• 제목/요약/키워드: Molecular vibration

검색결과 73건 처리시간 0.027초

에틸렌-초산비닐 공중합체의 공중합 조성이 복합체의 충격음 흡수성능에 미치는 영향 (Influence of Chemical composition of Ethylene-Vinyl Acetate Copolymers on Impact Noise Damping of Composites)

  • 이현종
    • 임산에너지
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    • 제18권2호
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    • pp.55-61
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    • 1999
  • 본 실험에서는 화학조성이 다른 일련의 에틸렌/초산비닐 공중합체의 점탄성(또는 화학조성)이 목재/고분자/목재 샌드위치 복합체의 진동·충격음 흡수성능에 미치는 영향을 검토하였다. 그 결과는 다음과 같다. 복합체의 진동·충격음 흡수성능은 고분자의 분자 운동상태에 민감하다. 즉, 복합체의 진동·충격음 흡수성능 고분자가 시험온도에 있어서 유리전이 상태일 때(대략 초산 비닐 55∼75%) 가장 크며, 고분자가 고무상태(초산비닐 47∼20%) 또는 유리상태(초산비닐 100∼87%)일 때는 작다. 또한 유리전이상태의 고분자 적층재는 약 6∼12dB의 충격음 저감효과가 있었다.

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Proteomic Changes in the Sound Vibration-Treated Arabidopsis thaliana Facilitates Defense Response during Botrytis cinerea Infection

  • Ghosh, Ritesh;Choi, Bosung;Kwon, Young Sang;Bashir, Tufail;Bae, Dong-Won;Bae, Hanhong
    • The Plant Pathology Journal
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    • 제35권6호
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    • pp.609-622
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    • 2019
  • Sound vibration (SV) treatment can trigger various molecular and physiological changes in plants. Previously, we showed that pre-exposure of Arabidopsis plants to SV boosts its defense response against Botrytis cinerea fungus. The present study was aimed to investigate the changes in the proteome states in the SV-treated Arabidopsis during disease progression. Proteomics analysis identified several upregulated proteins in the SV-infected plants (i.e., SV-treated plants carrying Botrytis infection). These upregulated proteins are involved in a plethora of biological functions, e.g., primary metabolism (i.e., glycolysis, tricarboxylic acid cycle, ATP synthesis, cysteine metabolism, and photosynthesis), redox homeostasis, and defense response. Additionally, our enzyme assays confirmed the enhanced activity of antioxidant enzymes in the SV-infected plants compared to control plants. Broadly, our results suggest that SV pre-treatment evokes a more efficient defense response in the SV-infected plants by modulating the primary metabolism and reactive oxygen species scavenging activity.

Influence of porosity and axial preload on vibration behavior of rotating FG nanobeam

  • Ehyaei, Javad;Akbarshahi, Amir;Shafiei, Navvab
    • Advances in nano research
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    • 제5권2호
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    • pp.141-169
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    • 2017
  • In this paper, a nanobeam connected to a rotating molecular hub is considered. The vibration behavior of rotating functionally graded nanobeam based on Eringen's nonlocal theory and Euler-Bernoulli beam model is investigated. Furthermore, axial preload and porosity effect is studied. It is supposed that the material attributes of the functionally graded porous nanobeam, varies continuously in the thickness direction according to the power law model considering the even distribution of porosities. Porosity at the nanoscopic length scale can affect on the rotating functionally graded nanobeams dynamics. The equations of motion and the associated boundary conditions are derived through the Hamilton's principle and generalized differential quadrature method (GDQM) is utilized to solve the equations. In this paper, the influences of some parameters such as functionally graded power (FG-index), porosity parameter, axial preload, nonlocal parameter and angular velocity on natural frequencies of rotating nanobeams with pure ceramic, pure metal and functionally graded materials are examined and some comparisons about the influence of various parameters on the natural frequencies corresponding to the simply-simply, simplyclamped, clamped-clamped boundary conditions are carried out.

Torsional vibration analysis of bi-directional FG nano-cone with arbitrary cross-section based on nonlocal strain gradient elasticity

  • Noroozi, Reza;Barati, Abbas;Kazemi, Amin;Norouzi, Saeed;Hadi, Amin
    • Advances in nano research
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    • 제8권1호
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    • pp.13-24
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    • 2020
  • In this paper, for the first time based on the nonlocal strain gradient theory the effect of size dependency in torsional vibration of bi-direction functionally graded (FG) nonlinear nano-cone is study. The material properties were assumed to vary according to the arbitrary function in radial and axial directions. The Navier equation and boundary conditions of the size-dependent bidirectional FG nonlinear nano-cone were derived by Hamilton's principle. These equations were solved by employing the generalized differential quadrature method (GDQM). The presented model can turn into the classical model if the material length scale parameters are taken to be zero. The effects of some parameters, such as inhomogeneity constant, cross-sectional area parameter and small-scale parameters, were studied. As an essential result of this study can be stated that an FG nano-cone model based on the nonlocal elasticity theory behaves softer and based on the strain gradient theory behaves harder.

딥러닝을 이용하여 진동 응답 기반 비선형 변환 접근법을 적용한 단일 랩 조인트의 접착 면적 탐지 시스템 (Adhesive Area Detection System of Single-Lap Joint Using Vibration-Response-Based Nonlinear Transformation Approach for Deep Learning)

  • 김민제;김동윤;윤길호
    • 한국전산구조공학회논문집
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    • 제36권1호
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    • pp.57-65
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    • 2023
  • 본 연구는 딥러닝을 위한 비선형 변환 접근법을 사용하여 Single-lap joint의 접착 영역을 조사하기 위한 진동 응답 기반 탐지 시스템을 제시한다. 산업 혹은 공학 분야에서 분해가 쉽지 않은 구조 내에 보이지 않는 부분의 상태와 접착된 구조의 접착 부위 상태를 알기 어려운 문제가 있다. 이러한 문제를 해결하기 위해 본 연구는 비선형 변환을 이용하여 기준 시편의 진동 응답으로 다양한 시편의 접착 면적을 조사하는 탐지 방법을 제안한다. 이 연구에서는 CNN 기반 딥러닝으로 진동 특성을 파악하기 위해 비선형 변환을 적용한 주파수 응답 함수를 사용했고 분류를 위해 가상의 스펙트로그램을 사용했다. 또한, 제시된 방법을 검증하기 위해 알루미늄, 탄소섬유복합재 그리고 초고분자량 폴리에틸렌 시편에 대한 진동 실험, 분석적 해, 유한요소해석을 수행했다.

Damping Properties and Transmlission Loss of Polyurethane. II. PU Layer and Copolymer Effect

  • Yoon, kwan-Han;Kim, Ji-Gon;Bang, Dae-Suk
    • Fibers and Polymers
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    • 제4권2호
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    • pp.49-53
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    • 2003
  • Polyurethane (PU) layer and copolymer consisted of the different molecular weights (1000 and 2000 g/mol) of poly(propylene glycol) (PPG) were prepared. The damping and mechanical properties of these materials were compared with PU 1000 made by PPG having the molecular weight of 1000 g/mol. The optimum composition of PU2000 used for PU layer and copolymer was diphenylmethane diioscynate (MDI)/propylene glycol (PPG)/butanediol (BD) (1/0.3/0.7) based on the damping and mechanical properties. The damping peak of PU copolymer was higher than those of PU layer and PUI 1000 in low temperature range (-30- $10^{\circ}C$). For application in noise reduction, the transmission loss of the mechanical vibration through solid structure was measured. PU layer and copolymer were used as a damping layer. The transmission loss of PU copolymer was more effective than those of PU layer and PU 1000 in the experimental frequency range.

수소 결합한 물 분자에서 OH 신축 진동의 국소모드와 정규모드 (Local and Normal Modes of OH Stretching Vibration in Hydrogen-Bonded Water Molecules)

  • 권세은;양민오
    • 대한화학회지
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    • 제64권6호
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    • pp.350-353
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    • 2020
  • 물 분자내의 OH 신축진동(stretching vibration) 운동을 나타내는 정규모드(normal mode)와 국소모드(local mode) 진동수들을 비교하여 수소결합한 물 분자에 대한 국소모드에 기반한 계산의 타당성을 조사하였다. 물 분자의 단량체, 이합체, 삼량체에 대한 계산을 수행하여 분자 클러스터 크기가 커짐에 따라 국소모드 진동수, 국소모드의 비조화성, 그리고 국소모드와 정규모드 진동수들의 유사성이 어떤 경향성을 보이는지 순이론적 양자화학 계산 방법으로 연구하였다. 단량체에서 삼량체로 분자의 갯수가 증가할수록 OH 결합의 비조화성은 증가하며 국소모드와 정규모드 진동수 간의 차이는 줄어드는 것으로 나타났다. 따라서, 응축상에 존재하는 물 분자들의 OH 신축 진동수의 이론적 계산은 비조화성을 쉽게 다룰 수 있는 국소모드에 기반한 방식이 적절할 수 있음을 확인하였다.

Forward and backward whirling of a spinning nanotube nano-rotor assuming gyroscopic effects

  • Ouakad, Hassen M.;Sedighi, Hamid M.;Al-Qahtani, Hussain M.
    • Advances in nano research
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    • 제8권3호
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    • pp.245-254
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    • 2020
  • This work examines the fundamental vibrational characteristics of a spinning CNT-based nano-rotor assuming a nonlocal elasticity Euler-Bernoulli beam theory. The rotary inertia, gyroscopic, and rotor mass unbalance effects are all taken into consideration in the beam model. Assuming a nonlocal theory, two coupled 6th-order partial differential equations governing the vibration of the rotating SWCNT are first derived. In order to acquire the natural frequencies and dynamic response of the nano-rotor system, the nonlinear equations of motion are numerically solved. The nano-rotor system frequency spectrum is shown to exhibit two distinct frequencies: one positive and one negative. The positive frequency is known as to represent the forward whirling mode, whereas the negative characterizes the backward mode. First, the results obtained within the framework of this numerical study are compared with few existing data (i.e., molecular dynamics) and showed an overall acceptable agreement. Then, a thorough and detailed parametric study is carried out to study the effect of several parameters on the nano-rotor frequencies such as: the nanotube radius, the input angular velocity and the small scale parameters. It is shown that the vibration characteristics of a spinning SWCNT are significantly influenced when these parameters are changed.

Free vibrations analysis of arbitrary three-dimensionally FGM nanoplates

  • Dehshahri, Kasra;Nejad, Mohammad Zamani;Ziaee, Sima;Niknejad, Abbas;Hadi, Amin
    • Advances in nano research
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    • 제8권2호
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    • pp.115-134
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    • 2020
  • In this paper, the free vibrations analysis of the nanoplates made of three-directional functionally graded material (TDFGM) with small scale effects is presented. To study the small-scale effects on natural frequency, modified strain gradient theory (MSGT) has been used. Material properties of the nanoplate follow an arbitrary function that changes in three directions along the length, width and thickness of the plate. The equilibrium equations and boundary conditions of nanoplate are obtained using the Hamilton's principle. The generalized differential quadrature method (GDQM) is used to solve the governing equations and different boundary conditions for obtaining the natural frequency of nanoplate made of three-directional functionally graded material. The present model can be transformed into a couple stress plate model or a classic plate model if two or all parameters of the length scales set to zero. Finally, numerical results are presented to study the small-scale effect and heterogeneity constants and the aspect ratio with different boundary conditions on the free vibrations of nanoplates. To the best of the researchers' knowledge, in the literature, there is no study carried out into MSGT for free vibration analysis of FGM nanoplate with arbitrary functions.

Bonding And Anti-bonding Nature of Magnetic Semiconductor Thin Film of Fe(TCNQ:tetracyanoquinodimethane)

  • Jo, Junhyeon;Jin, Mi-jin;Park, Jungmin;Modepalli, Vijayakumar;Yoo, Jung-Woo
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.294-294
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    • 2014
  • Developing magnetic thin films with desirable physical properties is a key step to promote research in spintronics. Organic-based magnetic material is a relatively new kind of materials which has magnetic properties in a molecular and microscopic level. These materials have been constructed by the coordination between 3d transition metal and organic materials producing long-range magnetic orders with a relatively high transition temperature. However, these materials were mostly synthesized as a form of powder, which is difficult to study for their physical properties as well as apply for electronic/spintronic devices. In this study, we have employed physical vapor deposition (PVD) to develop a new organic-based hybrid magnetic film that is achieved by the coordination of Fe and tetracyanoquinodimethane (TCNQ). The IR spectra of the grown film show modified CN vibration modes in TCNQ, which suggest a strong bonding between Fe and TCNQ. The thin film has both ferromagnetic and semiconducting behaviors, which is suitable for molecular spintronic applications. The high resolution photoemission (HRPES) spectra also show shift of 1s peak point of nitrogen and the carbon 1s peaks display traces of charge transfer from Fe to TCNQ as well as shake-up features, which suggest strong bonding and anti-bonding nature of coordination between Fe and TCNQ.

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