• 제목/요약/키워드: Multiple pores

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Study of Supersonic Flame Acceleration within AN-based High Explosive Containing Various Gap Materials (다양한 틈새 물질을 포함하는 AN계열 화약의 초음속 화염 전파 특성 연구)

  • Lee, Jinwook;Yoh, Jai-Ick
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.4
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    • pp.32-42
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    • 2013
  • We study the gap effect on detonating high explosives using numerical simulation. The characteristic acoustic impedance theory is applied to understand the reflection and transmission phenomena associated with gap test of high explosives and solid propellants. A block of charge with embedded multiple gaps is detonated at one end to understand the ensuing detonation propagation through pores and non uniformity of the tested material. A high-order multimaterial simulation provides a meaningful insight into how material interface dynamics affect the ignition response of energetic materials under a shock loading.

Potential-dependent Complex Capacitance Analysis for Porous Carbon Electrodes (다공성 탄소전극의 전위에 따른 복소캐패시턴스 분석)

  • Jang, Jong H.;Yoon, Song-Hun;Ka, Bok H.;Oh, Seung M.
    • Journal of the Korean Electrochemical Society
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    • v.6 no.4
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    • pp.255-260
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    • 2003
  • The complex capacitance analysis was performed in order to examine the potential-dependent EDLC characteristics of porous carbon electrodes. The imaginary capacitance profiles $(C_{im}\;vs.\;log\lf)$ were theoretically derived for a cylindrical pore and further extended to multiple pore systems. Two important electrochemical parameters in EDLC can be estimated from the peak-shaped imaginary capacitance plots: total capacitance from the peak area and $\alpha_0$ from the peak position. Using this method, the variation of capacitance and ion conductivity in pores can be traced as a function of electric potential. The electrochemical impedance spectroscopy was recorded on the mesoporous carbon electrode as a function of electric potential and analyzed by complex capacitance method. The capacitance values obtained from the peak area showed a maximum at 0.3V (vs. SCE), which was in accordance with cyclic voltammetry result. The ionic conductivity in pores calculated from the peak position showed a maximum at 0.2 V (vs. SCE), then decreased with an increase in potential. This behavior seems due to the enhanced electrostatic interaction between ion and surface charge that becomes enriched at more positive potentials.

Enhancement of Sensitivity in Interferometric Biosensing by Using a New Biolinker and Prebinding Antibody

  • Park, Jae-Sook;Lim, Sung-Hyun;Sim, Sang-Jun;Chae, Hee-Yeop;Yoon, Hyun-C.;Yang, Sang-Sik;Kim, Byung-Woo
    • Journal of Microbiology and Biotechnology
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    • v.16 no.12
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    • pp.1968-1976
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    • 2006
  • Recombinant E. coli ACV 1003 (recA:: lacZ) was used to measure low concentrations of DNA-damaging chemicals, which produce $\beta$-galactosidase via an SOS regulon system. Very low $\beta$-galactosidase activities of less than 0.01 unit/ml, $\beta$-galactosidase produced through an SOS response corresponding to the 10 ng/ml (ppb) of DNA damaging chemicals in the environment, can be rapidly determined by using an alternative interferometric biosensor with optically flat thin films of porous silicon rather than by the conventional time-consuming Miller's enzyme assay as well as the ELISA method. fu order to enhance the sensitivity in the interferometry, it needs to obtain more uniform distribution and higher biolinking efficiency, whereas interferometric sensing is rapid, cheap, and advantageous in high throughput by using a multiple-well-type chip. In this study, pore size adjusted to 60 nm for the target enzyme $\beta$-galactosidase to be bound on both walls of a Si pore and a calyx crown derivative was apllied as a more efficient biolinker. Furthermore, anti-$\beta$-galactosidase was previously functionalized with the biolinker for the target $\beta$-galactosidase to be specifically bound. When anti-$\beta$-galactosidase was bound to the calyx-crown derivative-linked surface, the effective optical thickness was found to be three times as high as that obtained without using anti-$\beta$-galactosidase. The resolution obtained was very similar to that afforded by the time-consuming ELISA method; however, the reproducibility was still unsatisfactory, below 1 unit $\beta$-galactosidase/ml, owing to the microscopic non-uniform distribution of the pores in the etched silicon surface.

Electrochemical Synthesis of Dumbbell-like Au-Ni-Au Nanorods and Their Surface Plasmon Resonance

  • Park, Yeon Ju;Liu, Lichun;Yoo, Sang-Hoon;Park, Sungho
    • Journal of Electrochemical Science and Technology
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    • v.3 no.2
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    • pp.57-62
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    • 2012
  • In this report, we demonstrate that the longitudinal localized surface plasmon resonance mode can be suppressed when the nanorods were in dumbbell shape. The seed nanorods were synthesized by electrochemical deposition of metals into the pores of anodic aluminum oxide templates. The dumbbell-like nanorods were grown from seed Au-Ni-Au nanorods by a rate-controlled seed-mediated growth strategy. The selective deposition of Au atoms onto Au blocks of Au-Ni-Au nanorods produced larger diameter of Au nanorods with bumpy surface resulting in dumbbell-like nanorods. The morphology of nanorods depended on the reduction rate of $AuCl_4^-$, slow rate producing smooth surface of Au nanorods, but high reduction rate producing bumpy surface morphology. Through systematic investigation into the UV-Vis-NIR spectroscopy, we found that the multiple localized surface plasmon resonance (LSPR) modes were available from single-component Au nanorods. And, their LSPR modes of Au NRs with bumpy surface, compared to the smooth seed Au NRs, were red-shifted, which was obviously attributed to the increased electron oscillation pathways. While the longitudinal LSPR modes of smoothly grown Au NRs were blue-shifted except for a dipole transverse LSPR mode, which can be interpreted by decreased aspect ratio. In addition, dumbbell-like nanorods showed an almost disappeared longitudinal LSPR mode. It reflects that the plasmonic properties can be engineered using complex nanorods structure.

An Experimental Study on the Combustion Characteristics of CWM Single Droplet (CWM 단일액적의 연소특성에 관한 연구)

  • Park, Chong-Sang;Lee, Tae-Won;HA, Jong-Yul;Chung, Sung-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.3
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    • pp.402-410
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    • 2000
  • As the combustion process of CWM consists of the water evaporation, the release and combustion of volatile matter, and the combustion of char for every particle, it is more complex than that of existent liquid fuel. Though the many studies on CWM combustion have been carried out by the single droplet using hanging methods or the multiple droplet using atomization methods, any report don't presents definite solution about the effects by the initial water evaporation and combustion of volatile. When CWM is suddenly exposed in the high temperature surroundings, the internal water evaporates and then each droplet builds up pores. Besides, porosity rate changes along the temperature of surroundings, the composition ratio of CWM, and the initial diameter of droplet. In result, because it affects the whole combustion rate, the combustion of CWM has complex mechanism as compared with the combustion of liquid or gas fuel. Therefore, concentrating on porous structure of CWM, this study has proceeded to acquire the basic data on the CWM injection combustion and closely examines the effects of the first stage combustion on the whole combustion by measuring the diameter variations, pore rate, mass fraction burned, and the internal temperature changes of CWM droplet. The results demonstrate that $60{\sim}70%$ of initial mass is reduced during water evaporation and volatile combustion period, and swelling rate, mass faction burned, and density variation are greatly concerned with atomization of CWM etc.

Anatomical Characteristics of Kenaf Cultivated in Korea (국내에서 생장한 Kenaf의 해부학적 특성)

  • Kwon, Young-Man;Hwang, Won-Joong;Kwon, Sung-Min;Jo, Jun-Hyung;Lee, Myoung-Ku;Kim, Nam-Hun
    • Journal of Forest and Environmental Science
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    • v.21 no.1
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    • pp.98-103
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    • 2005
  • Anatomical properties of kenaf cultivated in Korea was investigated using light microscopy. Bast fiber, phloem ray and cortex parenchyma cell were observed in bast, and vessel, wood fiber and ray in core. A lot of solitary and multiple radial pores in core existed. The cell type of ray parenchyma in radial section was procumbent, upright and square cells. Uniseriate and multiseriate rays existed in tangential section. The layer of bast fiber in bast increased with increasing the growth period.

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A Micro-observation on the Wing and Secondary Cracks Developed in Gypsum Blocks Subjected to Uniaxial Compression (일축압축상태의 석고 실험체에서 발생하는 날개크랙과 이차크랙에 대한 미시적 관측)

  • 사공명
    • Journal of the Korean Geotechnical Society
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    • v.19 no.2
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    • pp.171-178
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    • 2003
  • Wing and secondary cracks are unique types of cracks observed in rock masses subjected to uniaxial and biaxial compressive loading conditions. In this study, morphological features of wing and secondary cracks developed in gypsum specimens are investigated in the macro and micro scales. Along the path of wing crack, microtensile cracks are observed. Microtensile cracks coalesce with pores and show branch phenomenon. From the onset of the wing crack, multiple initiations of microtensile cracks are observed. Microtensile cracks show tortuous propagation paths and relatively constant aperture of the cracks during the propagation. It is shown that microtensile cracks propagate by splitting failure. At the micro scale, microfsults are observed in the path of the secondary cracks. Along the path of the secondary cracks, separation of grains and conglomerate grains, oblique microfaults, and irregular aperture of microfault are observed. These features show that the secondary cracks are produced in shear mode. The measured sizes of fracture process zone across the propagation direction near the tip of wing and secondary cracks range from 10$\mu{m}$ to 20$\mu{m}$ far wing cracks and from 100$\mu{m}$ to 200$\mu{m}$ for secondary cracks, respectively.

Electrokinetic Remediation of Soil Contaminated with Zn, Ni and F (동전기 정화기술을 이용한 Zn, Ni, F 복합오염 토양의 정화)

  • Cho, Jung-Min;Ryu, Byung-Gon;Park, Sung-Woo;Kim, Kyeong-Jo;Baek, Ki-Tae
    • Journal of Soil and Groundwater Environment
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    • v.14 no.1
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    • pp.36-43
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    • 2009
  • The feasibility of electrokinetic remediation was investigated in the laboratory to treat contaminated soil with Zn, Ni and F. Electro-migration and electro-osmosis are the major removal mechanisms because fluorines desorbed from soil exist as an anionic form in soil pores, and Zn and Ni exist as a cationic form. Desorption of fluorine was enhanced under the alkaline condition, but that of Zn and Ni increased under the acidic condition. Sequential pH control was effective to control the mixed wastes from contaminated soil. 2 V/cm was applied to reactor to evaluate the effect of constant voltage gradient, after two weeks, the removal efficiency of Zn, Ni and F was 20.5%, 2.5% and 57.4%, respectively. Even though the removal of Zn and Ni was very low, the pH control enhanced transport of Zn and Ni significantly. As a result, sequential pH control is a effective method to remediate mixed waste-contaminated soil.

Anatomical and Physical Characteristics of Kenaf Grown in Korea (국내에서 생장한 Kenaf (양마)의 해부 및 물리적 특성)

  • Kim, Nam-Hun;Hwang, Won-Joong;Kwon, Goo-Joong;Kwon, Sung-Min;Lee, Myoung-Ku;Cho, Jun-Hyung
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.3
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    • pp.1-7
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    • 2006
  • Anatomical and physical properties of kenaf grown in Chuncheon, Korea were investigated using light and scanning electron microscopy and X-ray diffraction method. Bast fiber, phloem ray, cortex parenchyma cell and sieve tube member were observed in phloem, and vessel element, fiber and ray in xylem. Solitary and multiple radial pores in xylem existed. The cell types of ray parenchyma in radial section were procumbent, upright and square cells. The length of bast fiber increased with increasing the growth period. The length of wood fiber was 0.74~0.82 mm, but was not significantly different between the growth period and stem height. Relative crystallinity was 53~74% in phloem and 43~58% in xylem. Cellulose crystallinity width was 2.68~3.24 nm in phloem and 2.46~2.95 nm in xylem. The green moisture content and green density increased but basic density decreased with increasing the stem height.

A Study on the Reduced Rebound Method of Surface Finishing Spray Photocatalytic Mortar (표면 마감 광촉매 스프레이 모르타르의 리바운드량 저감 방안 연구)

  • Baek, Hyo-Seon;Park, Jeong-Hwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.9
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    • pp.604-609
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    • 2020
  • There are various methods of finishing concrete surfaces, and when considering workability, the spray method is effective, but rebound occurs. The allocation of rebound occurrence control should be adjusted according to the materials used. Thus, a basic study was conducted on multiple techniques for reducing the rebound incidence that are suitable for surface finishing materials containing a photocatalyst. A prior study derived the reduction effect and optimal mix ratio for photocatalytic performance. Based on that study, the rebound reduction was verified according to the specifications of the content and the mechanical durability characteristics of the mixed materials. Rebound, compressive strength, flexural rigidity, and table flow tests were done. The flow was fixed at 170±10 mm considering the workability of the mortar spray equipment. For the experimental variables, the rebound number was adjusted to the silica sand variables relative to the cement weight, and silica sands No. 5 and No. 7 were used. The results show the highest compression strength in the final S-1 variable, and the amount of rebound was minimized. These results were sufficiently filled with the bindings of the silica pores, which increased the binding force between the aggregates, resulting in a lower amount of rebound.