• 한국음향학회지
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• 제20권4호
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• pp.71-80
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• 2001

2개 층으로 구성된 페커리스 (Pekeris) 모델에 해저퇴적층의 영향을 고려하기 위해 1개의 퇴적층을 증가시킨 2개의 해저층으로 구성된 3층의 유체모델을 가정하고 원통형 좌표계에서 그린 (Green)함수와 경계조건, 좀머펠트 (Sommerfeld) 방사조건 등을 적용하여 해를 구했다. 모드는 불연속 (discrete)모드와 가상 (virtual)모드로 구분하여 구했으며 유도된 불연속모드 산출 관계식은 Tolstoy와 Clay의 정규 (normal)모드 생성방정식과 일치함을 확인하였다. 또한, 환경조건을 페커리스 모델의 조건과 유사하도록 조절하여 시뮬레이션을 수행한 결과, 동일한 결과를 보임을 통해 유도된 수식이 조건에 따라서는 페커리스 모델로 환원됨을 확인하였다. 따라서 본 모델이 근거리 음장내의 가상모드에 대한 퇴적층의 영향 연구에 사용될 수 있다고 판단된다.

• 한국지반공학회논문집
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• 제18권4호
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• pp.55-64
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• 2002

본 논문에서는 점탄-점소성 구성모델을 다층지반에서의 대형지진 발생시의 조건에 적용하기 위해 일본 고베 포트아일랜드에서 발생한 1995 Hyogoken Nanbu 지진에 대한 지진응답 해석을 수행하였다. 지진응답해석 결과 점성토의탄-점소성 모델과 점탄-점소성 모델로 계산된 가속도 기록은 포트아일랜드에서 계측된 가속도 기록과 거의 일치함을 알 수 있었으며, 점성토 지반 부근에서 점탄-점소성 모델과 탄-점소성 모델은 미세하게 다른 거동 특성을 나타내어 점소성 모델의 타당성을 확인하였다. 따라서 동적 점탄-점소성 구성모델은 대변형률 영역에서 점성토의 소성변형을 유발하는 대형 지진 등의 발생시 점성토의 증폭 및 감쇠특성의 파악을 위해 적용가능한 모델임이 입증되었다.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2008년도 춘계 학술발표회 초청강연 및 논문집
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• pp.1042-1050
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• 2008

In this study, SCP method was used by purpose to improve loose sand and soft clay that is drilled Sand Compaction Pile in underground. Settlement behavior of field analyzed through SCP method. When sand Compaction Pile drilled in clay, forming composite ground that foundation and Sand Compaction Pile behavior. According to SCP method can expect bearing capacity improvement, Settlement reduction, lateral flow protection. SCP increase the consolidation settlement of ground and it reduce settlement for that purpose increase liquefaction resistance, lateral Resistance. Because SCP had been widely used for sand. Area of Inchon-A by sand compose clay and silt to upper Ground and compose soft clay to under ground. After pre-loading, it measured settlement by extensometer and settlement extensometer that purpose of ground improvement with 13% in replacement ratio. The result analyzed settlement behavior is similar to Multi-layered Ground that it happened to elastic settlement at upper ground and to consolidation settlement at under ground.

• Macromolecular Research
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• 제16권1호
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• pp.6-14
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• 2008

Polypropylene (PP)-layered silicate nanocomposites were developed using a new processing method involving a supercritical carbon dioxide ($scCO_2$)-assisted co-rotating twin-screw extrusion process. The nanocomposites were prepared through two step extrusion processes. In the first step, the PP/clay mixture was extruded with $CO_2$ injected into the barrel of the extruder and the resulting foamed extrudate was cooled and pelletized. In the second step, the foamed extrudate was extruded with venting to produce the final PP/clay nanocomposites without $CO_2$. In this study, organophilic-clay and polypropylene matrix were used. Maleic anhydride grafted polypropylene (PP-g-MA) was used as a compatibilizer. This study focused on the effect of $scCO_2$ on the dispersion characteristics of the clays into a PP matrix and the rheological properties of the layered silicate based PP nanocomposites. The dispersion properties of clays in the nanocomposites as well as the rheological properties of the nanocomposites were examined as a function of the PP-g-MA concentration. The degree of dispersion of the clays in the nanocomposites was analyzed by X-ray diffraction and transmission electron microscope. Various rheological properties of the nanocomposites were measured using a rotational rheometer. In the experimental results, the $scCO_2$ assisted continuous manufacturing extrusion system was used to successfully produce the organophilic-clay filled PP nanocomposites. It was found that $scCO_2$ had a measurable effect on the clay dispersion in the polymer matrix and the melt intercalation of a polymer into clay layers.

• Food Science and Biotechnology
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• 제14권1호
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• pp.112-116
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• 2005

Composite films were prepared with soy protein isolate (SPI) and various clay minerals by casting from polymer and clay water suspension. Effects of clay minerals on film thickness, moisture content (MC), tensile strength (TS), elongation at break (E), water vapor permeability (WVP), and water solubility (WS) were tested. Properties including thickness, surface smoothness, and homogeneity of films prepared with organically modified montmorillonite (O-MMT), Wamok clay (W-clay), bentonite, talc powder, and zeolite were comparable to those of control SPI films. TS increased significantly (p<0.05) in films prepared with O-MMT and bentonite, while WVP decreased significantly (p<0.05) in bentonite-added films. WS of most nanocomposite films decreased significantly (p<0.05).

• 폴리머
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• 제31권4호
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• pp.297-301
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• 2007

본 연구에서는 poly(ethylene oxide) (PEO), 가소제인 ethylene carbonate(EC), 리튬염인 $LiClO_4$ 그리고 $Na^+-MMT/organic$ MMT를 이용하여 고분자/층상 실리카 나노복합재료(polymer/(layered silicate) nanocomposites, PLSN)를 제조하였으며, organic MMT의 첨가에 따른 고분자 매트릭스에 미치는 영향을 이온전도도를 통하여 관찰하였다. 리튬전지의 전해질로서의 응용을 위해, $Na^+$를 양이온으로 갖는 순수한 MMT($Na^+-MMT$)를 유기화한 nanoclay(organic-MMT)를 사용하였다. 그 결과, 층간 거리 및 소수성이 증가하며 이와 같은 특성은 PEO와의 나노복합체를 형성할 때 MMT의 박리 거동에 영향을 미치는 것을 확인할 수 있었다. 또한, 이온전도도에서는 organic MMT가 순수한 $Na^+-MMT$보다 우수함을 나타내었으며, methyl dihydrogenated tallow ammonium으로 개질된 MMT(MMT-2OA)를 첨가하였을 때 가장 높은 이온전도도를 보였다.

• Elastomers and Composites
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• 제46권2호
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• pp.112-117
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• 2011

고기능 포장재료를 포함한 고차단성 소재산업은 국민소득 증가 및 웰빙 문화와 함께 성장성이 높은 산업으로 성장할 것으로 예상된다. 따라서 최근 고차단성 소재로 기존의 소재와 비교하여 우수한 물성을 나타내는 고분자 나노복합재료에 대한 관심이 크게 증가하고 있다. 고분자 나노복합재료는 고분자 수지와 나노 크기의 충전제로 이루어진 소재를 의미하며, 이에 사용되는 무기 충전제는 층상 실리케이트, 탄소나노튜브, 금속 또는 무기물의 나노입자 등 다양한 물질들이 사용되고 있다. 현재 가장 활발히 적용되고 있는 입자는 다른 나노크기의 충전제와 달리 자연에 풍부하게 존재하며 경제적이고 나노 구조적인 특성을 잘 지닌 층상 실리케이트, 즉 점토(Clay)이다. Clay를 이용한 고분자 나노복합재료는 강도 향상, 난연성, 가스 차단성, 내마모성, 저수축화 등의 장점이 있어서 자동차 소재 및 포장재 등에 우선적으로 적용되고 있다. 따라서 본고에서는 가스차단 소재의 필요성과 더불어 관련 소재 및 기술에 대하여 중심으로 살펴보도록 하겠다.

• Transactions on Electrical and Electronic Materials
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• 제14권1호
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• pp.43-46
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• 2013

In order to develop electrical insulation material, organically modified layered silicate was incorporated into an epoxy matrix to prepare nanocomposite. Transmission electron microscopy (TEM) observation showed that organophillic clay was in an exfoliated state, while hydrophilic clay was not dispersed into nanolayers within the epoxy matrix. Epoxy/organophilic clay (2.8 wt%) nanocomposite was mixed and cured at $150^{\circ}C$ for 4.5 hr. I-V characteristics, volume resistance and dielectric properties for the cured nanocomposite were estimated. Current density increased with increasing temperature, and volume resistance decreased with increasing temperature, in neat epoxy and epoxy/organophilic clay (2.8 wt%) nanocomposite. As frequency increased, the dielectric loss value decreased in the two systems.

• 한국산업융합학회 논문집
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• 제12권1호
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• pp.5-10
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• 2009

The Nylon/clay nanocomposite were prepared with Cloisite25A and Cloisite30B. And mechanical properties and thermal properties of Nylon/clay nanocomposites on the amount of MMT have been investigated. From the results of XRD and TEM, we found that mono layered silicates were dispersed in polymer matrix and those resultants were exfoliated nanocomposites. When Cloisite30B was used as an intercalant in the Nylon/Clay nanocomposites, the mechanical and thermal properties of Nylon were higher than those with Cloisite25A.

• 한국결정성장학회지
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• 제29권1호
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• pp.19-23
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• 2019

The PMMA (polymethyl methacrylate)/clay nanocomposites were synthesized by in situ radical polymerizations with different clay contents (3 and 7 wt%) using microwave heating. The nanostructure, optical, and thermal properties of the synthesized PMMA/clay nanocomposites were measured by XRD, TEM, AFM, UV-vis, and TGA. It was found that the intercalated- or exfoliated structure of PMMA/clay nanocomposites was strongly dependent on the content of clay. Thus, the imposition of microwave-assisted polymerization facilitated a delamination process of layered silicates to achieve exfoliation state of interlayer distance. The PMMA/3 wt% C10A nanocomposite with well-dispersed and exfoliated clay nano-layers showed the good optical transparency similar to pure PMMA in this study. The thermal decomposition rates of the PMMA/clay nanocomposites become to be lower compared to that of the pure PMMA, indicating the intercalated- or exfoliated inorganic silicate has high thermal stability. A possible reason is that the thermally segmental motion of PMMA polymer into inorganic silicate interlayer spacing has increased the thermal stability of the PMMA/clay nanocomposites.