• 신재생에너지
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• 제19권4호
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• pp.2-10
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• 2023

The current mandatory domestic biodiesel blending ratio is 3.5%, which is planned to be gradually increased to achieve carbon neutrality by 2050. The aim of this study was to improve domestic self-sufficiency in biodiesel raw oil by conducting a technical review on the possibility of utilizing waste oils, such as soup oil, chicken oil, and leather oil, as biodiesel feedstocks. These waste oils have an acid value that is too high to be converted directly into biodiesel. Therefore, a pretreatment to reduce the acid value is necessary. The neutralization process was examined as a potential technology for reducing the acid value. The oil recovery rate of the soup oil after neutralization was significantly low at 37.6 wt%. The oil recovery rates of leather oil and chicken oil were 66.49 wt% and 79.08 wt%, respectively. Based on biodiesel conversion experiment using waste oil with a reduced acid value, the conversions were analyzed as 89 wt%, 91.1 wt%, and 90.5 wt% for soup oil, leather oil, and chicken oil, respectively. Thus, it is technically possible to use soup oil, leather oil, and chicken oil as raw materials for producing biodiesel.

• 한국염색가공학회지
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• 제18권6호
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• pp.31-36
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• 2006

Study has been made for producing anionic surfactant using waste fleshing scraps from the leather making process through refining, esterification, sulfonation and blending processes. As a most optimum lard oil refining method, refining was carried out for 4 hours under temperature of $120^{\circ}C$ and approximately 200 mbar vacuum, which gave a recovery of more than 80% lard oil. Refined lard oil obtained thus was undergone methlyl-esterification, then sulfonated to make a degreasing agent. By methyl-esterification using lard oil, more than 85% of fatty acid and $12{\sim}13%$ of glycerine were extracted from the oil. Sulfonation of the extracted fatty acid ester lard oil has shown most optimum at $15{\sim}20%$ chlorosulfonic acid content, and the content of bonding sulfate at this time was higher than 3.5%. Finally the followed anionic surfactant having degreasing force of 80% and higher could be made by blending process.

• 유기물자원화
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• 제10권3호
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• pp.98-109
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• 2002

피혁 제조 공정에서 발생되는 각종 피혁 가공 폐기물의 발생율은 원료피 기준 거의 50% 이상이며 배출되는 피혁 가공 폐기물들은 50% 이상의 수분을 함유한 동물성 유지 및 섬유상 단백질로 구성되어 있어 귀중한 유지 및 단백질 자원임에도 불구하고 다른 용도로의 재활용 적용 없이 대부분 산업 폐기물로 소각하거나 단순 매립 처리하고 있다. 이로 인해 이들 피혁 가공 폐기물에 의한 환경오염 문제가 날로 심각해져 가고 있는 실정이며 피혁 가공 폐기물에 대한 과다한 처리비용(4만원~6만원/Ton)으로 생산 원가 측면에서도 큰 부담이 되고 있다. 더욱이 Fleshing scrap, Pelt scrap과 같은 유기성 폐기물의 경우는 부패성이 높아 적절하게 처리되지 않고 불법투기될 경우에 발생하는 악취, 오수 누출 등에 의한 2차 오염이 발생됨으로 이러한 문제점을 해결하고자 재자원화 실험을 실시하여 유지 및 단백질의 재회수 기술 개발과 이를 이용한 재 자원화 기술 개발로 피혁 처리용 약품을 제조하였다.

• 대한가정학회지
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• 제11권4호
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• pp.363-373
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• 1973

The Sewability was tested with the seam strength and Puckering Grade by a general sewing machine according to some properties of simulated Leather, yarn tensile strength needle and stitches. The main results tested are as follows ; 1. The thick and uncomfortable leather is unable to be sewed by a general sewing machine, but the thin and soft one is able to. 2. The interval between stitches depends on type of leather used, and the variance in accordance with type of leather varies much more in the case of narrower interval. 3. When the sewability of leather-surface is not so good, is desirable to pour oil on the surface for the purpose of better efficiency. 4. The seam strength is directly proportional to interval of stitch and tensile strength of yarn and leather used, and needle No. 14 is more effective than No.1l. 5. The more the soft and thin leather is, the lower the Puckering Grade becomes. Type of yarn and interval of stitches do not seem to effect the Puckering Grade.

• 패션비즈니스
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• 제20권4호
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• pp.88-95
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• 2016

This paper investigated to the effectiveness of an eco-friendly method for oiling cow leather. After leather was lac-dyed with a vegetable leather processing solution and a mordant, olive oil was used to treat the leather. Changes in surface color and dyeability, light fastness, rubbing fastness, and water fastness were measured. An increase in dyeability caused by the mordant appeared in all the samples. The dyeability of leatger treated with Cu-mordant was higher than that treated with Fe-mordant and Al-mordant, and the three times greater than when no mordant was used. Dyeability after oiling more than doubled compare with before oiling. An increase in dyeability by oiling was highe greater than doubled compared with before oiling. The non-mordant-treated samples exhibited a 5-fold increase in dyeability, and the other samples showed more than two times more dyeability than did non-oiled samples. A color difference of more than 20.0-fold appeared in all samples, and the differences in lightness and chroma were greater than were the differences in other color factors. The colors after oiling were measured R, P, and PB. Light fastness improved in all samples after oiling, and all of the measurements were reduced in the order of Fe-mordant> Cu-mordant> Al-mordant ${\geq}$non mordant.

• Elastomers and Composites
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• 제57권4호
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• pp.129-137
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• 2022

Low molecular weight liquid butadiene rubber (LqBR) is a processing aid that can resolve the migration problem of tire tread compounds. Various studies are being conducted to replace the petroleum-based processing oil with LqBR. However, the effect of the loading time of LqBR in the compounding process on silica dispersion and vulcanizate properties is not well known. In this study, we analyzed silica dispersion, vulcanizate properties, and viscoelastic properties of silica-filled tire tread compound according to the processing aid type (TDAE oil, non-functional LqBR) and, silane terminated LqBR) and input timing. In the non-functional LqBR compounds, the 'with TESPT' mixing procedure showed excellent dynamic viscoelastic properties while silane-terminated LqBR compounds showed that the 'after TESPT' mixing procedure was good for 300% modulus and abrasion resistance.

• 접착 및 계면
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• 제23권2호
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• pp.33-38
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• 2022

본 연구에서는bio polyol 함량에 따라 bio polyol based 친환경 수분산 폴리우레탄을 합성하고 그 특성을 알아보고자 하였다. Polyester polyol(DT-1040)과 castor oil based polyol(COP)의 비율에 따른 bio polyol based 수분산 폴리우레탄을 성공적으로 합성한 것을 확인할 수 있었다. 합성된 bio polyol based 수분산 폴리우레탄의 Tg는 -70 ℃와 -30 ℃ 부근에서 나타났으며, COP의 함량이 증가할수록 유리전이온도 구간이 넓어지는 것을 확인할 수 있었다. 또한, COP의 함량이 증가할수록 인장강도는 감소하였고, 접착력은 DT-1040:COP=7:3일 때 최고값을 나타내었다.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2008년도 제38차 학술발표대회
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• pp.111-113
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• 2008

In this study, for natural leather use, the phytoncide oil of antibacterial materials was encapsulated in several micro-diameter shell which slowly releases from the leather treated with antibacterial microcapsules. The microcapsule was synthesized by in-situ polymerization of urea and formaldehyde. The effects of surfactants on the average particle size and distributions, morphologies and antibiosis were investigated to design microcapsule.

• 한국응용과학기술학회지
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• 제39권6호
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• pp.924-931
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• 2022

Undenatured castor oil and trimethylolpropane (TMP) were used to obtain bio-based water-based polyurethane. Isophorone diisocyanate (IPDI) was incorporated into the formulation to obtain a transparent film, and ethylenediamine (EDA) was used for chain extension. In order to measure the change in physical properties according to the contents of castor oil and TMP, each tensile strength, elongation, and abrasion resistance test was conducted. As the contents of castor oil and TMP increased, the tensile strength increased, the elongation decreased, and the surface hardened strongly as the respective contents increased.

• 복식
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• 제58권8호
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• pp.63-73
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• 2008

From the ancient Korea to the late Joseon Korean fur and leather had been preferred in and out of Korea for their good quality and excellent manufacturing skill. Since Unified Silla (A.D.676${\sim}$A.D.936) Korean fur and leather were manufactured divisionally by workmen specialized in materials and products, and such manufacturing process was succeeded to Goryeo and Joseon. Manufacturing of fur and leather was consisted of as follows: hunting and butchering - peeling - beating with a paddle and removing fat - oil manufacturing - drying - tanning, then cutting and sewing, and there was a special caring method. In order to make good fur and leather, each process of manufacturing needed particular techniques and all available methods were tried to have tender fur and leather by using smoking, excrement, lime, vegetable tannin and even cerebral liquid. And also required mouth-chewing and hand-pounding with a lot of time and of labor Keeping furs resilience and flexibility, sowing several skins together, even when the after-all-process skin was converted into clothes, was much more difficult than sewing fabric. Thus, the manufacturing cost was as much expensive as skin materials, and the volume of manufacturing of fur and leather was also limited. Therefore, fur and leather must have been popular for scarcity value in the manufacturing process, and this scarcity must have caused an extreme luxury of fur.