• New & Renewable Energy
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• v.19 no.4
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• pp.2-10
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• 2023

The current mandatory domestic biodiesel blending ratio is 3.5%, which is planned to be gradually increased to achieve carbon neutrality by 2050. The aim of this study was to improve domestic self-sufficiency in biodiesel raw oil by conducting a technical review on the possibility of utilizing waste oils, such as soup oil, chicken oil, and leather oil, as biodiesel feedstocks. These waste oils have an acid value that is too high to be converted directly into biodiesel. Therefore, a pretreatment to reduce the acid value is necessary. The neutralization process was examined as a potential technology for reducing the acid value. The oil recovery rate of the soup oil after neutralization was significantly low at 37.6 wt%. The oil recovery rates of leather oil and chicken oil were 66.49 wt% and 79.08 wt%, respectively. Based on biodiesel conversion experiment using waste oil with a reduced acid value, the conversions were analyzed as 89 wt%, 91.1 wt%, and 90.5 wt% for soup oil, leather oil, and chicken oil, respectively. Thus, it is technically possible to use soup oil, leather oil, and chicken oil as raw materials for producing biodiesel.

• Textile Coloration and Finishing
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• v.18 no.6 s.91
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• pp.31-36
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• 2006

Study has been made for producing anionic surfactant using waste fleshing scraps from the leather making process through refining, esterification, sulfonation and blending processes. As a most optimum lard oil refining method, refining was carried out for 4 hours under temperature of $120^{\circ}C$ and approximately 200 mbar vacuum, which gave a recovery of more than 80% lard oil. Refined lard oil obtained thus was undergone methlyl-esterification, then sulfonated to make a degreasing agent. By methyl-esterification using lard oil, more than 85% of fatty acid and $12{\sim}13%$ of glycerine were extracted from the oil. Sulfonation of the extracted fatty acid ester lard oil has shown most optimum at $15{\sim}20%$ chlorosulfonic acid content, and the content of bonding sulfate at this time was higher than 3.5%. Finally the followed anionic surfactant having degreasing force of 80% and higher could be made by blending process.

• Journal of the Korea Organic Resources Recycling Association
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• v.10 no.3
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• pp.98-109
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• 2002

Each kinds of the leather process wastes which is occurred in the leather making process is almost more than 50% on the basis of the raw hide. The emitted process wastes are important oil and fats and protein resources because they are composed of animal oil and fats and fibrous protein. But most of them are incinerate or filled up simply as the industrial wastes without applying to recycling into the other use. Thus the problems of environmental pollution are becoming more critical and the processing cost of the leather process wastes (40,000~60,000 won) is a heavy burden on the production cost. Because the organic wastes such as fleshing scrap, pelt scrap are high fetid, its unlawful abandonment without being processed properly causes the occurrence of secondary pollution by an offensive odor and leakage of waste water. Thus we made the re-resource experiments in order to resolve this problems. The principal contents of this study are to process the collected leather waste scrape through separate the oil and fat ingredients with various propert by processing various chemicals and enzymes on the next effector. The re-resource application of separated oil and fat ingredients produced chemical for leather applicable to manufacturing process of leather through chemical transformation process(sulphation reaction, sulphitation reaction etc.) of oil and fats.

• Journal of the Korean Home Economics Association
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• v.11 no.4
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• pp.363-373
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• 1973

The Sewability was tested with the seam strength and Puckering Grade by a general sewing machine according to some properties of simulated Leather, yarn tensile strength needle and stitches. The main results tested are as follows ; 1. The thick and uncomfortable leather is unable to be sewed by a general sewing machine, but the thin and soft one is able to. 2. The interval between stitches depends on type of leather used, and the variance in accordance with type of leather varies much more in the case of narrower interval. 3. When the sewability of leather-surface is not so good, is desirable to pour oil on the surface for the purpose of better efficiency. 4. The seam strength is directly proportional to interval of stitch and tensile strength of yarn and leather used, and needle No. 14 is more effective than No.1l. 5. The more the soft and thin leather is, the lower the Puckering Grade becomes. Type of yarn and interval of stitches do not seem to effect the Puckering Grade.

• Journal of Fashion Business
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• v.20 no.4
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• pp.88-95
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• 2016

This paper investigated to the effectiveness of an eco-friendly method for oiling cow leather. After leather was lac-dyed with a vegetable leather processing solution and a mordant, olive oil was used to treat the leather. Changes in surface color and dyeability, light fastness, rubbing fastness, and water fastness were measured. An increase in dyeability caused by the mordant appeared in all the samples. The dyeability of leatger treated with Cu-mordant was higher than that treated with Fe-mordant and Al-mordant, and the three times greater than when no mordant was used. Dyeability after oiling more than doubled compare with before oiling. An increase in dyeability by oiling was highe greater than doubled compared with before oiling. The non-mordant-treated samples exhibited a 5-fold increase in dyeability, and the other samples showed more than two times more dyeability than did non-oiled samples. A color difference of more than 20.0-fold appeared in all samples, and the differences in lightness and chroma were greater than were the differences in other color factors. The colors after oiling were measured R, P, and PB. Light fastness improved in all samples after oiling, and all of the measurements were reduced in the order of Fe-mordant> Cu-mordant> Al-mordant ${\geq}$non mordant.

• Elastomers and Composites
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• v.57 no.4
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• pp.129-137
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• 2022

Low molecular weight liquid butadiene rubber (LqBR) is a processing aid that can resolve the migration problem of tire tread compounds. Various studies are being conducted to replace the petroleum-based processing oil with LqBR. However, the effect of the loading time of LqBR in the compounding process on silica dispersion and vulcanizate properties is not well known. In this study, we analyzed silica dispersion, vulcanizate properties, and viscoelastic properties of silica-filled tire tread compound according to the processing aid type (TDAE oil, non-functional LqBR) and, silane terminated LqBR) and input timing. In the non-functional LqBR compounds, the 'with TESPT' mixing procedure showed excellent dynamic viscoelastic properties while silane-terminated LqBR compounds showed that the 'after TESPT' mixing procedure was good for 300% modulus and abrasion resistance.

• Journal of Adhesion and Interface
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• v.23 no.2
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• pp.33-38
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• 2022

In this study, we report on the synthesis and properties of eco-friendly waterborne polyurethane (WPU) according to bio-polyol contents. It was successfully synthesized by the different polyester polyol (DT-1040) and castor oil based polyol (COP) ratios. The glass transition temperature (Tg) of the synthesized bio polyol based waterborne polyurethane was around -70 ℃ and -30 ℃, and it was confirmed that the Tg range was widened as the COP content increased. In addition, as the COP content increased, the tensile strength decreased, and optimum adhesive strength showed when DT-1040:COP ratio was 7:3.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2008.04a
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• pp.111-113
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• 2008

In this study, for natural leather use, the phytoncide oil of antibacterial materials was encapsulated in several micro-diameter shell which slowly releases from the leather treated with antibacterial microcapsules. The microcapsule was synthesized by in-situ polymerization of urea and formaldehyde. The effects of surfactants on the average particle size and distributions, morphologies and antibiosis were investigated to design microcapsule.

• Journal of the Korean Applied Science and Technology
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• v.39 no.6
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• pp.924-931
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• 2022

Undenatured castor oil and trimethylolpropane (TMP) were used to obtain bio-based water-based polyurethane. Isophorone diisocyanate (IPDI) was incorporated into the formulation to obtain a transparent film, and ethylenediamine (EDA) was used for chain extension. In order to measure the change in physical properties according to the contents of castor oil and TMP, each tensile strength, elongation, and abrasion resistance test was conducted. As the contents of castor oil and TMP increased, the tensile strength increased, the elongation decreased, and the surface hardened strongly as the respective contents increased.

• Journal of the Korean Society of Costume
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• v.58 no.8
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• pp.63-73
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• 2008

From the ancient Korea to the late Joseon Korean fur and leather had been preferred in and out of Korea for their good quality and excellent manufacturing skill. Since Unified Silla (A.D.676${\sim}$A.D.936) Korean fur and leather were manufactured divisionally by workmen specialized in materials and products, and such manufacturing process was succeeded to Goryeo and Joseon. Manufacturing of fur and leather was consisted of as follows: hunting and butchering - peeling - beating with a paddle and removing fat - oil manufacturing - drying - tanning, then cutting and sewing, and there was a special caring method. In order to make good fur and leather, each process of manufacturing needed particular techniques and all available methods were tried to have tender fur and leather by using smoking, excrement, lime, vegetable tannin and even cerebral liquid. And also required mouth-chewing and hand-pounding with a lot of time and of labor Keeping furs resilience and flexibility, sowing several skins together, even when the after-all-process skin was converted into clothes, was much more difficult than sewing fabric. Thus, the manufacturing cost was as much expensive as skin materials, and the volume of manufacturing of fur and leather was also limited. Therefore, fur and leather must have been popular for scarcity value in the manufacturing process, and this scarcity must have caused an extreme luxury of fur.