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http://dx.doi.org/10.5012/bkcs.2013.34.9.2731

Tetrameric Self-Assembly of a Cu(II) Complex Containing Schiff-Base Ligand and Its Unusually High Catecholase-like Activity  

Sarkar, Shuranjan (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University)
Lee, Woo Ram (Department of Chemistry, Research Institute for Natural Sciences, Korea University)
Hong, Chang Seop (Department of Chemistry, Research Institute for Natural Sciences, Korea University)
Lee, Hong-In (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University)
Publication Information
Bulletin of the Korean Chemical Society / v.34, no.9, 2013 , pp. 2731-2736 More about this Journal
Abstract
We report a new tetrameric supramolecular Cu(II) complex ($Cu_4L_4$ = tetrakis(N,N'-bis(salicylidene)-2,2'-ethylenedianiline)Copper(II)) with a Schiff-base ligand ($H_2L$ = N,N'-bis (salicylaldimine)-1,2-ethylenediamine) containing two N,O-bidentate chelate groups. Though the copper sites of $Cu_4L_4$ are non-coupled, the complex exhibits a unsually high catecholase-like activity ($k_{cat}=935h^{-1}$) when the $Cu_4L_4$ solution is treated with 3,5-di-tert-butylcatechol (3,5-DTBC) at basic condition in the presence of air. Combined information obtained from UV-VIS and EPR measurements could lead the suggestion of the reaction pathway in which the substrate may bind to Cu(II) ions by anti-anti didentate bridging mode.
Keywords
Cu(II) complex; N,O-ligand; Self-assembly; Cu(II) EPR; Catecholase;
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