• Title/Summary/Keyword: Molten temperature

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Algorithm Development for Infiltration Control in Component Fabrication Process of Metal Matrix Composites and Their Evaluation (금속기복합재료의 부품 제조공정에 관한 함침제어알고리즘 개발 및 평가)

  • Kang, Chung-Gil;Yun, Kung-Sik
    • Journal of Korea Foundry Society
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    • v.16 no.6
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    • pp.523-536
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    • 1996
  • This paper relates to fabrication processing analysis of metal matrix composites by the injection of liquid metal into a fibrous preforms. One dimensional heat transfer analysis during squeeze infiltration process of aluminum base composites has been studied. An analysis method was investigated for the temperature distribution, infiltration velocity and melt infiltration characteristics with the commercial preform with short fiber array. When molten metal is infiltrated in a fibrous preform with random orientation, phase transformation will be occurred in a region such as molten metal, solidified region, preform region and infiltration composites region. a mathematical modelling for a solidification phenomena in fabrication process of metal matrix composites using a squeeze infiltration technique was investigated by the basic relations for liquid metal into a fibrous preform. The temperature distribution of theoretical results was compared with experimental data.

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PTCR Effects in KCI Molten Salt Synthesized $BaTiO_3$ (KCI 용융염 합성법에 의한 $BaTiO_3$ 의 PTCR 효과)

  • 윤기현;이은홍
    • Journal of the Korean Ceramic Society
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    • v.22 no.5
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    • pp.29-34
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    • 1985
  • The PTCR characteristics of the $BaTiO_3$ as a function of the molten KCl and dopant $Sb_2O_3$ were investitated. When the weight ratio of KCl to raw materials was above 0.1, $BaTiO_3$ was synthesized by calcining at 80$0^{\circ}C$ for 6 hrs. As the amount of the KCl increased the resistivity of the $BaTiO_3$ at room temperature incr-eased. This can be explained by charge compensation effect between electrons and holes and with microstruc-tures change of the specimens. The resistivity of the $BaTiO_3$ decreased with increasing amount of $Sb_2O_3$. In the time-current characteristics initial current decreased with increasing the ratio of KCl to raw materials but initial current increased and then decreased with the increase of the dopant $Sb_2O_3$. These results of the time-current characteristics can be explained by the resistivity-temperature characteristics.

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Atmospheric and Pressurized Operation of a 25 kW MCFC Stack (25 kW급 용융 탄산염 연료 전지 스택의 상압 및 가압 운전)

  • Koh, Joob-Ho;Seo, Hai-Kung;Lim, Hee-Chun
    • Proceedings of the KSME Conference
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    • 2000.04b
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    • pp.264-269
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    • 2000
  • As a part of the ongoing effort towards commercial application of high-temperature fuel cell power generation systems, we have recently built a pilot-scale molten carbonate fuel cell power plant and tested it. The stack test system is composed of diverse peripheral units such as reformer, pre-heater, water purifier, electrical loader, gas supplier, and recycling systems. The stack itself was made of 40cells of $6000cm^2$ area each. The stack showed an output higher than 25kW power and a reliable performance at atmospheric operation. A pressurized performance was also tested, and it turned out the cell performance increased though a few cells have shown a symptom of gas crossover. The pressurized operation characteristics could be analyzed with numerical computation results of a stack model.

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Influence of Coating Conditions on Fe Dissolution and Dross Formation in Continuous Hot-dip Galvanizing Process (연속 용융아연도금 공정에서 Fe용출 및 드로스 발생에 미치는 도금조건의 영향)

  • 전선호;김상헌
    • Journal of the Korean institute of surface engineering
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    • v.36 no.5
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    • pp.364-372
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    • 2003
  • In continuous galvanizing process, dissolution of iron into molten zinc results in a fairly great amount of dross. In order to decrease dross, the amount of dissolved iron of strip in molten zinc was investigated in the range of 0∼0.22%Al content, 440∼$470^{\circ}C$ strip temperature and 3∼60 sec dipping time. Uniform Fe-Al-Zn inhibition layer was formed in the coating layer/strip interface not only in the grain boundary but also in the grain of substrate with the increase of Al content in the zinc pot, while the amount of iron dissolution was decreased. Inhibition layer was unstable as the dipping time and strip temperature increased and the amount of iron dissolution increased.

Modelling of the Resistance Model for Anode and Cathode for Molten Carbonate Fuel Cells (용융탄산염 연료전지용 공기극과 연료극의 저항 모델링)

  • LEE, CHANG-WHAN;JUNG, JUNG-YUL
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.3
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    • pp.267-273
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    • 2018
  • From the experiments of various temperature and gas compositions, total resistance which is composed of ohmic resistance, anode resistance, cathode resistance and Nernst loss was calculated wit simple assumption. In this work, the anode and the cathode resistance was modelled with new equation which can account for the correlation between the operating temperature and the gas composition. The proposed model can predict the resistance with maximum error of 2.57% and employed in the simulation of molten carbonate fuel cells.

Electrical Fire Identification due to Conductor Structure Analysis of Electrical Wires (전선의 도체조직 분석에 의한 전기화재 감식)

  • Park, O-Cheol;Kim, Wang-Kon;Park, Nam-Kyu;Hong, Jin-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.615-618
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    • 2003
  • To investigate the electrical fire identification due to conductor structure analysis of an electrical wire, we are studied by temperature heating test, over current test, short test and electric molten marks. And metal structure analysis of wire by short, we are found out increase in crystal grain with heating temperature. Structure of specimen at over current 300[%] occurred hardly structure formation and boundary of grain.

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Wetting Property and Reflectivity of Sn-3.5Ag Solder by Plating for LED Lead Frame (LED용 리드프레임 상의 Sn-3.5Ag 솔더 도금의 젖음성 및 반사율)

  • Kee, Se Ho;Xu, Zengfeng;Kim, Won Joong;Jung, Jae Pil
    • Korean Journal of Metals and Materials
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    • v.50 no.8
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    • pp.563-568
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    • 2012
  • The wetting property and reflectivity of Sn-3.5Ag solder which was dip coated on a LED lead frame were investigated. The wettability of molten solder on Cu substrate was evaluated by the wetting balance tester, and surface tension was calculated from maximum withdrawal force and withdrawal time. Temperature of the molten solder in a bath was varied in the range of $250-290^{\circ}C$. With increasing temperature, the surface tension decreased a little. The reflectivity of Sn-3.5Ag coated on a substrate became a little lower than the highest current LED lead frame reflectivity.

Residual salt separation technique using centrifugal force for pyroprocessing

  • Kim, Sung-Wook;Lee, Jong Kwang;Ryu, Dongseok;Jeon, Min Ku;Hong, Sun-Seok;Heo, Dong Hyun;Choi, Eun-Young
    • Nuclear Engineering and Technology
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    • v.50 no.7
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    • pp.1184-1189
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    • 2018
  • Pyroprocessing uses various molten salts during electrochemical unit processes. Reaction products after the electrochemical processes must contain a significant amount of residual salts to be separated. Vacuum distillation is a common method to separate the residual salts; however, its high operation temperature may cause side reactions. In this study, a simple rotation technique using centrifugal force was suggested to separate the residual salts from the reaction products at relatively low temperature compared to the distillation technique. When a reaction product container with porous wall rotates inside a vessel heated above the melting point of the residual salt, the residual salt in the liquid phase is separated through centrifugal force. It was shown that the $LiNO_3-Al_2O_3$ mixture can be separated by this technique to leave solid $Al_2O_3$ inside the container, with a separation efficiency of 99.4%.

Electrochemical extraction of uranium on the gallium and cadmium reactive electrodes in molten salt

  • Valeri Smolenski;Alena Novoselova
    • Nuclear Engineering and Technology
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    • v.56 no.1
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    • pp.42-47
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    • 2024
  • The electrochemical extraction of uranium in ternary low melting LiCl-KCl-CsCl eutectic on inert and reactive electrodes via different electrochemical techniques was investigated. It was established that the electrochemical reduction process of U(III) ions on the inert W electrode was irreversible and proceeded in one stage. On reactive liquid Ga and liquid Cd electrodes the reduction of uranium ions took place with the considerable depolarization with the formation of UGa2, UGa3 and UCd11 intermetallic compounds. Thermodynamic characteristics of uranium compounds and alloys were calculated. The conditions for the extraction of uranium from the electrolyte in the form of alloys on both liquid reactive electrodes via potentiostatic electrolysis were found.

Surface Study on the Supported Molten Salt Catalyst (담지된 금속염 혼합물 촉매의 표면 연구)

  • Kim, Jong Pal;Lee, Kwang Hyun
    • Applied Chemistry for Engineering
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    • v.20 no.4
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    • pp.381-385
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    • 2009
  • A basic objective is the preparation and surface studies of supported molten salt catalysts because molten salts can stay as the liquid phase in the range of the ordinary reaction temperature. Many kinds of metal salt mixtures for the formation of molten salt phase are appliable but CuCl and KCl were selected in this study because Cu is considered catalytically reactive in many reactons. The loading of the molten salt was selected as 25 vol% of the total pore volume of ${\gamma}-alumina$ to provide reasonable exposed surface area. The surface structure of catalysts containing molten salts in the ${\gamma}-alumina$ was studied using scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS). CuCl and KCl were added into the ${\gamma}-alumina$ using concentrated hydrochloric acid solution by the impregnation technique. The surfaces of the prepared catalysts before and after heat treatments were compared and they suggested that the heat treatment of catalysts helped the formation of molten-salt although the surface compositions of CuCl and KCl were not uniform.