• Macromolecular Research
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• v.16 no.5
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• pp.424-428
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• 2008

We prepared an ionic gel polymer electrolyte for dye-sensitized solar cells (DSSCs) without leakage problem. Triiodide compound (BTDI) was synthesized by the reaction of benzene tricarbonyl trichloride with diethylene glycol monotosylate and subsequent substitution of tosylate by iodide using NaI. Bisimidazole was prepared by the reaction of imidazole with the triethylene glycol ditosylate under strongly basic condition provided by NaH. BTDI and bisimidazole dissolved in an ionic liquid were injected into the cells and permeated into the $TiO_2$ nanopores. In situ crosslinking was then carried out by heating to form a network structure of poly(imidazolium iodide), thereby converting the ionic liquid electrolytes to a gel or a quasi-solid state. A monomer (BTDI and bisimidazole) concentration in the electrolytes of as low as 30 wt% was sufficient to form a stable gel type electrolyte. The DSSCs based on the gel polymer electrolytes showed a power conversion efficiency of as high as 1.15% with a short circuit current density of $5.69\;mAcm^{-2}$, an open circuit voltage of 0.525 V, and a fill factor of 0.43.

• Current Photovoltaic Research
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• v.2 no.3
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• pp.124-129
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• 2014

Dye-sensitized solar cells (DSSCs) are considered as promising alternatives to conventional photovoltaic device. However, commercialization of the DSSCs is restricted due to the low efficiency. In this paper, highly efficiency DSSCs were fabricated by the adding the TBA to the $TiO_2$ paste. $TiO_2$ photoanode added 0.2 M TBA in DSSCs are shown the best efficiency of 9.14 %. This result ascribed to improvement of the connection between the $TiO_2$ nanoparticles by the addition of the optimized amount TBA. The morphology of the photoanode was observed by FE-SEM. Further investigation about the kinetics of the electrochemical processes are performed by the EIS analysis. Longest diffusion length was obtained in case adding 0.2 M of TBA to $TiO_2$ paste, which was matched well with the improved efficiency.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.58 no.11
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• pp.2214-2218
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• 2009

Dye-sensitized solar cell (DSC) has been considered as a possible alternative to current silicon based p-n junction photovoltaic devices due to its advantages of high efficiency, simple fabrication process and low production cost. Numerous researches for high efficient DSC in the various fields are under way even now. Among them, the compact layer, which prevents the back electron transfer between transparent conductive oxides and the redox electrolyte, is fabricated by various methods such as a ZnO dip-coating, $TiCl_4$ dip-coating, and Ti sputtering. In this study, we tried to fabricate the $TiO_2$ compact layer by the spin-coating method using aqueous $TiCl_4$ solution. The effect of the spin-coating method was checked as compared with conventional dip-coating method. As a result, DSC with a spin-coated compact layer had 33.4% and 6% better efficiency than standard DSC and DSC with a dip-coated compact layer.

• Membrane and Water Treatment
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• v.15 no.1
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• pp.41-50
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• 2024

Presence of hazardous dyes in water cause considerable risks to the human health and environment due to their potential toxicity and ecological disruptions. Therefore, in the present research, to suggest an alternative method for the retention of toxic Azocarmine G (ACG) dye from aqueous media, natural and H₂SO₄-modified acacia sawdust were performed for the first time as low-cost and efficient adsorbents. Based on batch experiments, it was determined that the best conditions for the developed dye retention process were an initial pH of 2.0 and an equilibrium time of 240 min. Analysis of the data using both pseudo-first order and pseudo-second order kinetic models showed that the retention of ACG onto the adsorbents predominantly occurred through chemical adsorption. Langmuir, Freundlich, and Dubinin-Radushkevich isotherm models were employed to provide insights into the interaction between the adsorbate and adsorbent and the mechanism of the adsorption process. Maximum monolayer adsorption capacities of natural and H₂SO₄-modified acacia sawdust were determined as 28.01 and 64.90 mg g^-1, respectively by Langmuir isotherm model. Results of the study clearly indicated that the modification of acacia sawdust with H₂SO₄ leads to a substantial increase in the adsorption performance of anionic dyes.

• Journal of the Korean Ceramic Society
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• v.48 no.1
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• pp.94-98
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• 2011

A Sn-doped $In_2O_3$ (ITO) nanowire photoelectrode was produced using a simple metal evaporation method at low synthesis temperature (< $540^{\circ}C$). The nanowire electrodes have large surface area compared with that of flat ITO thin film, and show low electrical resistivity of $5.6{\times}10^{-3}{\Omega}cm$ at room temperature. In order to apply ITO nanowires to the photoelectrodes of dye-sensitized solar cell (DSSC), those surfaces were modified by $TiO_2$ nanoparticles using a chemical bath deposition (CBD) method. The conversion efficiency of the fabricated $TiO_2$/ITO nanostructure-based DSSC was obtained at 1.4%, which was increased value by a factor of 6 than one without ITO nanowires photoelectrode. This result is attributed to the large surface area and superior electrical property of the ITO nanowires photoelectrode, as well as the structural advantages, including short diffusion length of photo-induced electrons, of the fabricated $TiO_2$/ITO nanostructure-based DSSC.

• Journal of Powder Materials
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• v.23 no.2
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• pp.95-101
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• 2016

Carbon nanofiber (CNF) composites coated with spindle-shaped $Fe_2O_3$ nanoparticles (NPs) are fabricated by a combination of an electrospinning method and a hydrothermal method, and their morphological, structural, and chemical properties are measured by field-emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. For comparison, CNFs and spindle-shaped $Fe_2O_3$ NPs are prepared by either an electrospinning method or a hydrothermal method, respectively. Dye-sensitized solar cells (DSSCs) fabricated with the composites exhibit enhanced open circuit voltage (0.70 V), short-circuit current density ($12.82mA/cm^2$), fill factor (61.30%), and power conversion efficiency (5.52%) compared to those of the CNFs (0.66 V, $11.61mA/cm^2$, 51.96%, and 3.97%) and spindle-shaped $Fe_2O_3$ NPs (0.67 V, $11.45mA/cm^2$, 50.17%, and 3.86%). This performance improvement can be attributed to a synergistic effect of a superb catalytic reaction of spindle-shaped $Fe_2O_3$ NPs and efficient charge transfer relative to the one-dimensional nanostructure of the CNFs. Therefore, spindle-shaped $Fe_2O_3$-NP-coated CNF composites may be proposed as a potential alternative material for low-cost counter electrodes in DSSCs.

• Journal of the Korean Society of Clothing and Textiles
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• v.28 no.6
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• pp.795-806
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• 2004

Unripe indigenous persimmons which contain rich tannins have been used as natural dye materials traditionally and have been using continuously for dyed clothes named Gal-ot in Jeju. Those persimmons were cheap and easy to use as dyes because of inedible and widely cultured in Korea. Persimmon juice dyes not only make fabrics brown-color but also give functional and hygienic properities such as stiffness, air ventilation of clothes, antibacterial activity, protectivity against ultraviolet light. However there are several serious problems which are ristriction of dyeing periods, longtime irradiation, uneven color and low color fastness etc. in persimmon juice dyeing. This study purpose to improve dye effect and method in order to enlarge useability of persimmon juice dyeing. Cotton fabrics were pad-dyed to 100% pick-up using padding machine after dipping in persimmon juice extracted from unripe persimmons indigenous from Jeju. It was possible and available to control pick-up rate. The color of dyed cotton fabrics by padding method was more even and repeatable than which by traditional hand method. Persimmon juice concentrations were 4 types of 10, 25, 50 and 100％. The more concentration increased, the more color deepened. UV Irradiation instead of sunlight was applied to color developing. Irradiation times were shortened till 1∼8 hrs. Same color values could be taken without water wetting which were required in sunlight irradiation. Tensile strengths of cotton fabrics pad-dyed with low concentration of persimmon juice decreased but recovered at high concentrations. Elongations(％) of cotton fabrics pad-dyed with persimmon juice were increased 1％ more than undyed cotton in sunlight irradiation. Drape stiffness increased upto double times as much as.

• Textile Coloration and Finishing
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• v.21 no.3
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• pp.37-42
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• 2009

The low melting PET yarn has sheath/core structure: sheath portion consists of low melting point PET and core portion is regular PET. Dyeing properties of fabric made from low melting PET yarn were investigated at different dyeing temperatures. It was found that the exhaustion yield on the low melting PET fabric was higher than on regular PET fabric. The total K/S value of the dyed low melting PET fabric increased as heat setting temperature increased above $150^{\circ}C$ because the sheath portion of the low melting yarn melted. Although fastness to light of the low melting PET fabric was similar to regular PET fabric, fastness to washing was inferior to regular PET fabric by 1 grade.

• Journal of Sericultural and Entomological Science
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• v.40 no.2
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• pp.136-142
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• 1998

The low-pollution dyeing condition and dyeing method suitable for the silk fiber were investigated. Instead of surfactants, water-soluble polymers and electrolytes were added as auxiliary agents in the new process of dyeing. By the new method, the level dyeing and sufficient exhaustion were achieved. The K/S values of silk fabrics were little different among electrolytes added in the dye-bath.

• Korean Chemical Engineering Research
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• v.53 no.5
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• pp.576-583
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• 2015

This paper aims to investigate the potential use of cempedak durian peel (CDP) from Negara Brunei Darussalam, which is low-cost, locally available, eco-friendly and highly efficient to remove methyl violet (MV) dye from aqueous solutions. The time required for equilibrium to be reached is 2.0 h with no adjustment of pH necessary. FTIR analysis was indicative of the involvement of -COOH and C=O functional groups in adsorption process. The Langmuir model provided the best fit with maximum adsorption capacity of $0.606mmol\;g^{-1}$. Thermodynamics data indicate that the adsorption is spontaneous, feasible and endothermic in nature. Best regeneration of CDP's adsorption ability is achieved by base solution, showing about 95% removal efficiency of MV even after 5 cycles, indicating that CDP can be regenerated and reused. This, together with its high adsorption capacity, makes CDP a potential adsorbent for the removal of MV in wastewater.