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A Study on the RuO2 Electrode Catalyst Prepared by Colloidal Method (콜로이드법으로 합성한 RuO2 전극촉매의 연구)

  • PARK, JIN-NAM
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.3
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    • pp.193-200
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    • 2019
  • $RuO_2$, $PtO_2$, and various $(Ru,Pt)O_2$ colloidal solution were prepared using modified Watanabe method. Electrodes were manufactured by dipping of Ni mesh into the colloidal solution. Manufactured electrodes were characterized by XRD, SEM, and EDS. $(Ru,Pt)O_2$ electrodes showed $RuO_2$ crystal structure and high roughness. The hydrogen evolution reaction (HER) activities were evaluated by Linear Sweep Voltammetry. 1Ru2Pt electrode showed similar activity with commercial electrode, HER potentials are -0.9 V for both.

Pyrolysis Behavior of Pulverized Coal Particles at High Heating Rate (미분탄 입자의 고속가열 열분해거동 해석)

  • JANG, JIHOON;HAN, KARAM;YU, GEUN SIL;LIM, HYEON SOO;LEE, WOOK RYUN;PARK, HO YOUNG
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.3
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    • pp.260-268
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    • 2019
  • The pyrolysis characteristics of pulverized coal particle was numerically analyzed with the drop tube furnace. Based on the simulated gas flow field in the drop tube furnace, the particle velocity, temperature and volatile evolution were calculated with the fourth order Runge-Kutta method. The effects of changes in reactor wall temperature and particle diameter on the pyrolysis behavior of coal particle were investigated. The particle heating rate was very sensitive to the reactor wall temperature and particle size, that is, the higher wall temperature and the smaller particle size resulted in the higher heating rate and the consequent quicker volatile evolution.

Comparative Study between Single-stage and Two-stage Expansion Using LNG Cold Heat (액화천연가스 냉열을 이용한 단일팽창과 이단팽창 사이의 비교 연구)

  • NOH, SANGGYUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.2
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    • pp.188-192
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    • 2019
  • Comparative studies between single- and two-stage expansion process using LNG cold heat have been performed for a closed Rankine power generation cycle. PRO/II with PROVISION release 10.0 from Schneider Electric Company was used, and the Peng-Robinson equation of state model with Twu's alpha function was selected for the modeling and optimization of the power generation cycle using LNG cold heat. In two-stage power generation cycle, 6.7% more power was obtained compared to that of single-stage power generation cycle through the optimization works.

An Optimization of Aging Time for Low-Temperature Water-Gas Shift Over Cu-Zn-Al Catalyst (저온 수성가스 전이 반응용 Cu-Zn-Al 촉매의 숙성시간 최적화)

  • SHIM, JAE-OH;NA, HYUN-SUK;AHN, SEON-YONG;JANG, WON-JUN;ROH, HYUN-SEOG
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.2
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    • pp.103-110
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    • 2019
  • Cu-Zn-Al catalysts were prepared via co-precipitation method for low-temperature water-gas shift (LT-WGS) reaction under practical reaction condition. Aging time was systematically changed to find optimum point for LT-WGS under practical condition. The Cu-Zn-Al catalyst aged for 72 hours showed the highest CO conversion within low-temperature range as well as very stable catalytic activity for 200 hours despite the practical reaction condition.

Simulation of Temperature Behavior in Hydrogen Tank During Refueling Using Cubic Equations of State (3차 상태방정식을 이용한 수소 충전 온도 거동 모사)

  • PARK, BYUNG HEUNG
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.5
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    • pp.385-394
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    • 2019
  • The analysis of temperature behavior of a hydrogen tank during refueling is of significance to clarify the safety of the compressed hydrogen storage in vehicles since the temperature at a tank rises with inflow of hydrogen. A mass balance and an energy balance were combined to obtain analytical model for temperature change during the hydrogen refueling. The equation was coupled to Peng-Robinson-Gasem (PRG) equation of state (EOS) for hydrogen. The PRG EOS was adopted after comparison with other four different cubic EOSs. A parameter of the model was determined to fit data from experiments of various inlet flow rates and temperatures. The temperature and pressure change with refueling time were obtained by the developed model. The calculation results revealed that the extent of precooling was more effective than the flow rate control.

An Optimization Study on the Reliquefaction of Boil-Off Gas from Liquefied Petroleum Gas Storage Tank (액화석유가스 저장탱크로부터 발생하는 증발가스 재액화 공정의 최적화에 대한 연구)

  • NOH, SANGGYUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.5
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    • pp.395-400
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    • 2019
  • Comparative studies between single- and two-stage refrigeration cycle using propane as a refrigerant have been performed for a vapor recompression refrigeration cycle. PRO/II with PROVISION release 10.2 from AVEVA company was used, and the Soave-Redlich-Kwong equation of state model with Twu's alpha function was selected for the modeling and optimization of the refrigeration cycle for the reliquefaction of BOG coming out from the LPG storage tank. In two-stage refrigeraton cycle, 24.8% of compressor power was reduced compared to that of single-stage refrigeration cycle through the optimization works.

A Study on the Efficiency Enhancement of the HT-PEMFC Having Fuel Processing System by Connecting Adsorption Chilling System (흡착식 냉방 시스템을 이용한 수소개질/연료전지 시스템의 효율향상)

  • NASEEM, MUJAHID;KIM, CHUL-MIN;LEE, SANGYONG
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.5
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    • pp.411-417
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    • 2019
  • An adsorption chiller is connected to the fuel processing/fuel cell system to increase the energy efficiency of the system. Since, the minimum temperature of $70^{\circ}C$ is needed to operate the adsorption chiller, HT-PEMFC is used as a heating source and $80^{\circ}C$ hot water in the water tank at the system is supplied to the chiller. Experimentally measured COP of the adsorption chiller was between 0.4-0.5 and the total calcuated efficiency of the connected system was between 60% and 70% comparing to 47% without adsorption chilling system.

A Study on the Characteristics of Spark Ignition Engine Cleanliness by Low Level Bio-Alcohol Blending (저농도 바이오알코올 혼합에 따른 스파크 점화 엔진 청정 특성 연구)

  • CHA, GYUSOB;NO, SOOYOUNG
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.5
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    • pp.428-435
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    • 2019
  • A comparative evaluation of engine cleanliness was performed on the transport gasoline blended with bio- alcohols, and this study was considered to achieve the aim of greenhouse gas reduction in Korea. In particular, the fuel blended with bio-ethanol and bio-butanol showed the best engine cleaning performance both on combustion chamber deposits and intake valve deposits. The deposit control gasoline additive was effective to remove intake valve deposits. In contrast, the amount of combustion chamber deposits were tend to increase even though fuels blended with bio-alcohols were used. In overall, fuels blended with bio-alcohols, compared to fossil fuels, still showed outstanding performance in terms of engine cleanliness.

Investigation of Oxidation Sensitivity with Temperature of Steel Plate Type (강판 종별 온도에 따른 산화 민감도 조사)

  • KIM, JUHAN;LEE, KEEMAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.5
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    • pp.455-464
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    • 2019
  • Experiments were conducted to investigate the sensitivity of steel plate oxidation with temperature in a simulated furnace. Used steel plates were a general steel and a high tensile steel. Porous media burner (PM burner) used in model furnace was made for uniform temperature profile. The surrounding temperature was controlled by adjusting the flow rate of the mixture in the combustor. Oxide layer analysis was performed using SEM image analysis and EDS line scanning. Both steel sheets showed a tendency to increase the thickness of the steel sheet surface oxide layer as the temperature increases, and it was confirmed that the flaking phenomenon in surface oxidation layer appeared when the temperature was above a certain temperature.

Resource Assessment of Theoretical Potential of Ocean Energy in Korea (국내 해양에너지 이론적 잠재량 산정 연구)

  • HWANG, SUJIN;JO, CHULHEE
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.5
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    • pp.465-472
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    • 2019
  • This paper describes the resource assessment of theoretical potential of ocean energy including tidal current energy, tidal range energy, wave energy and ocean thermal energy in Korea to provide reliable basis for feasible development plan of ocean energy. Because of different characteristics of each ocean energy resources, the resource assessment methods were established considering characteristics of each ocean energy resources. The coastal region of Korea has been divided into 10 regions. The results show that tidal current energy is abundant in Incheon-Gyunggi and Jeollanam-do and tidal range energy is abundant in Incheon-Gyunggi. And wave energy is abundant in Jeollanam-do, Jeju and Gyeongsangbuk-do and there is ocean thermal energy in Gangwon-do and Gyeongsangbuk-do.