then validated with observed growth responses. S. aureus growth was observed only under aerobic storage at $10-15^{\circ}C$. At $10-15^{\circ}C$, NaCl and $NaNO_2$ did not inhibit S. aureus growth at less than 1.25% NaCl. Concentration dependency was observed for NaCl at more than 1.25%, but not for $NaNO_2$. The concordance percentage between observed and predicted growth data was approximately 93.86%. This result indicates that S. aureus growth can be inhibited in vacuum packaging and even aerobic storage below $10^{\circ}C$. Furthermore, $NaNO_2$ does not effectively inhibit S. aureus growth.

Corrosive Characterisics of 12Cr Alloy Steel and Fatigue Characteristics of the Artificially Degraded 12Cr Alloy Steel (12Cr 합금강의 부식특성 및 인공열화된 12Cr합금강의 피로특성)

  • Jo, Sun-Young;Kim, Chul-Han;Bae, Dong-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.6
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    • pp.965-971
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    • 2001
  • To estimate the reliability of 12Cr alloy steel, the material of turbine blade in the steam power plant, Its corrosion susceptibility and fatigue characteristics in NaCl and Na$_2$SO$_4$solution with the difference of concentration and temperature was investigated. The polarization tests recommended in ASTM G5 standard for corrosion susceptibility in the various corrosive solutions was estimated. It showed that the higher temperature, the faster corrosion rates and corrosion rates were the fastest in 3.5 wt.% NaCl and 1M Na$_2$SO$_4$solution. From these results, the degradation conditions were determined in distilled water, 3.5 wt.% NaCl and 1M Na$_2$SO$_4$solution at room temperature, 60$\^{C}$ and 90$\^{C}$ during 3, 6 and 9 months. Its surface had a few pits for long duration. But, it was not susceptible in sulfide and chloride condition of several temperatures. If the degraded 12Cr alloy steel and non-degraded one were compared with fatigue characteristics, Any differences were not found regardless of temperature and degradation period.

Decolorization of Real Textile Wastewater by Coagulation Conditions (응집조건이 염색폐수의 색도제거에 미치는 영향)

  • Hong, Young-Ho
    • Applied Chemistry for Engineering
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    • v.20 no.1
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    • pp.34-39
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    • 2009
  • This study was carried out in order to investigate the decolorization and reduced sludge of real textile wastewater by coagulation process. The aim of the study was to verify the relation between decolorization and coagulants of real textile wastewater treatment processes. Coagulation processes were performed using $FeCl_3$, $FeSO_4$, and $Al_2(SO_4)_3$. Real textile wastewater has a mean concentration for BOD, COD, pH, color to be 800 mg/L, 600 mg/L, 9.7, and 102, respectively. From the experimental results, it was shown that the $FeCl_3$ exhibited higher decolorization at the operating conditions 335~2000 mg/L of coagulants and 500 mg/L NaOH dosage. The efficiency of color removal depended on the wastewater pH and concentration of coagulants.