• Title/Summary/Keyword: Interpenetrating network

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A study on the AC dielectric breakdown characteristics and mechanical characteristics of interpenetraing polymer network epoxy composites (상호침입망목 에폭시 복합재료의 교류절연파괴 특성 및 기계적 특성에 관한 연구)

  • 손인환;이덕진;김명호;김경환;김재환
    • Electrical & Electronic Materials
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    • v.9 no.7
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    • pp.702-707
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    • 1996
  • In this paper, in order to improve the withstand voltage properties of epoxy resin, IPN(interpenetrating polymer network) method was introduced and the influence was investigated. The single network structure specimen(E series), simultaneous interpenetrating polymer network specimen(EM series) and pseudo interpenetrating polymer network(EMP series) specimen were manufactured. In order to understand the internal structure properties, scanning electron microscopy method was utilized, and glass transition temperature was measured. Also, AC voltage dielectric breakdown strength, tensile strength and impact strength were measured to investigate the influence upon electrical and mechanical properties. As a result, it was confirmed that simultaneous interpenetrating polymer network specimen was the most execellent.

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AC Dielectric Breakdown Properties and Mechanical Properties of Interpenetrating Polymer Network Epoxy Resin (상호침입망목 에폭시수지의 교류 절연파괴특성 및 기계적 특성)

  • 이덕진;김명호;김경환;심종탁;손인환;김재환
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.320-323
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    • 1995
  • In this paper, in order to improve withstand voltage properties of epoxy resin, IPN(interpenetrating polymer network) method was introduced and the influence was investigated. The sing1e network structure specimen(E series), simultaneous interpenetrating polymer network specimen(EMF series) and pseudo interpenetrating polymer network(EMP series) specimen were manufactured. In order to understand the internal structure properties, scanning electron microscopy method was utilized, rind glass transition temperature was measured. Also, AC voltage dielectric strength, tensile strength and impact strength were measured to investigate influence upon electrical and mechanical properties. As a result, it was confirmed that simultaneous interpenetrating polymer network specimen was the most execellent.

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The Effect of Interpenetrating Polymer Network upon Tracking Resistance of Epoxy Composite Materials (에폭시 복합재료의 내트래킹성에 미치는 상호침입망목의 효과)

  • 김탁용;이덕진;손인환;김명호;김경환;김재환
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.225-229
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    • 1996
  • In this study, in order to develop outdoor insulating materials, SIN(simultaneous interpenetrating polymer network) was introduced to Epoxy resin and the environment resistance was investigated. The single network structure specimen(E series) formed of Epoxy resin alone and simultaneous interpenetrating polymer network specimen (EM series) in which epoxy resin was taken as the first network and methyl methacrylate resin as the second network were manufactured. Ten kinds of specimens were manufacture by filler (SiO$_2$) content. SEM were utilized in order to confirm their network structure changes, and AC voltage dielectric strength was measured. Also, UV-test and tracking test were carried out investigate the environment resistance characteristic. Therefore the variations of network structure were happened as a result of SEM test, and it was confirmed that simultaneous interpenetrating polymer network specimens were more excellent than single network structure specimens.

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A study on the dielectric breakdown properties of two and three interpenetrating polymer network epoxy composites (2,3 성분 상호침입망목 에폭시 복합재료의 절연 파괴 특성에 관한 연구)

  • 김명호;김경환;손인환;이덕진;장경욱;김재환
    • Electrical & Electronic Materials
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    • v.9 no.4
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    • pp.364-371
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    • 1996
  • In this study, in order to investigate the applicability of IPN structure to epoxy resin which has been widely used as electrical and electronic insulating materials, DC dielectric breakdown properties and morphology were compared and analyzed according to variation of network structure, using the single network structure specimen formed of epoxy resin alone, interpenetrating polymer network specimen formed of epoxy resin/methacrylic acid resin, and interpenetrating polymer network specimen formed of epoxy resin/methacrylic acid resin/polyurethane resin. As results of the measunnent of DC dielectric breakdown strength at 50[.deg. C] and 130[>$^{\circ}C$], IPN specimen formed of epoxn, resin 100[phr] and methacrylic acid resin 35[phr] was the most excellent, and which corresponded to the SEM phenomena. The effect of IPN was more remarkable at high temperature region than at low temperature region. It is supposed that the defect of epoxy resin, dielectric breakdown strength is lowered remarkably at high temperature region, be complemented according to introducing IPN method.

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A Study on the Dielectric Characteristics in Epoxy Resins due to Variation of Network Structures (망목 구조 변화에 따른 에폭시 수지의 유전 특성에 관한 연구)

  • 김재환;손인환;심종탁;김경환;김명호;최병옥
    • Electrical & Electronic Materials
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    • v.10 no.7
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    • pp.651-658
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    • 1997
  • In this paper, effect of interpenetrating polymer network(IPN) introduction on the dielectric properties, heat proof properties, internal structure and defects of the Epoxy/SiO$_2$composite materials, were investigated. we reported a relation between network structures and electrical properties, especially dielectric characteristics with variation of network structures for epoxy composite materials. According to experimental results, the specimens which have single network structures have lower dielectric constant than interpenetrating polymer network(IPN) specimens, but have relatively larger dependency to variation of temperature and frequency. It was confirmed that change of structures is attained by introducing of IPN to insulating materials. Therefore it is counted that introduction of multiple structure including IPN is necessary to improve heat proof and electrical properties.

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Dielectric Breakdown Characteristics of Epoxy Composites due to Voltage Wave Pattern (전압파형에 따른 에폭시 복합재료의 절연파괴특성)

  • Kim, M.H.;Park, C.O.;Lee, Y.S.;Lee, D.J.;Kim, J.H.
    • Proceedings of the KIEE Conference
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    • 1997.07e
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    • pp.1767-1769
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    • 1997
  • In this paper, interpenetrating polymer network method was introduced in order to improve withstand voltage properties of epoxy resin. The single network structure specimen(E series), simultaneous interpenetrating polymer network specimen(EM series) and pseudo interpenetrating polymer network(EMP series) specimen were manufactured. In order to investigate influence upon electrical properties, dc, ac, and impulse voltage dielectric strength were measured. As a result, it was confirmed that electrical properties of epoxy composites can be superior as IPN introduced to it bring about firm and high density of inner structure.

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A Semi-Interpenetrating Network for Temperature-Sensitive Polymer System

  • Yuk, Soon-Hong;Cho, Sun-Hang
    • Macromolecular Research
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    • v.8 no.2
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    • pp.89-94
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    • 2000
  • A semi-interpenetrating network (IPN) was prepared for a temperature-sensitive polymer system composed of sodium alginate and poly (N, N-dimethylaminoethyl methacrylate (DMAEMA)-co-ethyl acrylamide (EAAm)). The role of sodium alginate is to provide crosslinked network and that of poly(DMAEMA-co-EAAm) is to provide temperature responsiveness to the polymer system. Semi-IPN gel shows temperature-induced swelling transition at the same temperature of the lower critical solution temperature of poly(DMAEMA-co-EAAm) and its swelling kinetics is manipulated by the control of crosslinking densitv.

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Swelling and Drug Release Characteristics of Poly (ethylene oxide)-Poly (methacrylic acid) Interpenetrating Networks (폴리에틸렌 옥사이드-폴리메타크릴산 IPN 공중합체의 팽윤 및 약물 방출특성)

  • Lee, Seung-Jin
    • Journal of Pharmaceutical Investigation
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    • v.21 no.3
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    • pp.149-153
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    • 1991
  • Polyethylene oxide (PEO)-polymethacrylic acid (PMAA) interpenetrating polymer networks (IPN) were synthesized via radical polymerization of PMAA and simultaneous crosslinking of PEO using triisocyanate. The equilibrium swelling of PEO-PMAA IPN was determined at different pHs. The swelling of PEO-PMAA IPN, ranged from 20% to 90%, was more sensitive than that of homo polymer PMAA gel This is probably due to protonation and deprotonation of the PMAA network and interpolymer complex formation between PEO and PMAA. Several model drugs were loaded into the IPN matrices and the release mechanisms were investigated. The release of nonionizable drugs such as ftorafur and prednisolone was controlled by swelling of the matrices. However, he release of propranolol, positively charged drug, was more affected by the ionic interaction between the drug and PMAA newtork, and the interpolymer complexation.

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Semi-interpenetrating Solid Polymer Electrolyte for LiCoO2-based Lithium Polymer Batteries Operated at Room Temperature

  • Nguyen, Tien Manh;Suk, Jungdon;Kang, Yongku
    • Journal of Electrochemical Science and Technology
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    • v.10 no.2
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    • pp.250-255
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    • 2019
  • Poly(ethylene oxide) (PEO)-based solid polymer electrolytes (SPEs) show promise for improving the lithium ion battery safety. However, due to oxidation of the PEO group and corrosion of the Al current collector, PEO-based SPEs have not previously been effective for use in $LiCoO_2$ (LCO) cathode materials at room temperature. In this paper, a semi-interpenetrating polymer network (semi-IPN) PEO-based SPE was applied to examine the performance of a LCO/SPE/Li metal cell at different voltage ranges. The results indicate that the SPE can be applied to LCO-based lithium polymer batteries with high electrochemical performance. By using a carbon-coated aluminum current collector, the Al corrosion was mostly suppressed during cycling, resulting in improvement of the cell cycle stability.

Fabrication and Characterizations of Interpenetrating Polymer Network Hydrogel Membrane Containing Hydrogel Beads (하이드로젤 비드를 포함한 상호 침투 고분자 네트워크 하이드로젤 멤브레인의 제조 및 특성 분석)

  • Kim, Do-Hyeong;Kang, Moon-Sung
    • Membrane Journal
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    • v.29 no.4
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    • pp.231-236
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    • 2019
  • In this study, alginate-based hydrogel membranes composed of hydrogel beads and highly tough hydrogel matrix including moisturizing oil and natural emulsifier were prepared and their elution characteristics were evaluated. As a result, it was confirmed that the elution rate of the moisturizing oil component can be controlled within a desired range by controlling the composition of the hydrogel bead and the tough hydrogel matrix. In particular, it has been confirmed that by combining tough hydrogel having a structure of interpenetrating polymer network (IPN) and hydrogel beads, the physical stability of the membranes can be improved and the elution rate of the moisturizing oil can also be controlled more finely.