• Title/Summary/Keyword: N-complex

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복잡계 비밀 통신

  • Bae, Young-Chul;Kim, Chun-Suk;Kim, Ju-Wan;Koo, Young-Duk
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • v.9 no.2
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    • pp.289-293
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    • 2005
  • this paper, we introduce a secure communication method using complex system. We make a complex system with the n-double scroll or Chua's oscillator. The Complex system is created by applying identical n0double scroll or non-identical n-double scroll and Chua's oscillator with weak soupled method to each cell. In order to secure communication, we have synthesizing the desired information with a complex system circuit by adding the information signal to the hyper-chaos signal. And then, transmitting the synthesized signal to the ideal channel, we confirm secure communication by separating the information signal and the complex system signal in the receiver.

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L-B막을 위한 (N-alkyl pyridinium)-TCNQ 착제의 합성

  • 정순욱;황교현;김동식;손병청;강도열
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1990.10a
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    • pp.108-109
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    • 1990
  • For the purpose of fabricating of L-B Films, (N-alkyl pyridinium)-TCNQ(1:1) complex is synthesized. This complex is verified by U.V, I.R and elemental analyzer.

Influence of Surfactant on the Iodine Complex Formation of Some Non-ionic Polymers (비이온성 고분자의 Iodine 착물형성에 대한 계면활성제의 영향)

  • Ahn, Beom-Shu
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1031-1037
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    • 2018
  • The formation of a complex between PVP or HPC and iodine was indicated by a red shift in the tri-iode band while PVA-iodine complex showed its characterized band around 500 nm in pure aqueous media. Addition of surfactant SDS resulted in a disapperance of the characteristic blue color of the PVA-iodine complex indicating that the complex is not formed in aqueous surfactant media. However in case of PVP or HPC, presence of the monomers of SDS favored the complex formation but in higher concentration, the micelles of SDS decreased the complex. Complexation was found to increase with increasing content of n-propanol in the system since n-propanol inhibits the formation of gels or microgels in the polymer solution. But in case of PVA-iodine complex, addition of n-propanol led to conversion of bigger polyiodides into smaller ones, which is indicative of increased intermolecular hydrogen bond interaction between propanol and PVA effecting a decrease in the PVA aggregate space.

A Cyclic Subnormal Completion of Complex Data

  • Jung, Il Bong;Li, Chunji;Park, Sun Hyun
    • Kyungpook Mathematical Journal
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    • v.54 no.2
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    • pp.157-163
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    • 2014
  • For a finite subset ${\Lambda}$ of $\mathbb{N}_0{\times}\mathbb{N}_0$, where $\mathbb{N}_0$ is the set of nonnegative integers, we say that a complex data ${\gamma}_{\Lambda}:=\{{\gamma}_{ij}\}_{(ij){\in}{\Lambda}}$ in the unit disc $\mathbf{D}$ of complex numbers has a cyclic subnormal completion if there exists a Hilbert space $\mathcal{H}$ and a cyclic subnormal operator S on $\mathcal{H}$ with a unit cyclic vector $x_0{\in}\mathcal{H}$ such that ${\langle}S^{*i}S^jx_0,x_0{\rangle}={\gamma}_{ij}$ for all $i,j{\in}\mathbb{N}_0$. In this note, we obtain some sufficient conditions for a cyclic subnormal completion of ${\gamma}_{\Lambda}$, where ${\Lambda}$ is a finite subset of $\mathbb{N}_0{\times}\mathbb{N}_0$.

N,N'-Dimethylethylenediamine-N,N'-di-α-butyric Acid Cobalt(III) Complexes Utilizing Oxidation of Sulfur of S-Methyl-L-cysteine

  • Kim, Hyun-Jin;Youm, Kyoung-Tae;Yang, Jung-Sung;Jun, Moo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.23 no.6
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    • pp.851-856
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    • 2002
  • The Reaction of S-methyl-S-cysteine(L-Smc) with racemic $s-cis-[Co(demba)Cl_2]-1$ (Hydmedba = $NN'-dimethylethylenediamine-NN'-di-\alpha-butyric$, acid) yields ${\Delta}$-s-cis-[Co(dmedba)(L-Smc)] 2 with N, O-chelation. Oxidation of sulfur of 2 with $H_2O_2$ in a 1 : 1 mole ratio gives ${\Delta}$-s-cis[Co(dmedba)(L-S(O)mc)] 3 having an uncoordinated sulfenate group. Oxidation of sulfur of L-Sm with $H_2O_2in$ a 1: 1 mole ratio produces S-methyl-L-cysteinesulfenate (L-S(O)me) 5. Direct reaction of 1 with 5 in basic medium gives an N.O-chelated ${\Delta}$s-cis[Co(dmedba)(L-S(O)mc)-N.O], which turmed out be same as obtained by oxidation of 2, while an N, S-chelated ${\Delta}$-s-cis-[Co(dmedba)(S-S(O)mc)-N,O] complex 4 is obtained in acidic medium from the reaction of 1 with 5. This is one of the rare $[$Co^{III}$(N_2O_2-type$ ligand)(amino acid)] type complex preparations, where the reaction conditions determine which mode of N, O and N, S caelation modes is favored.

Tetrameric Self-Assembly of a Cu(II) Complex Containing Schiff-Base Ligand and Its Unusually High Catecholase-like Activity

  • Sarkar, Shuranjan;Lee, Woo Ram;Hong, Chang Seop;Lee, Hong-In
    • Bulletin of the Korean Chemical Society
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    • v.34 no.9
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    • pp.2731-2736
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    • 2013
  • We report a new tetrameric supramolecular Cu(II) complex ($Cu_4L_4$ = tetrakis(N,N'-bis(salicylidene)-2,2'-ethylenedianiline)Copper(II)) with a Schiff-base ligand ($H_2L$ = N,N'-bis (salicylaldimine)-1,2-ethylenediamine) containing two N,O-bidentate chelate groups. Though the copper sites of $Cu_4L_4$ are non-coupled, the complex exhibits a unsually high catecholase-like activity ($k_{cat}=935h^{-1}$) when the $Cu_4L_4$ solution is treated with 3,5-di-tert-butylcatechol (3,5-DTBC) at basic condition in the presence of air. Combined information obtained from UV-VIS and EPR measurements could lead the suggestion of the reaction pathway in which the substrate may bind to Cu(II) ions by anti-anti didentate bridging mode.

SOLUTIONS FOR QUADRATIC TRINOMIAL PARTIAL DIFFERENTIAL-DIFFERENCE EQUATIONS IN ℂn

  • Molla Basir Ahamed;Sanju Mandal
    • Journal of the Korean Mathematical Society
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    • v.61 no.5
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    • pp.975-995
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    • 2024
  • In this paper, we utilize Nevanlinna theory to study the existence and forms of solutions for quadratic trinomial complex partial differential-difference equations of the form aF2 + 2ωFG + bG2 = exp(g), where ab ≠ 0, ω ∈ ℂ with ω2 ≠ 0, ab and g is a polynomial in ℂn. In order to achieve a comprehensive and thorough analysis, we study the characteristics of solutions in two specific cases: one when ω2 ≠ 0, ab and the other when ω = 0. Because polynomials in several complex variables may exhibit periodic behavior, a property that differs from polynomials in single complex variables, our study of finding solutions of equations in ℂn is significant. The main results of the paper improved several known results in ℂn for n ≥ 2. Additionally, the corollaries generalize results of Xu et al. [Rocky Mountain J. Math. 52(6) (2022), 2169-2187] for trinomial equations with arbitrary coefficients in ℂn. Finally, we provide examples that endorse the validity of the conclusions drawn from the main results and their related remarks.

The Slow and Tight Binding of MR-387A to Aminopeptidase N

  • CHUNG, MYUNG-CHUL;HYO-KON CHUN;HO-JAE LEE;CHOONG-HWAN LEE;SU-IL KIM;YUNG-HEE KHO
    • Journal of Microbiology and Biotechnology
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    • v.6 no.4
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    • pp.250-254
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    • 1996
  • MR-387A [(2S, 3R)-2-hydroxy-3-amino-4-phenylbutanoyl-L-valyl-L-prolyl-(2, 4-trans)- L-4-hydroxy-proline] reversibly inhibits aminopeptidase N (BC 3.4.11.2) in a process that is remarkable for its unusual degree of time dependence. The time required to inactivate the enzyme by 50$%$ ($t_{1/2}$) for establishing steady-state levels of $EI^*$complex was approximately 5 minutes. This indicates that the inhibition is a slow-binding process. In dissociation experiments of $EI^*$ complex, enzymic activity was regained slowly in a quadratic equation, indicating that the inhibition of aminopeptidase N by MR-387A is tight-binding and reversible. Thus, the binding of MR-387A by aminopeptidase N is slow and tight, with $K_{i}$ (for initial collision complex, EI) and $K_i{^*}$ (for final tightened complex, $EI^*$) of $2.2\times10^{-8}$ M (from Lineweaver-Burk plot) and $4.4\times10^{-10}$ M (from rate constants), respectively. These data indicate that MR-387A and aminopeptidase N are bound approximately 200-fold more tightly in the final $EI^*$complex than in the initial collision EI complex.

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A Novel Al-Bridged Trinuclear Iron(II) Bis(imino)pyridyl Complex with Catalytic Ethylene Polymerization Behavior

  • Long, Zerong;Li, Zhongquan;Ma, Ning;Wu, Biao
    • Bulletin of the Korean Chemical Society
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    • v.32 no.8
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    • pp.2537-2543
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    • 2011
  • A self-assembled Al-bridged diiminopyridine-based ligand (3) was synthesized and characterized by FT-IR, ESI-MS and NMR spectroscopy. Electron spectral titrations were performed to confirm the formation of a novel trinuclear bis(imino)pyridyl iron(II) complex (4) upon addition of $FeCl_2$ into Al-bridged ligand 3 in methanol solution. Simultaneously, a typical bis(imino)pyridine-iron(II) complex (2) was synthesized and fully characterized. The X-ray crystal study of the iron(II) complex 2 disclosed a five-coordinate, distorted square-pyramidal structure with the tridentate N^N^N ligand and chlorides. The optimal molecular structure of 4 was obtained by means of molecular mechanics, which showed that each iron atom in the complex 4 is surrounded by two chlorides, a tridentate N^N^N ligand and one oxygen atom, supporting considerations about the possibility of six-coordinate geometry from MMAO or the ethylene access. A comparison of 4 with the reference 2 revealed a remarkable decrease of the catalytic activity and MMAO consumption (activity up to $0.41{\times}10^3\;kg\;{mol_{Fe}}^{-1}h^{-1}bar^{-1}$, Al/Fe = 650 for 4 and $7.02{\times}10^3\;kg\;{mol_{Fe}}^{-1}h^{-1}bar^{-1}$, Al/Fe = 1600 for 2).

Synthesis and Properties of Terdentates with Extra Pyridine Ring and Their Ru(II) Complexes

  • 장영동;문승욱;Randolph P. Thummel
    • Bulletin of the Korean Chemical Society
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    • v.18 no.2
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    • pp.174-179
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    • 1997
  • The synthesis and electronic as well as redox properties of four Ru(Ⅱ) complexes based on the ligand 4'-(4-pyridyl)-3,3';5',3"-bis-dimethylene-2,2';6',2"-terpyridine are reported. Each new complex is of the type [Ru(L)2]n+ and [Ru(tpy)(L)]n+, where L is the terdentate ligand with extra pyridine ring at 4'-position or is a N-methylated ligand and n=2, 3, or 4. Cyclic voltammetry indicates that the first electron added to the complex enters the viologen-type acceptor in N-methylated ligand.