Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Tetrameric Self-Assembly of a Cu(II) Complex Containing Schiff-Base Ligand and Its Unusually High Catecholase-like Activity

  • Sarkar, Shuranjan (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University) ;
  • Lee, Woo Ram (Department of Chemistry, Research Institute for Natural Sciences, Korea University) ;
  • Hong, Chang Seop (Department of Chemistry, Research Institute for Natural Sciences, Korea University) ;
  • Lee, Hong-In (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University)
  • Received : 2013.05.31
  • Accepted : 2013.06.24
  • Published : 2013.09.20
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Abstract

We report a new tetrameric supramolecular Cu(II) complex ($Cu_4L_4$ = tetrakis(N,N'-bis(salicylidene)-2,2'-ethylenedianiline)Copper(II)) with a Schiff-base ligand ($H_2L$ = N,N'-bis (salicylaldimine)-1,2-ethylenediamine) containing two N,O-bidentate chelate groups. Though the copper sites of $Cu_4L_4$ are non-coupled, the complex exhibits a unsually high catecholase-like activity ($k_{cat}=935h^{-1}$) when the $Cu_4L_4$ solution is treated with 3,5-di-tert-butylcatechol (3,5-DTBC) at basic condition in the presence of air. Combined information obtained from UV-VIS and EPR measurements could lead the suggestion of the reaction pathway in which the substrate may bind to Cu(II) ions by anti-anti didentate bridging mode.

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References

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