• Journal of Magnetics
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• v.18 no.1
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• pp.21-25
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• 2013

Nickel substituted manganese ferrites, $Mn_{1-x}Ni_xFe_2O_4$ ($0.0{\leq}x{\leq}0.6$), were fabricated by sol-gel method. The effects of sintering and substitution on their crystallographic and magnetic properties were studied. X-ray diffractometry of $Mn_{0.6}Ni_{0.4}Fe_2O_4$ ferrite sintered above 523 K indicated a spinel structure; particles increased in size with hotter sintering. The M$\ddot{o}$ssbauer spectrum of this ferrite sintered at 523 K could be fitted as a single quadrupole doublet, indicative of a superparamagnetic phase. Sintering at 573 K led to spectrum fitted as the superposition of two Zeeman sextets and a single quadrupole doublet, indicating both ferrimagnetic and paramagnetic phase. Sintering at 673 K and at 773 K led to spectra fitted as two Zeeman sextets due to a ferrimagnetic phase. The saturation magnetization and the coercivity of $Mn_{0.6}Ni_{0.4}Fe_2O_4$ ferrite sintered at 773 K were 53.05 emu/g and 142.08 Oe. In $Mn_{1-x}Ni_xFe_2O_4$ ($0.0{\leq}x{\leq}0.6$) ferrites, sintering of any composition at 773 K led to a single spinel structure. Increased Ni substitution decreased the ferrites' lattice constants and increased their particle sizes. The M$\ddot{o}$ssbauer spectra could be fitted as the superposition of two Zeeman sextets due to the tetrahedral and the octahedral sites of the $Fe^{3+}$ ions. The variations of saturation magnetization and coercivity with changing Ni content could be explained using the changes of particle size.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.2 no.1
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• pp.10-19
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• 1992

Mn - Zn Ferrite has physical properties of the high initial permeability, saturation magnetic flux density, and low loss factor as a representative magnetic material of soft ferrites, in addition the mechanical property is excellent as a single crystal. Therefore it is important electronic components and used for VTR Head. Mn - Zn Ferrite single crystals with the diameter 8mm were grown in atmosphere mixed with $O_2$ and Ar gas by the Floating Zone(FZ) method that impurities can not be incorporated to the crystals because of not-using the crucible to put in the melt, and the sharp temperature gradient results from making a focus at one point utilizing the infrared ray emitted from the halogen lamp as a heat source. During the crystal growing, the highest temperature of melting area was maintained to be $1650^{\circ}C$, growth rate and rotation rate were 10 mm/hr, 20 rpm respectively. The phases and the growth directions of crystals were determined from the analysis of X RD patterns, Laue, TEM diffraction patterns and etch pit shapes were observed by the optical microscope through the chemical etching. The corelation of optimum conditions for acquiring the better crystals was found out with the growth rate, the length and diameter of melt at the interface according to the diameter of feed rod, and the patterns of growing interface also studied.

• Journal of Magnetics
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• v.18 no.1
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• pp.26-29
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• 2013

$Mn_xFe_{3-x}O_4$ powders have been fabricated by using sol-gel methods; their crystallographic and magnetic properties were investigated by using X-ray diffraction, scanning electron microscopy, M$\ddot{o}$ssbauer spectroscopy, and vibrating sample magnetometer. The $Mn_xFe_{3-x}O_4$ ferrite powders annealed at $500^{\circ}C$ had a single spinel structure regardless of the $Mn^{2+}$-doping amount and their lattice constants became larger as the $Mn^{2+}$ concentration was increased. Their Mossbauer spectra measured at room temperature were fitted with 2 Zeeman sextets due to the tetrahedral and octahedral sites of Fe ions, which made them ferrimagnetic. The magnetic behavior of $Mn_xFe_{3-x}O_4$ powders showed that the $Mn^{2+}$-doping amount made their saturation magnetization increase, but there were no severe effects on their coercivities. The saturation magnetization of the $Mn_xFe_{3-x}O_4$ powder varied from 38 emu/g to 70.0 emu/g and their minimum coercivity was 111.1 Oe.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.07a
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• pp.905-908
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• 2001

The microstructure and the magnetic properties of Mn-Zn ferrite, which were power loss and saturation magnetic flux density, were investigated as the function of the process before firing. The highest initial permeability and the lowest power loss were attained to the specimen with CaO 400 ppm as a resulted from the highest solubility to SiO$_2$and the creation of liquid phase which improved sintering. The biggest grain size, the highest saturation magnetic flux density and the lowest power loss, which was resulted from that the eddy current loss increased as grain size increased but the hysteresis loss much more decreased and the hysteresis loss strongly influenced on the total power loss rather than the eddy current loss, were obtained to the Mn-Zn ferrite added 2wt% PVA. The power loss was lowest and the saturation magnetic flux density was highest in case of 1 ton/$\textrm{cm}^2$ and the grain size was not influenced.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2001.10a
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• pp.652-655
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• 2001

Power transformers are increasingly becoming more significant in the advancement of electronic equipment. A high-performance, low-cost core material is necessary in order th come up with power transformers in the smallest and lightest scale possible and with low power requirements. In this study, we added V$_2$O$_{5}$ and CaCo$_3$to Mn-Zn ferrite to produce a high-performance low-cost core material. The compositions used were MnO : ZnO : Fe$_2$O$_3$= 37 : 11 : 52 mol%. The materials were sintered at 125$0^{\circ}C$ for three hours. Initial permeability was measured at 0.1MHz. At 200mT, power loss was measured by changing the temperature at 25KHz, 50KHz, 100KHz. When we added 0.lwt% and 0.1%wt% of V$_2$O$_{5}$와 CaCo$_3$, respectively we obtained 405 405KW/㎥ at 200mT, 100KHz, 6$0^{\circ}C$. We tan reduce eddy current loss as a primary loss of high frequency by adding a small amount of V$_2$O$_{5}$와 CaCo$_3$. This reduces power loss in the power transformersormers

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.07b
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• pp.1168-1171
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• 2003

In contrast to a conventional transformer, the flat transformer is made using a number of small ferrite cores. Two cores for transformer and one core for inductor, which composed one module. Many modules can be connected together to form a flat matrix transformer. This structural arrangement eliminates the single hot spot problem in conventional transformers and permits high current density pertains at high frequency. In this study, the ferrite magnetic cores of Mn-Zn system for the Flat transformer were manufactured and the electrical and magnetic characteristics of its tested. The power loss of sample FO2(Mn-Zn ferrite) sintered at $1350^{\circ}C$ was $350kW/m^3$ in test conditions of 250kHz, 200mT and $100^{\circ}C$, which showed the good power loss property in high frequency. The power loss of FO2 samples has been studied as a function of magnetic flux density and frequency. Steinmetz exponent was 2.82 at 250kHz and 2.73 at 500kHz. These results illustrated the switching of power loss mechanism in ferrite core from hysteresis losses to eddy current losses or others.

• Journal of the Korean Society for Heat Treatment
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• v.10 no.2
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• pp.109-120
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• 1997

Microstructure and mechanical properties of Fe-Si-Mn-P high strength steel sheet have been investigated by controlling the cooling rate. Bainite and ferrite were obtatined by annealing in the ferrite pluse austenite region, and ferrite and austenite were obtatined after annealing in the fully austenite region. Ferrite and pearlite were obtained when the cooling rate was controlled from the annealing temperature above $760^{\circ}C$ and bainite showed with increasing cooling rate, however below $760^{\circ}C$ ferrite and bainite were obtained. Tensile strengths and hardness nearly unchanged with increasing cooling rate after control the cooling rate from the temperature above $760^{\circ}C$, while tensile strengths increased and elongation decreased with increasing cooling rate when the cooling rate was controlled from the tempeature below $760^{\circ}C$. Without regard to annealing temperature, tensile strength increased and elongation decreased with increasing cooling rate. Tensile strengths and elongation values heat treated in the ferrite plus austenite region were higher than those in the fully austenite region. Retained austenite and strength-elongation balance showed the maximum value at $780^{\circ}C$ and decreased with increasing annealing temperature. Strength-elongation balance value was controlled by the retained austenite.

• Proceedings of the Materials Research Society of Korea Conference
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• 2005.05a
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• pp.158-158
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• 2005

• Korean Journal of Materials Research
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• v.1 no.4
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• pp.221-228
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• 1991

In this study we have investigated the sealing characteristics of glasses suitable for producing the magnetic gap of the ferrite head cores which have been widely used for VTR and computer magnetic heads. $PbO-B_2O_3$ g1asses were evaluated by measuring microhardness, thermal expansion coefficient and sliding wear resistance. Concentration distribution of elements at the interface was observed by WDS. wettability was measured by high temperature microscopy. The results were as follows ; 1. In sealing glasses of $PbO-B_2O_3$ system, thermal expansion coefficient and wear volume were increased with increasing PbO content, and were decreased with increasing $B_2O_3$ content. 2. The contact angle of $PbO-B_2O_3$ Systems was mainly influenced by PbO content. 3. The sealing temperature showed a tendency to decrease proportionally with the increase of the coefficient of thermal expansion. 4. The diffusion at the interface between Mn-Zn single crystal ferrite and sealing glasses of $PbO-B_2O_3$ system was dominated by small amount of diffusion of ferrite content into glass part, which was very little affected by sealing heat treatment time.

• Journal of the Korean Ceramic Society
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• v.34 no.3
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• pp.289-295
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• 1997

Effect of ceramic processing was investigated on the microstructure and electronic properties of low loss Mn-Zn ferrite. Addition of CaO and SiO2 to calcined powder rather than to raw materials mixtured resulted in finer-grained microstructure. Higher oxygen pressure during sintering caused microstructural inhomogeneity and the increase in power loss and disaccommodation factor. Relatively low power loss was found for sintering up to 130$0^{\circ}C$ from powders calcined at high temperature and milled shortly. It was caused by slow densification rate and normal grain growth up to 130$0^{\circ}C$. Calcination at low temperature and prolonged milling enhanced den-sification, which gave a fine grained microstructure and low powder loss at sintering temperture below 120$0^{\circ}C$. Sintering temperature above 125$0^{\circ}C$, however, showed abnormal grain growth.