A Study on the Improvement of the Interface Contact and the Prevention of the Charge Recombination by the Surface Treatment of Transparent Conductive Oxide in Dye-sensitized Solar Cell

염료감응형 태양전지 투명전도성 막의 표면처리를 통한 계면 접촉 향상 및 재결합 방지 연구

  • 서현웅 (부산대학 전자전기공학과) ;
  • 홍지태 (부산대학 전자전기공학과) ;
  • 손민규 (부산대학 전자전기공학과) ;
  • 김진경 (부산대학 전자전기공학과) ;
  • 신인영 (부산대학 전자전기공학과) ;
  • 김희제 (부산대학 전자전기공학과)
  • Published : 2009.11.01

Abstract

Dye-sensitized solar cell (DSC) has been considered as a possible alternative to current silicon based p-n junction photovoltaic devices due to its advantages of high efficiency, simple fabrication process and low production cost. Numerous researches for high efficient DSC in the various fields are under way even now. Among them, the compact layer, which prevents the back electron transfer between transparent conductive oxides and the redox electrolyte, is fabricated by various methods such as a ZnO dip-coating, $TiCl_4$ dip-coating, and Ti sputtering. In this study, we tried to fabricate the $TiO_2$ compact layer by the spin-coating method using aqueous $TiCl_4$ solution. The effect of the spin-coating method was checked as compared with conventional dip-coating method. As a result, DSC with a spin-coated compact layer had 33.4% and 6% better efficiency than standard DSC and DSC with a dip-coated compact layer.

Keywords

References

  1. Franc Smole, Marko Topic, JoZe Furlan, 'Analysis of TCO/p(a-Si:C:H) heterojunction and its influence on p-i-n a-Si:H solar cell performance', Journal of Non-Crystalline Solids, Vol. 194, pp. 312-318, 1996 https://doi.org/10.1016/0022-3093(95)00512-9
  2. B. O'Regan, M. Gratzel, 'Optical electrochemistry steady-state spec troscopy of conduction band electrons in a metal oxide semiconductor electrode', Chemical Physics Letters, Vol. 183, pp. 89-93, 1991 https://doi.org/10.1016/0009-2614(91)85104-5
  3. E. Ahmed, A. Zegadi, A.E. Hill, R.D. Pilkington, R.D. Tomlinson, A.A. Dost, W. Ahmed, S. Lepphvuori, J. Levoska, O. Kusmartseva, 'Impact of annealing processes on the properties of $Culn_{0.75}Ga_{0.2}5Se_2$ thin films', Solar Energy Materials and Solar Cells, Vol. 36, pp. 227-239, 1995 https://doi.org/10.1016/0927-0248(94)00175-8
  4. Michael Gratzel, 'Dye-sensitized solar cells', J. Photochem. Photobio. C: Photochem. Rev., Vol. 4, pp. 145, 2003 https://doi.org/10.1016/S1389-5567(03)00026-1
  5. M. Durr, A. Schmid, M. Obermaier, S. Rosselli, A. Yasuda, G. Nelles, 'Low-temperature fabrication of dye-sensitized solar cells by transfer of composite porous layers', Nature, Vol. 4, pp. 607, 2005 https://doi.org/10.1038/nmat1433
  6. M. Gratzel, 'A photovoltaic device structure based on internal electron emission', Nature, Vol. 421, pp. 6923, 2003 https://doi.org/10.1038/nature01316
  7. Hyunwoong Seo, Min-Kyu Son, Kyoung-Jun Lee, Jeonghoon Kim, Ji-Tae Hong, Hee-Je Kim, 'A Study on the Improvement of the Efficiency of Dye-sensitized Solar Cell using the Laser Scribing and the Grid Electrode', Trans. KIEE., Vol. 58, No. 1, pp. 1802, 2008
  8. B. O' Regan, M. Gratzel, 'A low-cost, high-efficiency solar cell based on dye-sensitized colloidal $TiO_2$ films', Nature, Vol. 353, pp. 737, 1991 https://doi.org/10.1038/353737a0
  9. Daniel J.V. Pulsipher, Ellen R. Fisher, '$O_2$ plasma treatment of mesoporous and compact $TiO_2$ photovoltaic films: Revealing and eliminating effects of Si incorporation', Surface & Coatings Technology, Vol. 203, pp. 2236, 2009 https://doi.org/10.1016/j.surfcoat.2009.02.014
  10. Bhagwat N. Pawar, Gangeri Cai, Dukho Hama, Rajaram S. Mane, T. Ganesh, Anil Ghule, Ramphal Sharma, K.D. Jadhava, Sung-Hwan Han, 'Preparation of transparent and conducting boron-doped ZnO electrode for its application in dye-sensitized solar cells', Solar Energy Materials & Solar Cells, Vol. 93, pp. 524, 2009 https://doi.org/10.1016/j.solmat.2008.12.010
  11. U.Opara Krasovec, M. Berginc, M. Hocevar, M. Topic, 'Unique $TiO_2$ paste for high efficiency dye-sensitized solar cells', Solar Energy Materials & Solar Cells, Vol. 93, pp. 379, 2009 https://doi.org/10.1016/j.solmat.2008.11.012
  12. Hua Yu, Shanqing Zhang, Huijun Zhao, Geoffrey Will, Porun Liu, 'An efficient and low-cost $TiO_2$ compact layer for performance improvement of dye-sensitized solar cells:, Electrochimica Acta, Vol. 54, pp. 1319, 2009 https://doi.org/10.1016/j.electacta.2008.09.025
  13. Jifu Shi, Jing Liang, Shengjie Peng, Wei Xu, Juan Pei, Jun Chen, 'Synthesis, characterization and electrochemical properties of a compact titanium dioxide layer', Solid State Sciences, Vol. 11, pp. 433, 2009 https://doi.org/10.1016/j.solidstatesciences.2008.06.010