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Comparison of Carotenoid Pigments on Korean Dark Sleeper, Odontobutis platycephala and Dark Sleeper, Odontobutis odontobutis interrupta in the Family Eleotridae (구굴무치과에 속하는 동사리와 얼룩동사리의 Carotenoid 색소성분의 비교)

  • 하봉석;김명선;백승한;김현영;김수영;정계임;권문정
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.27 no.5
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    • pp.813-820
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    • 1998
  • This study was performed as a part of comparative biochemical studies of carotenoid pigment for the fresh water fish. Carotenoids in integument of Korean dark sleeper, Odontobutis platycephala, and dark sleeper, Odontobutis odontobutis interrupta, which are all the Korean native fresh water fish, were separated by thin layer chromatography, column chromatography and HPLC. The separated carotenoid were then reduced and isomerized by NaBH4 and I2 respectively to investigate UV-Vis spectrophotometeric patterns and chracterized by IR, 1H-NMR and Mass spectrum. The content of total carotenoids in the integument of Korean dark sleeper was 3.01mg% in April, but it was increased to 3.74mg% in September at the near of spawning period. The carotenoid isolated in April consisted of $\beta$-carotene(25.6%), lutein(18.5%) and zeaxanthin(12.0%) as major carotenoids and also contained isocryptoxanthin, diatoxanthin, tunaxanthin, cynthiaxanthin, canthaxanthin and $\alpha$-cryptoxanthin as minor carotenoids. Similarly, in September the carotenoid consisted of $\beta$-carotene(16.5%), zeaxanthin(13.7%) and cynthiaxanthin(13.6%) as major carotenoids and also contained lutein, isocryptoxanthin, tunaxanthin, $\alpha$-cryptoxanthin, diatoxanthin and canthaxanthin as minor carotenoids. At the near of spawning period, the content of cynthiaxanthin and $\alpha$-cryptoxanthin were increased. The content of total carotenoids in the integument of spawning period. T도 carotenoid isolated in April and September consisted of $\beta$-carotene(24.9%, 27.5%), zeaxanthin(14.4%, 20.9%) and lutein(12.6%, 11.4%) as major carotenoids and also contained cynthiaxanthin, tunaxanthin, diatoxanthin, isocryptoxanthin, $\alpha$-cryp-toxanthin and canthaxanthin as minor carotenoids. At the near of spawning period, the content of zeaxanthin was increased, indicating that the carotenoid composition were dependent upon their living conditions and their integument colors. Both Korean dark sleeper and dark sleeper contained high amount of cynthiaxanthin and diatoxanthin which are found as rare carotenoids in the other of fresh water fish. It is interes that they also contained tunaxanthin which is a specific carotenoid in marine fishes.

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Effect of Reductants and their Properties of Electric Resistivity on the Preparation of Ag coated Cu Powders by Chemical Reduction Method (화학환원법을 이용한 은 코팅 구리 분말 제조 시 환원제의 영향 및 전기비저항 특성)

  • Ahn, Jong-Gwan;Yoon, Chi-Ho;Kim, Dong-Jin;Cho, Sung-Wook;Park, Je-Shin
    • Korean Journal of Metals and Materials
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    • v.48 no.12
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    • pp.1097-1102
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    • 2010
  • Silver coated copper powders were prepared by a chemical reduction method with controlling the deposition process variables such as the feeding rate of the silver ionic solution and concentration of the reductants at room temperature. The characteristics of the products were evaluated by scanning electron microscope (SEM), X-ray diffractometer (XRD), atomic absorption spectrophotometer (AA) and a 4 probe resistivity measurement system. The optimum condition of the preparation of Ag coated Cu powders was at 0.05 M of potassium sodium tartrate and 2 ml/min of the feeding rate of the silver ionic solution. Our method successfully produced dense, uniform, and well-dispersed Ag coated Cu powder of $2{\sim}2.5{\mu}m$ witha silver layer of 100~200 nm. Additionally, we found that thespecific resistivity of the 30 wt.% Ag coated Cu powder was similar to that of pure silver, so that the composite powder could be used as an alternative electromagnetic shielding material for silver.

Effects of Film Thickness and Annealing Temperature on the Specific Contact Resistivity and the Transmittance of the IZO Layers Grown on p-GaN by Roll-to-Roll Sputtering (p-GaN 위에 Roll-to-Roll sputter로 성장된 IZO의 접촉 비저항 및 투과도에 대한 박막 두께와 열처리 온도의 영향)

  • Kim, Jun Young;Kim, Jae-Kwan;Han, Seung-Cheol;Kim, Han Ki;Lee, Ji-Myon
    • Korean Journal of Metals and Materials
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    • v.48 no.6
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    • pp.565-569
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    • 2010
  • We report on the characteristics of indium-oxide-doped ZnO (IZO) ohmic contact to p-GaN. The IZO ohmic contact layer was deposited on p-GaN by a Roll-to-Roll (RTR) sputter method. IZO contact film with a thickness of 360, 230 and 100 nm yielded an ohmic contact resistance of $4.70{\times}10^{-4}$, $5.95{\times}10^{-2}$, $4.85{\times}10^{-1}\;{\Omega}cm^{2}$ on p-GaN when annealed at $600{^{\circ}C}$ for 1 min under a nitrogen ambient, respectively. While the transmittance of IZO film with a thickness of 360 nm slightly increased in the wavelength range of 380-800 nm after annealing, the transmittance rapidly increased up to 80% after annealing at $600{^{\circ}C}$ in the wavelength range of 380~430 nm because the crystallization of IZO film and created Ga vacancies near the p-GaN surface region were affected by the annealing. These results indicate that ohmic contact resistance and transmittance of the IZO films improved.

Prediction of Baltic Dry Index by Applications of Long Short-Term Memory (Long Short-Term Memory를 활용한 건화물운임지수 예측)

  • HAN, Minsoo;YU, Song-Jin
    • Journal of Korean Society for Quality Management
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    • v.47 no.3
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    • pp.497-508
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    • 2019
  • Purpose: The purpose of this study is to overcome limitations of conventional studies that to predict Baltic Dry Index (BDI). The study proposed applications of Artificial Neural Network (ANN) named Long Short-Term Memory (LSTM) to predict BDI. Methods: The BDI time-series prediction was carried out through eight variables related to the dry bulk market. The prediction was conducted in two steps. First, identifying the goodness of fitness for the BDI time-series of specific ANN models and determining the network structures to be used in the next step. While using ANN's generalization capability, the structures determined in the previous steps were used in the empirical prediction step, and the sliding-window method was applied to make a daily (one-day ahead) prediction. Results: At the empirical prediction step, it was possible to predict variable y(BDI time series) at point of time t by 8 variables (related to the dry bulk market) of x at point of time (t-1). LSTM, known to be good at learning over a long period of time, showed the best performance with higher predictive accuracy compared to Multi-Layer Perceptron (MLP) and Recurrent Neural Network (RNN). Conclusion: Applying this study to real business would require long-term predictions by applying more detailed forecasting techniques. I hope that the research can provide a point of reference in the dry bulk market, and furthermore in the decision-making and investment in the future of the shipping business as a whole.

Carbon-Encapsulated Ni Catalysts for CO2 Methanation (탄소층으로 캡슐화된 Ni나노입자 촉매의 CO2 메탄화 반응)

  • Kim, Hye Jeong;Kim, Seung Bo;Kim, Dong Hyun;Youn, Jae-Rang;Kim, Min-Jae;Jeon, Sang Goo;Lee, Gyoung-Ja;Lee, Kyubock
    • Korean Journal of Materials Research
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    • v.31 no.9
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    • pp.525-531
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    • 2021
  • Carbon-encapsulated Ni catalysts are synthesized by an electrical explosion of wires (EEW) method and applied for CO2 methanation. We find that the presence of carbon shell on Ni nanoparticles as catalyst can positively affect CO2 methanation reaction. Ni@5C that is produced under 5 % CH4 partial pressure in Ar gas has highest conversions of 68 % at 350 ℃ and 70 % at 400 ℃, which are 73 and 75 % of the thermodynamic equilibrium conversion, respectively. The catalyst of Ni@10C with thicker carbon layer shows much reduced activity. The EEW-produced Ni catalysts with low specific surface area outperform Ni catalysts with high surface area synthesized by solution-based precipitation methods. Our finding in this study shows the possibility of utilizing carbon-encapsulated metal catalysts for heterogeneous catalysis reaction including CO2 methanation. Furthermore, EEW, which is a highly promising method for massive production of metal nanoparticles, can be applied for various catalysis system, requiring scaled-up synthesis of catalysts.

Analysis of Monostatic/Bistatic Radar Cross Section of Multi-target for Target Signals Simulation (항적 신호 모의를 위한 다기종 모노스태틱/바이스태틱 레이다반사면적 분석)

  • Park, Jun-Sik;Chi, Soung-Hwan
    • The Journal of the Korea institute of electronic communication sciences
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    • v.16 no.5
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    • pp.789-798
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    • 2021
  • In this study, for the purpose of collecting and analyzing target-specific RCS data of target signals simulator for verification/improvement of radar system performance, VHF band monostatic/bistatic RCS of civil aircraft(B-747, B-737) and fighter(F-16) models were analyzed by EM simulation tool. In order to reduce the RCS analysis time, the analysis time and RCS data were compared and cross-verified. Also, the analysis range was selected by examining the interpolation error according to the analysis angle resolution. The RCS data obtained for each model were analyzed separately by the incident/reflection elevation angle and frequency. The RCS characteristics according to the shape of the aircraft and the incident/reflection azimuth angle were described. Finally, the statistical RCS distribution value of each model is presented through RCS distribution histogram analysis. In the future, the RCS database obtained by this study will be used for the target signals simulator of the VHF band radar system.

Fabrication and Characterization of Spherical Carbon-Coated Li3V2(PO4)3 Cathode Material by Hydrothermal Method with Reducing Agent

  • Moon, Jung-In;Song, Jeong-Hwan
    • Korean Journal of Materials Research
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    • v.29 no.9
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    • pp.519-524
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    • 2019
  • Spherical $Li_3V_2(PO_4)_3$ (LVP) and carbon-coated LVP with a monoclinic phase for the cathode materials are synthesized by a hydrothermal method using $N_2H_4$ as the reducing agent and saccharose as the carbon source. The results show that single phase monoclinic LVP without impurity phases such as $LiV(P_2O_7)$, $Li(VO)(PO_4)$ and $Li_3(PO_4)$ can be obtained after calcination at $800^{\circ}C$ for 4 h. SEM and TEM images show that the particle sizes are $0.5{\sim}2{\mu}m$ and the thickness of the amorphous carbon layer is approximately 3~4 nm. CV curves for the test cell are recorded in the potential ranges of 3.0~4.3 V and 3.0~4.8 V at a scan rate of $0.01mV\;s^{-1}$ and at room temperature. At potentials between 3.0 and 4.8 V, the third $Li^+$ ions from the carbon-coated LVP can be completely extracted, at voltages close to 4.51 V. The carbon-coated LVP exhibits an initial specific discharge capacity of $118mAh\;g^{-1}$ in the voltage region of 3.0 to 4.3 V at a current rate of 0.2 C. The results indicate that the reducing agent and carbon source can affect the crystal structure and electrochemical properties of the cathode materials.

Electrochemical Properties of Natural Graphite coated with PFO-based Pitch for Lithium-ion Battery Anode (리튬이차전지 음극용 석유계 피치로 코팅된 천연 흑연의 전기화학적 특성)

  • Kim, Geun Joong;Jo, Yoon Ji;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.57 no.5
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    • pp.672-678
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    • 2019
  • The electrochemical properties of pitch-coated natural graphite(NG) were investigated as an anode for lithium-ion batteries. The anode materials were prepared by heat-treatment of mixture of NG and petroleum pitch at $1000^{\circ}C$. The pitches with various softening points were used as carbon precursor. The physical properties of anode materials were analyzed by TGA, SEM, PSA and BET. As the softening point increased, the thickness of the coating layer increased and the specific surface area decreased. The electrochemical performances were investigated by initial charge/discharge efficiency, cycle stability, cyclic voltammetry, rate performance and electrochemical impedance spectroscopy. The carbon-coated NG using pitch with softening points of $250^{\circ}C$ showed an initial discharge capacity of 361 mAh/g and a coulombic efficiency of 92.6%. Also, the rate performance(5 C/0.2 C) was 1.6 times higher than that of NG, and it had a capacity retention (90%) after 50 cycles at 0.5 C.

Development of AR System for Asphalt Pavement Compaction Operation and Suggestion for Accompanying Education Program (AR을 이용한 아스팔트 포장 다짐공사 지원 시스템 구축 및 교육과정 제안)

  • Kim, Namho;Cho, Namjun;Kim, Noah
    • Journal of Practical Engineering Education
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    • v.11 no.1
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    • pp.33-41
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    • 2019
  • A pavement construction process consists of series of lay-down operation for pavement materials to form a designated thickness and compaction operation for the lay-down layer to form a designated strength. A technological breakthrough in pavement compaction equipment was made in last 15 years in western countries: intelligent compaction roller, that is equipped with GPS along with other pavement response sensors is becoming a game-changer in pavement construction. This paper introduces AR system that may be used in asphalt pavement compaction operation using intelligent compactor. Since AR technology is very new concept in road construction society, a suggestion for accompanying education program was also made for specific task group in pavement compaction operation. Since AR technology has not been introduced in asphalt pavement compaction operation, the AR compaction management would lead the construction quality of asphalt pavement to the beyond level.

Online Snapshot Method based on Directory and File Change Tracking for Virtual File System (가상파일시스템에서 디렉토리 및 파일 변경 추적에 기반한 온라인 스냅샷 방법)

  • Kim, Jinsu;Song, Seokil;Shin, Jae Ryong
    • The Journal of the Korea Contents Association
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    • v.19 no.5
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    • pp.417-425
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    • 2019
  • Storage snapshot technology allows to preserve data at a specific point in time, and recover and access data at a desired point in time. It is an essential technology for storage protection application. Existing snapshot methods have some problems in that they dependent on storage hardware vendor, file system or virtual block device. In this paper, we propose a new snapshot method for solving the problems and creating snapshots on-line. The proposed snapshot method uses a method of extracting the log records of update operations at the virtual file system layer to enable the snapshot method to operate independently on file systems, virtual block devices, and storage hardwares. In addition, the proposed snapshot mehod creates and manages snapshots for directories and files without interruption to the storage service. Finally, through experiments we measure the snapshot creation time and the performance degradation caused by the snapshot.