• Journal of Magnetics
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• 제21권4호
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• pp.622-628
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• 2016

Magnetization property is a critical factor for magnetorheological fluids (MRFs) to achieve the liquid-solid transition. The main focus of this study is on exploring the influence factors on magnetization properties of MRFs. In this paper, a theoretical analysis is performed to discuss the magnetization characteristics of MRFs firstly. Then, a method for the preparation of carbonyl iron-based MRFs is illustrated and five MRFs samples with various material parameters are prepared. It is succeeded by a series of experiments on testing the hysteresis loop and the magnetization curve of each sample and the influence factors are compared and analyzed. Experimental results indicate that there is basically no hysteresis phenomenon on MRFs which exhibits superparamagnetic behavior at room temperature. A surfactant coating on magnetic particles can slightly improve the MRFs magnetization. Additionally, the magnetic susceptibility and the saturation magnetization both increase with the particle concentration, whereas the influence of particle diameter is relatively very small. Moreover, as the temperature increases, the magnetization decreases and the declining rate accelerates gradually.

• 한국자기학회지
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• 제9권2호
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• pp.121-126
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• 1999

친수성 철계 자성유체의 제조와 이 자성유체를 Nd-영구자석과 병용하여 기름 밀봉 장치의 개발을 목적으로 실험검토한 결과 다음과 같은 결론을 얻었다. 1)평균 입경 100$\AA$, 자화값 125.5emu/g, 대기중 15$0^{\circ}C$까지 산화 변질성이 없는 실리카 피착 철 초미립자의 표면에 오레인산 이온, D.B.S. 이온 및 T.M.A. 이온을 흡착한 후 ethylene glycol 용액중에 분산시켜 친수성 철 분말 자성유체를 제조할 수 있었다. 2)이상의 친수성 철 분말 자성유체[70%(g/ )Fe]를 영구자석(3200 Gauss)과 병용하여 기름 밀봉 장치에 응용한 결과 영구자석의 설치 개수를 영구자석 6단 그리고 구동축과 밀봉 장치 사이 간격 0.2mm의 조건에서 압력 7400g/$\textrm{cm}^2$까지 견딜 수 있는 우수한 내압 특성을 얻었다.

• 한국자기학회지
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• 제14권4호
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• pp.131-137
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• 2004

이동통신주파수 대역에서 박형의 전파흡수체를 제작하기 위해 순철 분말을 흡수 충진재로 사용한 고무 복합체의 고주파 특성(복소투자율, 복소유전율) 및 전파흡수특성에 대해 조사하였다. 주요 실험변수는 순철 분말의 초기입도와 형상(구형, 압분체) 변화였다. Attrition milling에 의해 두께가 표피두께보다 작은 순철 압분체를 제작함으로써 임피던스정합 조건에 근접하는 고투자율과 고유전율을 동시에 얻을 수 있었다. 이는 milling에 의해 구형에서 평판상으로 모양이 바뀜에 따라 와전류 손실이 감소하고(복소투자율의 증가), 압분체 간의 정전용량이 증가한 것(복소유전율의 증가)에 기인한다. 초기입도가 10$\mu\textrm{m}$인 순철 압분체를 흡수 충진재로 사용함으로써 이동통신주파수 대역(0.8-2.0㎓)에서 반사손실이 -5㏈(70% 전력흡수율), 두께가 0.7mm 수준인 박형의 전파흡수체를 제안할 수 있었다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2015년도 제51회 KOSCO SYMPOSIUM 초록집
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• pp.325-326
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• 2015

Combustion of coke grains in a pellet used to be modeled using the shrinking core model in the previous indurator simulations. This leads to the discussions about its propriety due to the fundamental assumptions of the model inconsistent with the particle characteristics. The current study presents the grain model as an improvemen, and the differently used reaction models are compared. In addition, the simulations assuming changed particle conditions are conducted to display the effects of using the grain model.

• 폴리머
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• 제29권3호
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• pp.266-270
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• 2005

Fe(CO)$_5$(철-펜타카보닐)의 열분해법을 이용하여 산화철 나노 입자를 제조하였다. 표면 조절 시약으로서 생체적 합성 고분자인 폴리(비닐피롤리돈)(PVP)을 사용하여 산화철 나노 입자의 크기를 제어하였다. 산화철 나노 입자의 형성 여부는 XRD를 통해 분석하였으며, PVP 코팅된 산화철 나노 입자의 크기는 TEM, ELS를 통하여 분석하였다. PVP 코팅 된 산화철 나노 입자의 입자 크기는 PVP/Fe(CO)$_5$의 몰비와 용매, PVP 분자량에 의해 조절되었다. PVP 함량이 증가함에 따라 입자 크기가 증가하였으며 디메틸포름아마이드를 용매로 하였을 때 $50\~100$ nm의 산화철 나노 클러스터가 형성되었고, Carbitol을 용매로 하였을 때 균일하게 분산된 10 nm 이하의 작은 PVP 코팅된 산화철 나노 입자가 형성되었다. 본 연구에서 제조된 PVP코팅된 산화철 나노 입자는 물에 잘 분산될 뿐 아니라 생체적합적인 PVP로 코팅이 되었기 때문에 in vivo에 응용할 수 있으며, 입자의 크기가 $50\~100$nm및 10 nm로 조절됨으로써 MRI 조영제로서 가능성을 가지고 있음을 확인하였다.

• 한국세라믹학회지
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• 제35권3호
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• pp.239-244
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• 1998

출발원료인 ferric nitrate와 ethylene glycol를 사용하여 iron complex를 제조하였으며 이를 $350^{\circ}C$ 이상의 온도에서 열처리하여 200nm 이하의 미세한 입자 크기를 갖는 ${\alpha}-Fe_2O_3$ 분말을 얻었다. 또한 열분석 X-선 회절 분석 및 적외선 분광 분석을 통하여 제조된 iron complex의 분해 mechanism에 대하여 조사하였고, 출발원료의 조성비 및 반응온도에 따른 입자 크기 및 형상의 변화 양상을 전자현미경 분석과 비표면적 분석을 통하여 조사하였다.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2003년도 춘계학술대회 논문집
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• pp.1832-1835
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• 2003

This paper suggests the selective ultra precision polishing techniques for micro die and mold parts using magnetic-assisted machining. Fabrication of magnetic abrasive particle and their polishing performance are key technology at ultra precision polishing process of micro parts. Conventional magnetic abrasives have disadvantages. which are missing of abrasive particle and inequality between magnetic particle and abrasive particle. So, bonded magnetic abrasive particles are fabricated by several method. For example, plasma melting and direct bonding. Ferrite and carbonyl iron powder are used as magnetic particle where silicon carbide and Al$_2$O$_3$ are abrasive particle. Developed particles are analyzed using measurement device such as SEM. Possibility of magnetic abrasive and polishing performance of this magnetic abrasive particles also have been investigated. After polishing, surface roughness of workpiece is reduced from 2.927 $\mu\textrm{m}$ Rmax to 0.453 $\mu\textrm{m}$ Rmax.

• 한국공작기계학회논문집
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• 제12권5호
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• pp.59-66
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• 2003

This study suggests the new ultraprecision finishing techniques for micro die and mold parts using magnetic field-assisted polishing. Conventional magnetic abrasives have several disadvantages, which are missing of abrasive particle and inequal mixture between magnetic particle and abrasive particle. Therefore, bonded magnetic abrasive particles are fabricated by several method. For example, plasma melting and direct bonding. Carbonyl iron powder is used as magnetic particle there silicon carbide and alumina are abrasive particles. Developed magnetic abrasives are analyzed using SEM. Feasibility of magnetic abrasive and polishing performance of this magnetic abrasive particles also have been investigated. After polishing, surface roughness of workpiece is reduced from 85.4 ㎚ Ra to 9 ㎚ RA.

• 한국초전도ㆍ저온공학회논문지
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• 제19권1호
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• pp.22-25
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• 2017

Steel slag has been considered as an industrial waste. A huge amount of slag is produced as a byproduct and the steel slag usually has been dumped in a landfill site. However the steel slag contains valuable resources such as iron, copper, manganese, and magnesium. Superconducting magnetic separation has been applied on recovery of the valuable resources from the steel slag and this process also has intended to reduce the waste to be dumped. Cryo-cooled Nb-Ti superconducting magnet with 100 mm bore and 600 mm of height was used as the magnetic separator. The separating efficiency was evaluated in the function of magnetic field. A steel slag was ground and analyzed for the composition. Iron containing minerals were successfully concentrated from less iron containing portion. The separation efficiency was highly dependent on the particle size giving higher separating efficiency with finer particle. The magnetic field also effects on the separation ratio. Current study showed that an appropriate grinding of slag and magnetic separation lead to the recovery of metal resources from steel slag waste rather than dumping all of the volume.

• 한국입자에어로졸학회지
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• 제9권4호
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• pp.221-230
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• 2013

We demonstrated the efficacy of magnetic nanoparticles (MNPs) produced from a low grade iron ore as an adsorbent for the removal of Cr(VI), a toxic heavy metal anion present in wastewater. The adsorption of Cr(VI) by these MNPs strongly depended on the dosage of MNPs, the initial concentration of the Cr(VI) solutions, and pH. The highest Cr(VI) adsorption efficiency of 22.0 mg/g was observed at pH 2.5. The adsorption data were best fit with the Langmuir isotherm and corresponded to a pseudo-second-order kinetic model. The used adsorbent was regenerated by eluting in highly alkaline solutions. Sodium bicarbonate showed the highest desorption efficiency of 83.1% among various eluents including NaOH, $Na_2HPO_4$, and $Na_2CO_3$. Due to the high adsorption capacity, the simple magnetic separation, and the high desorption efficiency, this nano-adsorbent produced from inexpensive and abundant resources may attract the attention of the industries to apply for removing various metal anionic contaminants from wastewater.