Journal of the Korean Applied Science and Technology (한국응용과학기술학회지)

The Korean Society of Applied Science and Technology (한국응용과학기술학회)
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Manufacture of Water-borne Biopolyurethane Film Based on Caster Oil and Tri Methylol Propane for Leather Coationg

  • Lee Joo-Youb (Department of fire and Disaster Prevention , Jungwon University)
  • Received : 2022.11.29
  • Accepted : 2022.12.26
  • Published : 2022.12.30
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Abstract

Undenatured castor oil and trimethylolpropane (TMP) were used to obtain bio-based water-based polyurethane. Isophorone diisocyanate (IPDI) was incorporated into the formulation to obtain a transparent film, and ethylenediamine (EDA) was used for chain extension. In order to measure the change in physical properties according to the contents of castor oil and TMP, each tensile strength, elongation, and abrasion resistance test was conducted. As the contents of castor oil and TMP increased, the tensile strength increased, the elongation decreased, and the surface hardened strongly as the respective contents increased.

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References

  1. Z. L. Abo-Shanab, A. A. Ragab, M. Mohammedy, S. A. EI-Kholy, "Simple preparation method of asphalt polyurethane foam for various insulating purposes", Egyptian Journal of Petroleum, Vol .29, No. 4, pp. 257-264, (2011).
  2. T. H. Mekonnen, T. Haile, M. Ly, "Hydrophobic functionalization of cellulose nanocrystals for enhanced corrosion resistance of polyurethane nanocomposite coatings", Applied Surface Science, Vol. 540, Part. 1, 148299, (2021).
  3. Z. S. Petrovic, J. Milic, F. Zhang, J. Ilavsky."Fast-responding bio-based shape memory thermoplastic polyurethanes". Polymer, Vol. 121, No. 14, pp. 26-37, (2017). https://doi.org/10.1016/j.polymer.2017.05.072
  4. Q. Zhou, L. Zhang, M. Zhang, B. Wang, S. Wang. "Miscibility, free volume behavior and properties of blends from cellulose acetate and castor oil-based polyurethane". Polymer, Vol. 44, No 5, pp. 1733-1739, (2003). https://doi.org/10.1016/S0032-3861(02)00748-6
  5. Y. S. Kwak, S.W. Park, Y H. Lee, H. D. Kim. "Preparation and properties of waterborne polyurethanes for water-vapor-permeable coating materials". Journal of Apply Polymer Science, Vol. 89, Issue. 1, pp. 123-129, (2003). https://doi.org/10.1002/app.12128
  6. S. M. Cakic, I. S. Ristic, I. Krakovsky, D. T. Stojiljkovis, P. Belsky, L. Kollova. "Crystallizationand thermal properties in waterborne polyurethane elastomers: influence of mixed soft segment block". Materials Chemistry Physics, Vol. 144, Issue. 1, pp. 31-40, (2014). https://doi.org/10.1016/j.matchemphys.2013.12.008
  7. I. Sakurada, Y. Ikada, H. Uehara, Y. Nishizaki, F. Horii, "Chemicalstructure of poly(vinyl alcohol)/methylmethacrylate graft copolymers preparedby various methods", Macromolecular Chemistry and Physics, Vol. 139, Issue. 1, pp. 183-196, (1970). https://doi.org/10.1002/macp.1970.021390114
  8. H. D. Kim, Y. S. Oh, and J. H. Kim, "Development trend of high-strengthpoly (vinyl alcohol) fibers", Polymer Science and Technology. Vol. 15, Issue. 1, pp. 12-19, (2004)
  9. W. R White, D. T. Durocher, "Recycling of Rigid Polyurethane Articles and Reformulation into a Variety of Polyurethane Applications" Journal of cellular plastics, Vol. 33, No.5, pp. 477-86, (1997). https://doi.org/10.1177/0021955X9703300504
  10. Z. W. Abdullah, Y. Dong, I. J. Davis,and S. Barbhulya, "PVA, PVA blends, and their nanocomposites for biodegradable packaging application", Polymer-Plastics Technology and Engineering, Vol. 56, Issue. 12, pp. 1307-1344, (2017). https://doi.org/10.1080/03602559.2016.1275684
  11. S. Toxqui-Lopez, A. Olivares-Perez, I. Fuentes-Tapia, "Polyvinyl acetate with cellulose dinitrate holograms", Optical Materials, Vol. 28, Issue. 4, pp. 342-349, (2006).
  12. W. Han, H. Chen, X. Li, T. Zhang, "Thermodynamic modeling of magnesium ammonium phosphate cement and stability of its hydration products", Cement and Concrete Research, Vol. 138, Article. 106223, (2020).
  13. S. S. Lee, S. H. Lee, D. S. Lee, "Preparation and Properties of waterborne Polyurethane Based on Mixtures of Hybroxy-Terminated Polybutadien and Poly(propylene glycol)". Polymer(Korea), Vol. 30, Issue. 2, pp. 152 (2006)
  14. M. Fuensanta, J. Jofre-RecheJose, M. Martin-Martinez, "Structure and adhesion properties before and after hydrolytic ageing of polyurethane urea adhesives made with mixtures of waterborne polyurethane dispersions", International Journal of Adhesion and Adhesives, Vol. 85, pp. 165-176, (2018). https://doi.org/10.1016/j.ijadhadh.2018.06.002
  15. Y. Hu, G. Gu, S. Z.hou, L. Wu, "Preparation and properties of transparent PMMA/ZrO2 nanocomposites using 2-hydroxyethyl methacrylate as a coupling agent", Polymer, Vol. 52, Issue. 1, pp. 122-129, (2011). https://doi.org/10.1016/j.polymer.2010.11.020